全文获取类型
收费全文 | 43459篇 |
免费 | 4909篇 |
国内免费 | 1002篇 |
专业分类
电工技术 | 2884篇 |
技术理论 | 3篇 |
综合类 | 3092篇 |
化学工业 | 12338篇 |
金属工艺 | 828篇 |
机械仪表 | 644篇 |
建筑科学 | 2856篇 |
矿业工程 | 15839篇 |
能源动力 | 2937篇 |
轻工业 | 322篇 |
水利工程 | 401篇 |
石油天然气 | 1126篇 |
武器工业 | 36篇 |
无线电 | 358篇 |
一般工业技术 | 1648篇 |
冶金工业 | 2427篇 |
原子能技术 | 84篇 |
自动化技术 | 1547篇 |
出版年
2024年 | 27篇 |
2023年 | 272篇 |
2022年 | 941篇 |
2021年 | 1372篇 |
2020年 | 1544篇 |
2019年 | 858篇 |
2018年 | 907篇 |
2017年 | 878篇 |
2016年 | 1002篇 |
2015年 | 1404篇 |
2014年 | 2928篇 |
2013年 | 2543篇 |
2012年 | 4216篇 |
2011年 | 3662篇 |
2010年 | 2623篇 |
2009年 | 2772篇 |
2008年 | 2443篇 |
2007年 | 2893篇 |
2006年 | 2507篇 |
2005年 | 2115篇 |
2004年 | 1701篇 |
2003年 | 1646篇 |
2002年 | 1313篇 |
2001年 | 1212篇 |
2000年 | 1007篇 |
1999年 | 786篇 |
1998年 | 541篇 |
1997年 | 505篇 |
1996年 | 379篇 |
1995年 | 346篇 |
1994年 | 285篇 |
1993年 | 181篇 |
1992年 | 201篇 |
1991年 | 166篇 |
1990年 | 148篇 |
1989年 | 117篇 |
1988年 | 54篇 |
1987年 | 48篇 |
1986年 | 28篇 |
1985年 | 196篇 |
1984年 | 238篇 |
1983年 | 173篇 |
1982年 | 150篇 |
1981年 | 7篇 |
1980年 | 7篇 |
1979年 | 6篇 |
1978年 | 5篇 |
1977年 | 3篇 |
1976年 | 3篇 |
1951年 | 10篇 |
排序方式: 共有10000条查询结果,搜索用时 78 毫秒
1.
Fiber production from inorganic industrial solid wastes is an effective waste management strategy. Because of cost considerations, most enterprises generally use local solid wastes as raw materials to produce fibers. In this study, we explored the feasibility of producing fibers using fly ash and magnesium slag. The results show that the melting temperature of the blends composed of fly ash, magnesium slag, and a small amount of calcined dolomite first decreased and then increased with an increase in acidity coefficient (Mk) from 1.0 to 2.4. The samples could form a eutectic system in the Mk range of 1.4–1.8, and therefore have a relatively low melting temperature in this Mk range. Fly ash could react with magnesium slag and calcined dolomite to form akermanite, gehlenite-magnesium, and anorthite at temperatures close to the melting temperature; therefore, these crystalline phases were the main reaction products formed in the samples with Mk values lower than 1.80. Anorthite reacted further with some Na-containing and Si-containing spieces to produce labradorite. Thus, the content of anorthite and labradorite rapidly increased and they became the major crystal phases in the blend samples with Mk values greater than 1.80. MAS-NMR spectroscopic analysis revealed that the network structure of the melts depended on the ratio of bridging oxygen to non-bridging oxygen; a high ratio of bridging oxygen to non-bridging oxygen could lead to the formation of a dense network structure in the melt. The blends of fly ash and magnesium slag can be used to produce wool fibers and continuous fibers. In addition, the suitable temperature ranges for the production of both types of fibers were determined. The drawing temperature for continuous fiber production depended on the degree of polymerization and structure of the melt. 相似文献
2.
