首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   115篇
  免费   8篇
  国内免费   3篇
电工技术   3篇
综合类   4篇
化学工业   32篇
金属工艺   3篇
机械仪表   4篇
建筑科学   8篇
矿业工程   2篇
能源动力   4篇
轻工业   35篇
水利工程   4篇
石油天然气   5篇
无线电   3篇
一般工业技术   16篇
冶金工业   2篇
自动化技术   1篇
  2023年   8篇
  2022年   4篇
  2021年   6篇
  2020年   10篇
  2019年   6篇
  2018年   9篇
  2017年   4篇
  2016年   2篇
  2015年   4篇
  2014年   5篇
  2013年   13篇
  2012年   13篇
  2011年   9篇
  2010年   5篇
  2009年   5篇
  2008年   5篇
  2007年   2篇
  2006年   6篇
  2005年   7篇
  2004年   1篇
  2003年   1篇
  2002年   1篇
排序方式: 共有126条查询结果,搜索用时 16 毫秒
1.
2.
The synergistic effect of bark resin of Schinus molle (BRSM) and iodide ions in 0.5 M sulfuric acid has been studied for the first time by potentiodynamic polarization and electrochemical impedance spectroscopy measurements; also, the surface morphology has been analyzed by scanning electron microscopy–energy-dispersive X-ray spectroscopic analysis in the present work. The results show that the BRSM and iodide ions have an evident synergistic inhibition effect in a 0.5-M sulfuric acid solution. The adsorption of the BRSM/iodide ion system follows the Langmuir adsorption isotherm and acts as a mixed-type inhibitor in sulfuric acid. The BRSM/iodide ion system is an effective inhibitor for API5L X70 pipeline steel in the 0.5-M sulfuric acid solution. The maximum percentage inhibition efficiency is equal to 99% at 1 g/L BRSM + 2 mM KI.  相似文献   
3.
以驱蚊酯生产过程中产生的废醋酸为原料,经碱皂化和活性炭吸附有机杂质,制备了一种环保型融冰剂。皂化工艺中以Na OH为皂化剂,80℃下皂化2h;吸附剂活性炭用量为0.3%,吸附时间为0.5~0.8h。添加质量分数为0.4%~0.5%的磷酸二氢钠为缓蚀成分,实验所得产品融冰能力为同等浓度下氯化钠的163%,产品对碳钢的腐蚀率为Na Cl的7%,对混凝土无腐蚀。  相似文献   
4.
随着人们环保意识的增强和环保法规的日益严格,不含重金属防污剂的环境友好防污涂料成为目前研究的热点。文中通过室内的接触角、水解失重和吸水率跟踪测试,研究了3种主链降解型聚丙烯酸锌树脂的表面润湿性能和自抛光性能;并将其与天然产物防污剂(Butenolide)复配制备了天然产物基无铜自抛光防污涂料,通过防污剂释放率测试和浅海浸泡试验对防污剂的释放行为和实海防污能力进行了研究。结果表明:主链降解型聚丙烯酸锌树脂H100Z具有优异的自抛光性能(质量损失可达8.4 mg·cm−2)和较低的溶胀程度(吸水率仅为12.3%),可作为Butenolide的载体,实现对其可控、稳定和持续的释放,该防污涂料在南海海域(深圳)和东海海域(厦门)浸泡3个月后均展现出优异的防污效果。  相似文献   
5.
空港经济区作为一种新型的空间经济组织形式,其规划与建设正逐步成为热点之一。针对空港经济区建设的生态型困境,文章对已有生态城市的理论研究、实践总结基础上,提出了生态型空港经济区的规划建设理念,以安康高新区富强空港生态城为实证对象,从产业选择、空间布局、交通布局和社区营造等方面,总结生态型空港经济区的空间布局理念与模式,以期为今后相关地区的规划提供方法上的参考。  相似文献   
6.
Latent heat storage by phase change materials (PCM) is a promising way of thermal energy storage for equilibrating the daily fluctuation of temperature in office- and home buildings. Bio-originated compounds have got great importance to evade further plastic contamination all over the world. Durability of biodegradable natural materials by means of environmentally friendly agents is an exciting challenge. In this study Ca alginate-coconut oil eco-friendly core-shell PCM microcapsules were functionalized with Ag nanoparticles, following their synthesis using harmless reducing agents. Throughout the preparation of the PCM microcapsules by repeated interfacial coacervation/crosslinking procedure, the Ag nanoparticles were homogeneously dispersed in the Ca alginate shell. High coconut oil content was achieved in the Ag nanoparticle-loaded microcapsules, which was not influenced by the Ag nanoparticle content. The high PCM content resulted in correspondingly high latent heat storing capability. The freezing and melting heat storing capacities were in the range of 83.6 and 85.6 J/g, as well as 89.7 to 92.6 J/g, respectively, matching to the extremely high PCM content in the range of 82.7% to 84.8% (m/m). Leaking of the heat storing microcapsules was not observed after 200 heating-cooling cycles. The Ag nanoparticle content did not influence the PCM ratio of the microcapsules, although as expected their antimicrobial potential was significantly enhanced by it. The highest Ag nanoparticle loading, that was 1.3% (m/m) related to the total mass of microcapsules, exerted excellent antibacterial and antifungal impact.  相似文献   
7.
Selective separation of sodium with citric acid leaching from red mud has been put forward. The main factors and dealkalization mechanism by using inductively coupled plasma atomic emission spectroscopy, X-ray diffraction, and shrinking core model were studied. The results show that the dealkalization rate reached more than 95% under the following conditions: citric acid dosage of 15%, liquid-to-solid ratio of 7 mL/g, leaching temperature of 100°C, stirring speed of 300 rpm, and leaching time of 120 min. Sodium easily dissolved in the solution by citric acid leaching. The dealkalization process was controlled by internal diffusion and the apparent activation energy (Ea) was 19.43 kJ/mol.  相似文献   
8.
《功能材料》2012,43(10)
采用熔融缩聚法制备了一种新型可降解的6-氨基己酸(6N)和β-丙氨酸(βA)的二元共聚物(PAA),并研究了该共聚物的性能。采用红外光谱分析(FT-IR)、X射线衍射分析(XRD)、差示扫描量热分析(DSC)、热重分析(TGA)等手段对其结构进行了表征,结果表明,所合成的材料是2种单体的聚酰胺共聚物;随β-丙氨酸含量的增加,共聚物的结晶度、熔融温度呈先减小后增大的趋势,而分解温度呈依次减小的趋势,当共聚物中2种单体摩尔比为1∶1时,其为无定形共聚物。共聚物在去离子水中的降解实验结果表明,材料具有良好的降解性能;不同单体比例合成的共聚物中,共聚物的降解速率与共聚物的结晶度成反比,当聚合物中2种单体摩尔比为1∶1时,聚合物的降解速度最快,2周后几乎完全降解;整个降解过程中,降解液的pH值都维持在相对稳定的水平。在环保方面,该材料可望有良好的应用前景。  相似文献   
9.
生态超纤皮革是一种新型人工皮革材料。阐述了国内外汽车超纤皮革的发展和应用状况,介绍了隆莱特生态超纤皮革的优良性能及其特点。在汽车内饰的应用中,隆莱特生态超纤皮革可以替代天然皮革,在提高汽车内饰材料性能的同时还可降低产品的生产成本。  相似文献   
10.
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号