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1.
Two-dimensional rotating detonation waves (RDWs) with separate injections of hydrogen and air are simulated using the Navier–Stokes equations together with a detailed chemical mechanism. The effects of injection stagnation temperature and slot width on the detonation propagation patterns are investigated. Results find that extremely high temperatures can lead to a chaotic mode in which detonation waves are generated and extinguished randomly. Increasing the slot width can reduce the number of detonation waves and finally trigger detonation quenching at a low injection stagnation temperature. But increasing the slot width can change the RDW propagation pattern from a chaotic to a stable mode under high injection temperature. Furthermore, the kinetic parameter τ (representing the chemical reactivity of the mixture) and the kinematic parameter α (representing the mixing efficiency of hydrogen and oxygen) are introduced to distinguish the RDW propagation patterns.  相似文献   
2.
《Ceramics International》2022,48(22):33177-33184
The rare earth (Yb3+) substituted W-type hexagonal ferrites with composition CaPb2-xYbxFe16O27 (x = 0.0, 0.5, 1.0, 1.5, 2.0) were synthesized by a facile and cost-effective sol-gel auto combustion method with post heat treatment. The synthesized hexagonal ferrites were characterized by a variety of analytical techniques, and an impedance analyzer was used to investigate the effects of Ytterbium on structural, magnetic, spectral and dielectric properties. The relationship between their impedance, structure and dielectric properties was investigated. The X-ray diffraction patterns verify the presence of single-phase W-type hexagonal ferrites. Physical properties such as Dbulk (bulk density), Dxrd (X-ray density), and P (porosity) of the CaPb2-xYbxFe16O27 W-type hexagonal ferrites were calculated. The bulk density of all the samples was decreased, and X-ray intensity was increased with the Ytterbium replacement in the W-type hexaferrite. By adding Yb3+ ions, the lattice parameters, cell volume and X-ray density were reduced due to the substitution of ytterbium with smaller ionic radii compared to the lead ion with large ionic radii. The AC-conductivity was increased from (1.523 × 10?5 to 6.699 × 10?5) Ωcm?1. The dielectric constant and tangent loss was found to decrease substantially. The magnetic properties were found to enhance by the substitution of Yb3+. The low coercivity value of Yb3+ substituted W-type hexagonal ferrites are suitable for magnetic recording media operated at a high-frequency regime. The enhancement of electrical, dielectric and magnetic characteristics suggests these materials as promising for multi-layer chip inductors (MLCIs) circuit applications.  相似文献   
3.
《Ceramics International》2022,48(14):19513-19526
Comprehensive control of processing techniques is primordial when fine-tuning the morphological features of titanium dioxide nanotube arrays (TNTs). This systematic review and meta-analysis compiled articles published from 2007 to date on the synthesis and growth mechanism of nanotubes fabricated via electrochemical anodization and evaluated the potential relationships between anodizing conditions and the resulting structures. Studies were gathered from the Science Direct online database, screened according to predefined criteria, and evaluated for their eligibility. Ninety-nine studies were assessed in the meta-analysis, 87 of them on tube length, 80 on tube diameter, and 33 on wall thickness. Multiple linear regression was performed to test if anodization parameters significantly predicted the resulting morphology of TiO2 nanotubular structures. Overall regression for the three responses was statistically significant (length: R2 = 0.487, p < 0.001; diameter: R2 = 0.899, p < 0.001; wall thickness: R2 = 0.792, p < 0.001). Applied potential was one of the main effects predicting all three responses (p < 0.001 in every model). Other important main predictors were anodizing time for tube length (p < 0.001), water percentage for tube diameter (p < 0.001) and ammonium fluoride (NH4F) concentration for wall thickness (p < 0.001).  相似文献   
4.
介绍了在复杂环境下爆破拆除一地下特大钢筋混凝土支撑的技术难点。由于合理选取爆破参数,采取孔内高段、孔外低段毫秒微差起爆网路,安全防护采取覆盖、近体、保护性三种措施,有效地阻止了飞石对周围建筑物的损害,并对爆破可能产生的危害进行了科学验算,最后分多次爆破圆满完成拆除任务。  相似文献   
5.