Han Chen Shunzo Shimai Jin Zhao Xiaojian Mao Jian Zhang Guohong Zhou Shiwei Wang 《Journal of the European Ceramic Society》2021,41(6):3838-3843
Alumina platelets were arranged horizontally in submicron alumina particles by shear force in the flow of slurries during casting. The obtained alumina green bodies with platelets were pressureless-sintered in vacuum, producing ceramics with thoroughly oriented grains and high transmittance. The effects of sintering parameters on the densification, microstructure evolution, and orientation degree of alumina ceramics were investigated and discussed. The results showed that the densification, grain size, orientation degree, and in-line transmittance were increased with increasing sintering temperature. The enhancement of orientation degree was mainly coherent with grain growth. The grain-oriented samples exhibited a much higher in-line transmittance (at 600 nm) of 61 % than that of the grain random sample (29 %). Moreover, the transmission remained a high level in the ultraviolet range (<300 nm). 相似文献
3.
《矿业科学技术学报(英文版)》2021,31(3):429-437
In this article an attempt to determine the influence of mining factors on the seismic activity during the longwall mining of the upper layer of coal seam no. 405/2 in one of the Polish hard coal mines in the Upper Silesian Coal Basin was conducted. Two longwall panels were mined in analogous geological conditions and based on the same mining system and technology. However, there was significant difference with regards to the mining factors, which was reflected in the observed seismic activity. Some tools used in mining seismology were applied to illustrate the aforementioned influence of mining factors, e.g. the frequency-energy distribution, the frequency-magnitude distribution, the 2 D distribution of released seismic energy, the relationship between released seismic energy and the volume of mined coal, the Benioff strain release, and the Gutenberg-Richter(GR) b coefficient distribution(b is the proportion between high and low energy tremors). Concerning the Benioff strain release, a new solution, based on the slope of a fitted line in a moving time window, is proposed. 相似文献
4.
采用在线汞测试方法,以山西省低热值煤电厂中掺烧的煤泥为研究对象,利用实验室小型流化床,研究煤泥中汞的热转化行为差异及共性特征、影响煤泥热转化过程中汞迁移的关键因素,以揭示煤泥热转化过程中汞污染物的迁移机理。结果表明,同一种煤泥,相同气氛,800、900、1 000 ℃下,燃烧温度对煤泥中的汞的释放比例没有变化;相同温度,汞的释放比例为氮气>空气>氧气。3种煤泥在相同燃烧条件下,汞的释放特征相似,元素汞的释放量和释放比例差异较大。释放量与煤泥中的汞含量正相关,释放比例与煤泥中汞的赋存形态有一定关系。 相似文献
6.
The substitution of coal blending with sawdust had been widely investigated for metallurgical coke production. In this paper, the physiochemical structures of the semicoke derived from sawdust/coals blends co-coking were characterized by several analytical techniques including FTIR-ATR, XPS, NMR, OM, and SEM. Meanwhile, the influence of the sawdust on the physicochemical properties of the sawdust/coals blends were also investigated. Results indicated that partial substitution of coal blending with sawdust benefited from the formation of colloid and optical anisotropy due to the positive synergetic effect, whereas high proportion of sawdust (>10 wt%) inhibited the agglomeration of semi-coke. On the other hand, the semicoke consisted primarily of aromatic carbons replaced by the oxygen linked to carbons and aliphatic carbons when the coal blending was replaced by high proportion of sawdust, causing a less polyaromatic graphite-like structure formation in the semicoke. 相似文献
7.
8.
