A Highly Sensitive,Reversible, and Bidirectional Humidity Actuator by Calcium Carbonate Ionic Oligomers Incorporated Poly(Vinylidene Fluoride)

Sensitivity and multi-directional motivation are major two factors for developing optimized humidity-response materials, which are promising for sensing, energy production, etc. Organic functional groups are commonly used as the water sensitive units through hydrogen bond interactions with water molecules in actuators. The multi-coordination ability of inorganic ions implies that the inorganic ionic compounds are potentially superior water sensitive units. However, the particle forms of inorganic ionic compounds produced by classical nucleation limit the number of exposed ions to interact with water. Recent progress on the inorganic ionic oligomers has broken through the limitation of classical nucleation, and realized the molecular-scaled incorporation of inorganic ionic compounds into an organic matrix. Here, the incorporation of hydrophilic calcium carbonate ionic oligomers into hydrophobic poly(vinylidene fluoride) (PVDF) is demonstrated. The ultra-small calcium carbonate oligomers within a PVDF film endow it with an ultra-sensitive, reversible, and bidirectional response. The motivation ability is superior to other bidirectional humidity-actuators at present, which realizes self-motivation on an ice surface, converting the chemical potential energy of the humidity gradient from ice to kinetic energy.     

面向分拣机器人的珍珠形状视觉检测方法

针对人工进行珍珠形状分拣效率低、精度不稳定等问题,提出基于机器视觉的珍珠形状检测方法;采用背光成像方式消除珍珠表面纹理和光泽的影响,对获取的珍珠图像进行同态滤波等预处理算法,提高图像对比度;为了解决相互接触珍珠影响珍珠轮廓提取的问题,采用分水岭算法对珍珠图像进行分割,得到了独立存在的珍珠个体,再通过连通域标记、质心算法对珍珠进行定位;根据国家标准对珍珠形状的规定,基于珍珠图像信息建立珍珠形状参数模型,对珍珠形状进行量化;实验结果表明,不同形状的珍珠样本的检测误差为0.63%,形状统计精度为100%,算法耗时24 ms;该方法可准确高效地对珍珠进行分拣分级,具有一定的实用价值。     

结合位图切割和区域合并的彩色图像分割

就经典分水岭图像分割算法中存在的过分割问题，提出一种结合位图切割和区域合并的彩色图像分割算法。对原始彩色图像通过空域梯度算子求其梯度图像，并利用位图切割重建梯度图像；对新梯度图像进行分水岭预分割；对预分割图像基于异质性最小原则进行区域合并，并获得最终分割结果。相比于现有的同类方法，该算法引入位图切割，抑制噪声对分割结果的影响，在边缘模糊处分割准确，得到符合人类视觉的较小分割区域数目，同时在运行效率上提高。     

基于电锅炉的火电机组灵活性改造技术研究

为有效解决东北电力产能过剩,促进风电、核电等清洁能源消纳问题,提升燃煤供热机组的灵活性,针对东北地区某热电厂,通过对热电解耦时间、电锅炉型式以及不同电锅炉容量配置对机组实际发电负荷的影响等灵活性改造关键技术进行研究,确定了最佳电锅炉容量,提出了电锅炉装设方案,并对改造前后机组的调峰能力和性能指标进行对比分析。研究表明:随着电锅炉容量增长,抵减电锅炉用电后机组实际发电负荷率显著降低,提升火电机组灵活性改造后,电厂调峰能力显著提升,考虑以全厂172 MW发电负荷运行,电厂调峰能力在采暖初末期增加了368 MW,采暖中期增加了528 MW;全厂供热标煤耗由39.7 kg/GJ降低至34.3 kg/GJ,降低了5.4 kg/GJ;经济效益显著,扣除电锅炉用电成本后1个采暖季的调峰辅助服务补贴收益为1.47亿元;同时,电锅炉投运后可实现电厂的上网电量接近零,为清洁能源就地消纳做出贡献。     

New cardo silylated poly(azomethine)s containing 9,9′‐diphenylfluorene units as materials with Brønsted acid‐dependent fluorescence

