Total Site Hydrogen Integration with fresh hydrogen of multiple quality and waste hydrogen recovery in refineries

This paper proposes a novel method combining Pinch Methodology and waste hydrogen recovery, aiming to minimise fresh hydrogen consumption and waste hydrogen discharge. The method of multiple-level resource Pinch Analysis is extended to the level of Total Site Hydrogen Integration by considering fresh hydrogen sources with various quality. Waste hydrogen after Total Site Integration is further regenerated. The technical feasibility and economy of the various purification approaches are considered, demonstrated with a case study of a refinery hydrogen network in a petrochemical industrial park. The results showed that fresh hydrogen usage and waste hydrogen discharge could be reduced by 21.3% and 67.6%. The hydrogen recovery ratio is 95.2%. It has significant economic benefits and a short payback period for Total Site Hydrogen Integration with waste hydrogen purification. The proposed method facilitates the reuse of waste hydrogen before the purification process that incurs an additional environmental footprint. In line with the Circular Economy principles, hydrogen resource is retained in the system as long as possible before discharge.     

Polyetherimide-LaNi5 composite films for hydrogen storage applications

This study investigates the preparation of polyetherimide (PEI) – LaNi₅ composites films for hydrogen storage. Prior to the polymer addition, LaNi₅ was ball-milled at different conditions (250, 350, and 450 RPM) and annealed at 500 °C for 1 h under vacuum. The composites were produced with BM-LaNi₅-350 (PEI/LaNi₅-350) and annealed BM-LaNi₅-350 (PEI/LaNi₅-350-TT). Membranes were successfully produced through solvent casting assisted by an ultrasonic bath. The particles dispersion and the film morphology did not change after hydrogenation cycles. In the H₂ sorption experiments at 43 °C and 20 bar, the films stored H₂ without incubation time; both samples reached a capacity of ~0.6 wt%. The H₂ sorption kinetics of PEI/LaNi₅-350 was comparable to that of BM-LaNi₅-350, whereas PEI/LaNi₅-350-TT presented significantly slower kinetics. LaNi₅ oxidation was hindered by PEI, showing that it can be explored to improve metal hydrides air resistance. The results demonstrated that PEI films filled with LaNi₅ are promising materials for hydrogen storage.     

Influence of the Temperature on Coccolith-Containing Systems from Emiliania huxleyi Cultivations

Thermogravimetric analysis of a coccolith-containing biogenic broth showed a three-step degradation process. According to this system behavior, the biogenic broth was heated to specific temperatures and characterized in terms of its morphology, surface chemistry, and crystallinity. The elemental and organic composition of the treated samples was also evaluated and compared to the reference material. The presented results were acquired in an effort to exploit pretreatment scenarios for such a biogenic system that would improve and support a separation process.     

运营商内部数据通信网的VPN技术

针对电信运营商在构建内部数据通信网(DCN)时遇到的各应用系统的隔离问题，详细介绍了目前几种主流的虚拟专用网(VPN)技术，并进行分析比较，最后提出了运营商内部数据通信网的VPN解决方案。     

Poly(Styrene‐Divinylbenzene) Based Media for Liquid Chromatography

The latest developments and in particular important synthetic aspects for the preparation of modern poly(styrene‐divinylbenzene) (PS‐DVB) based liquid chromatography (LC) supports are reviewed. In this context, the chemistry of particular porous and nonporous, functionalized, monolithic, coated silica and more specialized mixed organic PS‐DVB media is covered. Special consideration is given to modern approaches such as micro‐(μ)‐HPLC and coating techniques and their most important applications. Synthetic particularities relevant to the corresponding applications are outlined.     

磷矿的电选试验研究

清水沟中低品位磷矿性质复杂，嵌布粒度细，磨至-0．174mm 92．8％，通过振动—气流联合作用摩擦荷电，采用悬浮电选机经-粗-精-扫电选。可由含P2O5为24．47％的原矿获得含P2O5为30．23％。回收率为83．26％，杂质含量合格的磷精矿。     

斗南锰矿选矿厂设计中几个问题的处理

作者在斗南锰矿选矿厂设计中,针对当前锰选厂生产的经验和存在的问题,从工艺角度分别对干、湿筛分、CS-2强磁机的处理量、矿泥强磁选机的选型、以及在强磁选前设置脱除强磁性物质装置等作了分析,并提出了作者的看法。     

靖边气田分离器分离效果对比分析

从理论计算分离器处理能力和现场开展试验两方面入手，对靖边气田目前在用的不同规格分离器的分离效果进行了对比分析，通过对现场数据统计和整理，得到了靖边气田不同规格分离器合理的处理气量，给气田开发建设中分离器的选型和维护改造中分离器的调整提供了依据。     

稀土元素的分离技术

对目前稀土元素分离过程中几种常用的分离技术进行了综述，使用得较多的仍然是溶剂萃取法和离子交换法，而且新方法也在不断地出现。     

On an invariance principle for unilateral contact at a bimaterial elastic interface

This paper examines the axisymmetric elastostatic problem related to the unilateral receding contact at a pre-compressed smooth bimaterial elastic interface. The separation at the interface is caused by the action of axisymmetric stress fields of unequal magnitude, which are applied at any location of the separate halfspace regions. The analysis of the problem focuses on the determination of the zone of separation as a function of the pre-compression, the magnitudes and locations of the axisymmetric stress fields inducing the separation, and the elasticity characteristics of the halfspace regions. It is found that the radius of the separation zone can be evaluated in explicit form. In the particular instance when the loadings applied at the surface of the halfspace regions are equal in magnitude and distribution, the analysis reveals that the radius of the separation zone is independent of the elasticity properties of the halfspace regions and can be evaluated in exact closed form.