《International Journal of Hydrogen Energy》2022,47(72):30830-30842
Carbon dioxide (CO2) and methane (CH4) are the primary greenhouse gases (GHGs) that drive global climate change. CO2 reforming of CH4 or dry reforming of CH4 (DRM) is used for the simultaneous conversion of CO2 and CH4 into syngas and higher hydrocarbons. In this study, DRM was investigated using Ag–Ni/Al2O3 packing and Sn–Ni/Al2O3 packing in a parallel plate dielectric barrier discharge (DBD) reactor. The performance of the DBD reactor was significantly enhanced when applying Ag–Ni/Al2O3 and Sn–Ni/Al2O3 due to the relatively high electrical conductivity of Ag and Sn as well as their anti-coke performances. Using Ag–Ni/Al2O3 consisting of 1.5 wt% Ag and 5 wt% Ni/Al2O3 as the catalyst in the DBD reactor, 19% CH4 conversion, 21% CO2 conversion, 60% H2 selectivity, 81% CO selectivity, energy efficiency of 7.9% and 0.74% (by mole) coke formation were achieved. In addition, using Sn–Ni/Al2O3, consisting of 0.5 wt% Sn and 5 wt% Ni/Al2O3, 15% CH4 conversion, 19% CO2 conversion, 64% H2 selectivity, 70% CO selectivity, energy efficiency of 6.0%, and 2.1% (by mole) coke formation were achieved. Sn enhanced the reactant conversions and energy efficiency, and resulted in a reduction in coke formation; these results are comparable to that achieved when using the noble metal Ag. The decrease in the formation of coke could be correlated to the increase in the CO selectivity of the catalyst. Good dispersion of the secondary metals on Ni was found to be an important factor for the observed increases in the catalyst surface area and catalytic activities. Furthermore, the stability of the catalytic reactions was investigated for 1800 min over the 0.5 wt% Ag-5 wt% Ni/Al2O3 and 0.5 wt% Sn-5 wt% Ni/Al2O3 catalysts. The results showed an increase in the reactant conversions with an increase in the reaction time. 相似文献
9.
In this investigation, low-cement castables were prepared using 70% alumina grog aggregates obtained from crushed alumina brick waste. The aggregates were thermally treated at 1550 °C for 3 h. Four types of low-cement castables were prepared with various types of aggregates (alumina grog with or without thermal treatment) and fillers (with or without zircon addition), and they were evaluated in terms of their physical, thermal, and chemical properties. Microstructural analysis via scanning electron microscopy (SEM) was performed on the castables before and after slag attack. Compared to the other fabricated castables, the thermally treated alumina grog castables with zircon showed better physical properties, such as a higher bulk density, cold crushing strength, and modulus of rupture and a lower apparent porosity and water absorption. In addition, they had a higher positive linear thermal expansion, refractoriness under load, permanent linear change, and hot modulus of rupture. The results of the SEM with energy dispersive X-ray analysis of the prepared castables confirmed that the mullite and anorthite phases were predominant when zircon was not added and the zircon–mullite phase additionally appeared upon the incorporation of zircon. A quantitative elemental analysis via X-ray fluorescence spectroscopy was employed to determine the composition of the castables. X-ray diffraction analysis showed that the alumina grog castables had a high mullite and low anorthite content, and the thermally treated alumina grog had a high anorthite, low mullite, and high zircon content. The improvement in the mechanical and thermo-mechanical properties of the castables with thermally treated alumina grog and added zircon can be attributed to the formation of the zircon–mullite phase with a low mullite phase content. 相似文献
10.
H. Hudelja B. Wicklein D. Kuščer A. Kocjan 《Journal of the European Ceramic Society》2021,41(1):590-598
Understanding aqueous dispersion, rheological properties and colloidal stabilisation mechanisms of hierarchically assembled ceramic powders is important for progress in the fields of catalysis, separation and/or adsorption. The present study was designed to evaluate the rheological and sedimentation behaviour of highly loaded aqueous suspensions (up to φA = 0.126) containing AlN-powder-hydrolysis-derived, micron-sized, mesoporous, gamma alumina (MA) particulates with a high surface area (~180 m2/g) dispersed with sodium polyacrylate (NaPAA). The as-prepared suspensions were prone to sedimentation and segregation. However, when divalent cations (Mg2+, Ca2+) or cellulose nanofibers were added, the formation of interparticle association networks in the aqueous suspensions containing MA particles was triggered, facilitating their long-term resistance to sedimentation lasting more than 12 weeks. 相似文献