电弧炉采用石灰石单渣冶炼工艺的研究

采用优质石灰石取代质量差的白灰 ,进行了单渣电弧炉熔炼。结果表明 ,钢水成本降低 ,钢水质量提高 ,取得了良好的效果。     

焦作市石灰岩开发及应用

焦作市石灰岩储量极为丰富,要把资源优势转变为经济优势,就要搞好综合开发利用,生产出科技含量高,具有市场竞争能力的新产品。本文旨在探讨石灰岩资源综合利用的新途径,为焦作矿业经济可持续发展作出新贡献,并为焦作市矿产资源规划提供科学依据。     

Characterization of Thai limestone for desulphurization in a fluidized bed combustor

The objective of this study is to determine the chemical kinetics of desulphurization of Thai limestone in an atmospheric fluidized bed combustor (AFBC). The experiments, which employed the batch technique using the limestone samples from six major sources in Thailand, were performed in a laboratory‐scale AFBC. The results obtained were analysed and correlated in the form of apparent reaction rate and deactivation rate constants as a function of operating conditions of the furnace and their properties, respectively. The formulae derived from these correlations were kept as general as possible in order that they could be used as input parameters for the selected mathematical model of desulphurization in an AFBC that is suitable for practical use. The predicted results were in good agreement with the experimental data reported in the literature. Copyright © 2003 John Wiley & Sons, Ltd.     

新型组合式碳化法生产纳米级碳酸钙新工艺

介绍了组合式碳化新工艺理论依据、工艺特点、设备结构及与传统方法对比情况。新型组合式碳化新工艺具有设备结构简单、操作方便、易于实现自控操作等特点,产品质量稳定,同一套设备控制不同工艺条件,可生产多种晶型、不同粒度、不同性质的纳米级或微米级各类碳酸钙产品,低温能耗低、投资少,连续生产,生产效率高、单塔生产能力大,符合大型化生产需求。     

Characterization of the reactivity of limestones with SO2 in a fluidized bed reactor

The reaction between SO₂ and calcined limestone particles has been studied in a fluidized bed combustor. Measurements of sorbent reactivity with SO₂ were made for small batches of limestone injected into the combustor. Simultaneous continuous combustion of bituminous coal provided conditions like those of a boiler for study of the sulphation reaction. A semi-empirical rate model of the CaO-SO₂ reaction has been developed. External mass transfer of SO₂, diffusion within the particles and chemical reaction are taken into account. The limestone reactivity with SO₂ is characterized by two parameters which are dependent on the temperature and sorbent particle size. A model for predicting the limestone requirements in a fluidized bed boiler has been developed. Parameters from the batch experiments are included. The predictions for sulfur retention agree with the experimental results. In addition, effects of operating conditions (gas velocity, recycle, limestone particle size) on the retention of SO₂ were simulated using the model.     

尾部烟气增湿活化脱硫原理性研究

论述应用大速差射流的尾部烟气脱硫增湿活化原理怀试验台架及其系统，试验结果及分析，在尾部烟气中ＳＯ２气体直接与固相脱硫剂（ＣａＯ粉及Ｃａ（ＯＨ）２粉）反应能力很弱；ＳＯ２气体直接与水滴反应生成Ｈ２ＳＯ３的能力也能弱，它受到ＳＯ２气体在水中溶解能力的限制；增湿活化的机理在于水滴与脱硫剂粒子碰撞后在其表面生在液态Ｃａ（ＯＨ）２离子膜，由它与ＳＯ２气体反应脱硫。因此，良好的活化反应器必须具有良好的水滴与脱     

石灰石在煤气化过程中的催化和固硫作用

基于CaO在煤气化中的催化和固硫作用,以及石灰石加热分解的性质,石灰石有可能作为煤气化过程中的催化剂和固硫剂。本文根据国内外对石灰石在煤燃烧和煤气化中作用的研究,从石灰石结构、Ca/C,Ca/S,可能的反应机理等几个方面进行了介绍和分析,并指出需进一步研究的内容。     

用对流磨粉碎石灰石的试验研究

本文扼要介绍了对流磨的结构与粉碎原理，及粉碎石灰石的试验研究。研究的主要内容是给料粒度与粉碎产物细度和能量效率的关系，以及喷嘴形状与能量效率的关系。     

Chemical Reaction Engineering and Research and development of gas solid systems

A general procedure is proposed for innovative research and development of gas-solid reactor systems, with a brief explanation of the significance of each step in the procedureBased upon the contacting mode between gas and solid phases, as well as the ways of supplying thermal energy to the reacting regions, various types of gas-solid reactor systems are classified by using tables of so called “matrix” form, for thermal cracking and gasification of heavy oils, gasification of coal, gasification of solid waste, calcination of limestone, clinkering of cement and reduction of iron ore.The importance of fundamental concepts is emphasized for successful research and development by presenting several examples; namely, calcination of limestone, thermal cracking of heavy oils and gasification of solid waste materials.In connection with the direction in which fundamental research should be oriented, four primary ways of thinking are proposed, which can be applied to obtain innovative ideas for further research and development in this field.One example of the author's practical experience was selected to show the role of the fundamental research in the course of large scale development. Finally the author outlines the role of chemical reaction engineering to innovate the novel gas-solid reactor systems which may be inevitable for simultaneous solution of the three big E's; namely, Energy, Environment and Economy.     

Strength of limestone-based non-calcined cement and its properties

A new type of cement was prepared with ground limestone powder, blastfurnace slag, steel slag and gypsum without calcination. The fraction of ground limestone powder in the cement was as high as 40 wt%–60 wt% without Portland clinker. All of its physical properties can meet the requirements of masonry cement standards. The impact of limestone content on physical properties of the cement and determined its impact on law was investigated. The steel slag can excit the aquation activity of this cement effectively, and the influence of its quantity on the strength of the materials was studied, which shows that the optimum quantity of mixing is 10%. By way of changing the different content of the lime stone by quartzy sample, the law of the compression strength and the PH value was determined, confirming that the lime stone can promote the early aquation of the slag and improve the early strength. The main hydration product of this cement is calcium aluminate hydrate, ettringite and calcium silicate hydrate, as indicated by XRD and SEM analysis.