Taylor Bubble Study of the Influence of Fluid Dynamics on Yield and Selectivity in Fast Gas-Liquid Reactions

A consecutive competitive gas-liquid reaction is investigated using a Taylor bubble setup regarding the influence of fluid mixing in the bubble wake on yield and selectivity. The concentration fields behind a Taylor bubble are visualized and measured quantitatively with a novel time-resolved absorption imaging technique based on Beer Lamberts law and an integral selectivity is derived. In addition, the calculation of the local selectivity, often used in numerical approaches, is discussed and the existing experimental limits for its derivation are pointed out. Finally, an increase in selectivity of a competitive consecutive reaction for enhanced mixing is experimentally confirmed.     

Numerical Simulation of Sterilization Processes for Shear‐Thinning Food in Taylor‐Couette Flow Systems

The performance of the Taylor‐Couette flow apparatus as a heat sterilizer is numerically investigated. The destruction of Clostridium botulinum and thiamine (vitamin B1) was selected as model reaction. When Taylor vortices were formed in the annular space, the heat transfer significantly enhanced as compared to the case without vortex flow. As a result, the equivalent lethality calculated from the temperature field increased, which is regarded as a quantum leap. Conversely, the improvement of heat transfer induced destruction of thiamine. These results suggest that there is a trade‐off relationship between the enhancement of heat transfer and the avoidance of thermal destruction of nutritional components. In conclusion, the Taylor‐Couette flow sterilizer has the potential for process intensification in heat sterilization processes.     

无源波分复用设备应用分析

【】：针对NB基站和新建基站采用C-RAN接入,导致城区光缆网纤芯资源紧张,提出利用无源波分复用设备方式进行扩容纤芯,但无源波分复用设备插入损耗,造成了全程链路衰耗增大,理论分析最大传输距离,给出了无源波分复用设备和彩光模块选型,最后结合光缆网现状,提出无源波分复用设备的应用方案。     

Deposition of UF5 on the surface of steel material having oxide coating in contact with gaseous UF6

When UF6 is handled in leak tight system, the amount of uranium compound formed on the surface of containers, valves, and others in UF6 handling facilities is not so significant for a short term that special attention has not been given to this problem. The present work was done to throw some more light on this problem based on the recent experiment. We discuss the possibility that the intermolecular transfer of a fluorine atom from UF6 to UF5 may participate in the formation of uranium compound. The discussion includes also the unique features contained in the experimental result, the reaction processes assumed in this problem, and the derivation of a rate equation for expressing the deposition of uranium compound. Furthermore, we propose a new method for determining nonlinear parameters included in a governing differential equation having two variables for expressing the deposition of uranium compound from experimental raw data.     

Investigations on Selectivity of Gas-Liquid Reactions in Capillaries

Biocatalysis offers a broad spectrum of possible ecological and economic advantages over conventional chemical catalysis processes, e.g., lower energy consumption and high enantio selectivity. The focus of this work is on gas-liquid reactions. These are of great importance in the chemical and biochemical industry and subject of current research since they are often limited by mass transfer or show low selectivity. Different suitable biocatalytically gas-liquid reaction systems were tested in capillary reactor designs in order to obtain information about the interaction between reaction and fluid mechanics. Furthermore, an optical measuring method was established. The experiments were performed in batch mode in a glass beaker with a flow cuvette for UV/Vis measurement of product concentration.     

泰勒涡流流动及强化传热数值研究

泰勒涡流为叠加于剪切流之上的二次流，其具有强化传热作用，在航空、水处理、制药工程和化工等领域都具有很大的应用价值。运用Fluent软件，建立长径比Γ = 30的模型并对同轴套管间的流态演变和传热特性进行了数值模拟。模拟结果显示了环隙内流体流态随着内筒转速增加的演变过程，表明在存在径向温差的情况下，涡流的存在强化了传热效率。对不同转速下的强化传热效果进行了对比分析，并确定了最佳状态点。     

双波长叠加紫外光度法测定SDBS

研究了硫酸耐尔蓝与十二烷基苯磺酸钠(SDBS)的反应,建立测定SDBS的双波长叠加紫外光度法。在pH=5.02缓冲溶液中,硫酸耐尔蓝与SDBS形成离子缔合物,在紫外区有正、负吸收峰,大正吸收波长位于304 nm,大负吸收波长位于280 nm,摩尔吸光系数分别为ε280为2.5×104L·mol-1·cm-1,ε304为2.2×104L·mol-1·cm-1,当用双波长叠加法时,ε280+304为4.7×104L·mol-1·cm-1,线性范围均为0.5~4 mg/L。研究了反应的适宜条件,用于环境水中SDBS的测定,回收率在98.9%~103.2%。     

相似模拟实验中光纤光栅传感检测研究

为探索相似模拟实验新的检测方法,研究了光纤光栅传感技术在相似模拟实验中的应用.采用在模型中埋设光纤光栅传感器的方法,检测采动过程中上覆岩层的应力变化.实验选用1.2m×0.12m平面应力模型,光纤光栅传感器选用无封装裸露光栅,分布有五个光栅点.为作对比分析,两光栅附近埋设压力传感器.结果可知,岩层应力变化可使光栅发生波长漂移,其变化趋势与压力传感器测试结果相一致,可以反映应力的变化规律.光纤光栅传感技术可以被应用于相似模拟实验中的应力检测,这对于提高相似模拟实验的检测手段具有重要的意义.     

大型结构非线性物理参数识别的线性化算法

提出了一种识别大型结构非线性物理参数的Taylor级数线性化算法.该算法基于反应力向量灵敏度模型参数化方法的改进算法,适用于线性结构的一般有限元模型;根据结构的时域测量响应,能够直接识别出未知集中输入下结构在单元水平上的非线性物理参数.在算法中,经Tay-lor级数线性化处理后的识别方程,可以简便地由通用有限元程序得到;且其严重病态特性可以通过预处理方法得到有效改善.结果表明,对数值仿真-剪力墙结构的物理参数识别,当保证无噪声条件下的识别精度100%时,算法的计算效率提高了100多倍,且识别结果对初始估计值敏感程度显著下降,因而特别适合于大型结构非线性物理参数的识别.