Kinetics of oxygen absorption in aqueous sodium dithionite solutions

The absorption and reaction of oxygen in aqueous alkaline solutions of sodium dithionite has been experimentally investigated in a novel gas-liquid contactor. The novel gas-lift bubble column contactor was used to study the kinetics over wide ranges of reactant concentrations, temperature, and pH. The oxygen-sodium dithionite reaction was found to be first-order with respect to dithionite in the range of dithionite concentration < 0.1 M, and second-order in the range of dithionite concentration > 0.1 M. The reaction with respect to oxygen was found to be zero-order for all dithionite concentrations. These results and experimental investigations of the effect of solution alkalinity and temperature on the reaction rate are consistent with previous findings obtained in different gas-liquid contactors. The results thus confirm the feasibility of using the gas-lift bubble column for the kinetics of gas-liquid reactions.     

美国能源部的浆态床F－T合成技术

浆态床Ｆ－Ｔ合成技术是美国能源部Ｆ－Ｔ合成技术的主要开发项目。本文就浆态相Ｆ－Ｔ合成催化剂的开发、中试示范实验和浆态反应器的化工基础研究作一扼要的介绍。     

华龙国际大厦混合结构构件及节点设计

论述了矩形钢管混凝土柱钢框架、混凝土核心筒结构在江西华龙国际大厦的应用，介绍了矩形钢管混凝土混合结构总体设计、节点大样及构造。     

轴向均布荷载压杆稳定问题的重心插值配点法

用重心插值配点法对轴向均布荷载下压杆稳定问题进行了研究。采用重心Lagrange插值多项式建立未知函数的微分矩阵,采用配点法将压杆稳定问题的控制方程表示为代数方程组。通过求解代数方程组系数矩阵的特征值和特征向量,得到了精度很高的后屈曲挠度数值和临界载荷数值。实例证明,这种方法原理简单,易于程序实现。     

2号高炉高冶强下的指标优化措施

在高冶强的生产状态下,高炉如何优化各项技术经济指标,降低其成本,从而提高产品竞争力,是现代高炉操作者积极探索的问题。梅钢2号高炉通过精料、优化操作、改进工艺措施等的实施,实现了高炉高冶强下的指标优化。     

高层建筑钢结构柱安装测控方法

针对目前高层建筑钢结构柱安装测量控制方法中存在的一些技术盲点,提出处理方法和改进建议。     

粮油中转储备库的加固改造设计

介绍了加固方案的选择、相关构件强度的计算、接点构造的处理等主要加固步骤。实践证明,此方案较经济、合理,且能最大程度地减少施工工作量。     

热场致发射电子源曝光系统的技术现状和应用前景

高亮度、长寿命的热场致发射(Thermal field emitter)阴极自七十年代中期已受到人们的关注和重视,历经十多年在理论分析、工艺制备和实验研究上做了大量工作之后,于1988年在电子束曝光机上的应用中取得了突破性进展。用晶向为(100)的钨和具有低逸出功的锆制成的(Zr/O/W)热场致发射阴极在四千小时的使用寿命下亮度值超过六硼化镧阴极一个数量级以上,最近的实验结果表明:在工件台上小束斑下能得到接近两千安培每平方厘米的束流密度,而且四十小时内束流稳定度接近千分之一。显然,这几个表征曝光系统综合技术性能的重要指标,说明多年困扰于各种电子束曝光系统(特别是高斯圆斑电子束系统)在高分辨率情况下生产率较低的技术难题已经得到了比较圆满的解决。 八十年代末期,当热场致发射电子源曝光系统的技术关键解决后,这项技术就成为技术发达国家,特别是美国和日本,在电子束曝光领域进行技术竞争的热点;九一年五月底在美国召开的国际三束会议上有关场致发射阴极和MEBES—4型机已经采用TFE的最新报道充分证实了这项技术在电子束曝光技术应用中的重要地位和发展潜力。     

Adsorption separation of condensate oil from produced water using ACTF prepared of oil palm leaves by batch and fixed bed techniques

A novel method is applied to produce amorphous carbon thin film (ACTF) from oil palm leaves. The novel prepared ACTF is in the form of thin films like graphene sheets having winding surface. ACTF was characterized by different methods of characterization: FTIR, BET, SEM, EDX, TEM, and Raman. ACTF employed as an adsorbent to separate emulsified condensate oil from synthetic produced water as a treatment process before reinjection in oil reservoirs. The adsorption performance of batch and fixed bed adsorption systems were investigated. Contact time, initial concentration of condensate oil ($C_o$ = 100–2500 mg/l) and temperature were studied by batch experiments. The obtained results indicated that the adsorption capacity and the removal efficiency increased with time up to 132.77 mg condensate/g adsorbent and 66.38% respectively, within 6 h equilibrium time at 308 K. The thermodynamic adsorption experiments conducted at 288, 308 and 318 K, referring exothermic nature of the adsorption process.The performance study of fixed bed adsorption described through the breakthrough curves concept with two parameters: column bed heights (5, 10 and 15 mm) and flow rate (2.2, 5 and 8.4 ml/min). Two models (Thomas and Yoon-Nelson models) were applied to expect different parameters of fixed bed as adsorption capacity and time need for 50% breakthrough. The results exhibited that 2.2 ml /min feed flowrate and 5 mm bed height at 1000 mg/l initial oil condensate concentration were the optimum conditions for the ACTF column. The experimental breakthrough curves showed acceptable fit with the calculated breakthrough profiles obtained by Thomas model.     

Ring Network Design by Lagrangean Based Column Generation

We discuss the problem of designing a telecommunication network with the survivability requirement that the network should be composed of connected rings of links. The network design problem is then to choose links from a given network, and compose them into a number of rings. Furthermore, the rings should be connected at certain transit nodes. The traffic between rings may pass through other rings. Each ring is associated with a certain fixed cost depending on the length of the ring. We describe the problem, modeled as a linear integer programming problem, and a heuristic solution method, based on column generation and Lagrangean relaxation.