浅谈延迟焦化装置露天栈桥的设计

根据延迟焦化装置露天栈桥的工程设计实践,围绕一炉两塔(一个加热炉两个焦炭塔)的焦化装置,分析了露天栈桥设计中的要点及难点,对其在平面布置、基础安排和吊车梁选型等设计方面做一些介绍和论述。     

规整填料和新型塔板设计参数选取的质疑及分析

笔者指出了目前规整填料和新型塔板设计计算中若干尚未完全解决的、有争议或值得进一步完善的设计参数。如:规整填料的每米理论板数、最小液体喷淋密度、最小气体空塔动能因子、新型塔板开孔率等,并提出了具体的设计方案供与同行切磋。     

双塔脱丙烷工艺技术

对扬子乙烯装置双塔脱丙烷系统低压塔液泛、高压塔再沸器堵塞等问题进行了技术分析,提出了工艺流程修改方案,完善了双塔脱丙烷技术,对同类装置有参考价值。     

Two‐phase production of cyclohexene and cyclooctene oxides in water as an approach to pollution prevention

Liquid–liquid two‐phase epoxidation from cyclohexene and cyclooctene in aqueous potassium peroxymonosulfate (commercially available as Oxone^®) solution was studied as an application in pollution prevention. To avoid potential emissions of volatile organic compounds an aqueous solution was employed to replace the usual chlorinated solvents used in epoxide production. A droplet column reactor and stirred tank reactor were used to investigate two‐phase synthesis of epoxide. An aqueous Oxone^® solution was used to oxidize a dispersion of alkene droplets and form epoxide. The study of aqueous epoxidation in both reactors showed that the epoxidation of alkenes can be represented as a first order reaction with respect to alkene. The salting out effect of Oxone^® concentration was studied in both reactors and found to be very similar at optimal conditions. In comparing the two reactors, it was found that the droplet column reactor produces larger quantities of product per unit reactor volume for the same reaction time. The objective of this study is to provide an alternative reactor design and synthesis route that can meet pollution prevention goals. Copyright © 2004 Society of Chemical Industry     

Active set truncated-Newton algorithm for simultaneous optimization of distillation column

An active set truncated-Newton algorithm (ASTNA) is proposed to solve the large-scale bound constrained sub-problems. The global convergence of the algorithm is obtained and two groups of numerical experiments are made for the various large-scale problems of varying size. The comparison results between ASTNA and the subspace limited memory quasi-Newton algorithm and between the modified augmented Lagrange multiplier methods combined with ASTNA and the modified barrier function method show the stability and effectiveness of ASTNA for simultaneous optimization of distillation column.     

二甲基甲酰胺溶剂回收装置焦油塔减压改造方案

实验研究了纯二甲基甲酰胺(DMF)水溶液和焦油塔进料在不同减压压力条件下的水解变化规律,确定了焦油塔减压操作的适宜操作压力和减压操作方案。     

如何延长高压液相色谱柱的使用寿命

分析了液相色谱柱失效的诸多现象和原因，并论述了极性溶剂冲洗法等一些使色谱柱恢复活性的方法。     

异形柱柱头混凝土连续托梁分次置换技术

通过某工程异形柱头混凝土置换实例,介绍了连续托梁分次置换技术的设计计算、施工方法和技术措施等。     

异形柱框架结构设计方法分析与参数控制

近年来,异形柱框架结构(框轻结构体系),因其能较好地满足建筑使用上和结构性能上的要求,而逐步得到了推广应用,并被列为建设部首批住宅建设新技术推荐目录。但异形柱框架结构设计目前还没有可依据使用的国家标准和行业标准。本文根据对江苏省地方标准《钢筋混凝土异形柱框架结构技术规程》(DB32/512-2002)的理解,结合笔者设计实践经验,提出个人看法,供同行参考。