Aromatic poly(azomethine)s have been studied due to their attractive properties such as high thermal stability, semiconducting behavior and the ability to coordinate species with their imine units (C?N). In this paper, the synthesis and characterization of two novel silylated poly(azomethine)s containing cardo units are reported. These materials were highly soluble in organic solvents such as chloroform and m‐cresol and were thermally stable, and PAzMC1 exhibited a high glass transition temperature value (287 °C), while that for PAzMC2 was not observed. UV–visible spectrophotometry revealed absorption bands related to the aromatic backbone of both PAzMCs, 300–285 nm in tetrahydrofuran and 310–301 nm in dimethylsulfoxide, and bands attributed to the conjugated imine unit at around 350 nm. In order to investigate the phenomenon of the emission of fluorescence promoted by dopant agents with regard to potential optoelectronic applications, the materials were doped with H₂SO₄ and their optical and electrochemical properties investigated. Thus, the absorption band of the imine group was suppressed due to the nitrogen atoms being protonated. Fluorescence spectroscopy analysis developed in dilute solutions of polymers showed no emission from the undoped polymers, whereas the acid‐doped species emitted fluorescence in the UV and violet regions (322 nm). Cyclic voltammetry measurements were carried out and HOMO–LUMO energies were estimated. This study provides a starting point for the development of new poly(azomethine)s with doping‐dependent emission. © 2019 Society of Chemical Industry     

超临界CFB机组汽动给水泵油中进水分析

白马循环流化床示范电站600MW超临界CFB机组自投运以来,A、B汽动给水泵组经常出现润滑油质偏差现象,主要原因为油中含水过大造成。通过对给水泵相关系统进行全面的分析研究,指出了润滑油进水的原因是,给水泵轴承和密封水采用的呼吸器易堵塞造成回油室为较大负压状态。给水泵转速变化时,低压密封水室压力轻微波动,微正压的水进入微负压的回油室,造成油中微量带水。经过分析研究提出改进建议,运行后取得了较好效果,汽动给水泵组的油中含水量大幅降低,保证了机组安全稳定运行。     

汽轮机运行调节方式优化策略探析

分析了汽轮机的喷嘴调节、节流调节、旁通调节、定压调节和滑压调节等几种基本调节方式的特点,指出现役燃煤火电机组多因调节方式单一而普遍存在着调峰能力不足、负荷响应迟缓以及因长期偏离设计工况致使运行安全经济性下降等诸多问题,提出了通过调节方式的优化组合,采用(节流)定压-滑压-(喷嘴)定压-旁通调节的复合调节方式,以实现煤电机组安全、经济、灵活、快速地参与电网的深度调峰,破解具有强随机波动性的新能源电量规模化并网的困境。     

Polymer electrolytes and interfaces in solid-state lithium metal batteries

The polymer electrolyte based solid-state lithium metal batteries are the promising candidate for the high-energy electrochemical energy storage with high safety and stability. Moreover, the intrinsic properties of polymer electrolytes and interface contact between electrolyte and electrodes have played critical roles for determining the comprehensive performances of solid-state lithium metal batteries. In this review, the development of polymer electrolytes with the design strategies by functional units adjustments are firstly discussed. Then the interfaces between polymer electrolyte and cathode/anode, including the interface issues, remedy strategies for stabilizing the interface contact and reducing resistances, and the in-situ polymerization method for enhancing the compatibilities and assembling the batteries with favorable performances, have been introduced. Lastly, the perspectives on developing polymer electrolytes by functional units adjustment, and improving interface contact and stability by effective strategies for solid-state lithium metal batteries have been provided.     

新形势下地勘单位实现绿色发展的研究

针对近年来国家对绿色发展的需求，从矿产资源需求现状及地勘行业新形势入手，分析了矿产勘查开发的必要性及面临的新形势，并重点阐述了新形势下地勘单位实现绿色发展的途径:引领生态优先绿色发展新理念，落实政策导向，深化绿色勘查理念，以绿色发展为指导，实现产业转型突破；支持国企致力于生态绿色发展行动，调整企业工作重点，提高绿色勘查技能，引进民营投资等混合所有制经济模式；培育高质量发展市场主体，做好人才培养、人才储备工作，强化专业技术团队建设；建立有效激励和约束机制。