分析了注射模生产的现状,针对其生产中智能化调控应用方面的不足,提出模内参数的自适应调节方案,还介绍了自适应工作的原理、可调参数种类、逻辑推理等,并实际验证了基于注塑设备联网集成工艺数据下注射模成型工艺自适应调节的可行性。  相似文献   
6.
This paper presents a physics-based compact gate delay model that includes all short-channel phenomena prevalent at the ultra-deep submicron technology node of 32 nm. To simplify calculations, the proposed model is connected to a compact α-power law-based (Sakurai-Newton) model. The model has been tested on a wide range of supply voltages. The model accurately predicts nominal delays and the delays under process variations. It has been shown that at lower technology nodes, the delay is more sensitive to threshold voltage variations, specifically at the sub-threshold operating region as compared with effective channel length variations above the threshold region.  相似文献   
7.
In present work, the development of macroporous monolithic layers bearing the artificial recognition sites toward L-phenylalanine has been carried out. The set of macroporous poly(2-aminoethyl methacrylate-co-2-hydroxyethyl methacrylate-co-ethylene glycol dimethacrylate) materials with average pore size ranged in 340–1200 nm was synthesized. The applicability of Hildebrand's and Hansen's theories for the prediction of polymer compatibility with porogenic solvents was evaluated. The dependences of average pore size on theoretically calculated parameters were plotted. The linear trend detected for Hansen's theory has indicated the high suitability of this approach to select appropriate porogens. The synthesized monolithic MIP layers were tested toward the ability to rebind phenylalanine-derivative in microarray format. The influence of such factors as average pore size of the material, the concentration of template molecule in polymerization mixture, interaction time of analyte with its imprinted sites on binding efficiency were studied. The developed materials demonstrated good analyte rebinding from buffer solution with recognition factors 2.5–3.4 depending on the MIP sample. The comparable rebinding efficiency was also detected when the analysis was carried using complex biological media. The selectivity of phenylalanine binding from the equimolar mixture of structural analogues was 81.9% for free amino acid and 91.2% for labeled one.  相似文献   
8.
The SAFT-γ Mie group-contribution equation of state is used to represent the fluid-phase behavior of aqueous solutions of a variety of linear, branched, and cyclic amines. New group interactions are developed in order to model the mixtures of interest, including the like and unlike interactions between alkyl primary, secondary, and tertiary amine groups (NH2, NH, N), cyclic secondary and tertiary amine groups (cNH, cN), and cyclic methine-amine groups (cCHNH, cCHN) with water (H2O). The group-interaction parameters are estimated from appropriate experimental thermodynamic data for pure amines and selected mixtures. By taking advantage of the group-contribution nature of the method, one can describe the fluid-phase behavior of mixtures of molecules comprising those groups over broad ranges of temperature, pressure, and composition. A number of aqueous solutions of amines are studied including linear, branched aliphatic, and cyclic amines. Liquid–liquid equilibria (LLE) bounded by lower critical solution temperatures (LCSTs) have been reported experimentally and are reproduced here with the SAFT-γ Mie approach. The main feature of the approach is the ability not only to represent accurately the experimental data employed in the parameter estimation, but also to predict the vapor–liquid, liquid–liquid, and vapor–liquid–liquid equilibria, and LCSTs with the same set of parameters. Pure compound and binary phase diagrams of diverse types of amines and their aqueous solutions are assessed in order to demonstrate the main features of the thermodynamic and fluid-phase behavior.  相似文献   
9.
We report here the development of two computational tools PCFPS (Photonic Crystal Fiber Parameter Study) and PCFPA (Photonic Crystal Fiber Parameter Analysis), equipped with graphical user interface (GUI) for modeling of photonic crystal fiber. The tools are based on different structural parameters, and they provide characteristic analysis of the modal parameters from the structural parameters. The main feature of PCFPS is that it enables the user to find out the values of each defining modal parameter that has an immense contribution towards the manufacture of photonic crystal fiber. Additionally, PCFPA allows the user to observe the variation in the modal parameters with respect to the changes in structural parameters (such as d, Λ, d/Λ, and λ/>Λ). Besides their ease of use, these two schemes have high computational precision and adaptability, giving a novel platform to optical engineers to modulate the microstructured fibers according to their requirement.  相似文献   
10.
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