首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   22376篇
  免费   2280篇
  国内免费   365篇
电工技术   86篇
综合类   503篇
化学工业   6033篇
金属工艺   712篇
机械仪表   249篇
建筑科学   435篇
矿业工程   46篇
能源动力   173篇
轻工业   13803篇
水利工程   40篇
石油天然气   551篇
武器工业   53篇
无线电   348篇
一般工业技术   1470篇
冶金工业   243篇
原子能技术   115篇
自动化技术   161篇
  2024年   303篇
  2023年   636篇
  2022年   1357篇
  2021年   1521篇
  2020年   1258篇
  2019年   1245篇
  2018年   1176篇
  2017年   1175篇
  2016年   1190篇
  2015年   1085篇
  2014年   1172篇
  2013年   1451篇
  2012年   1466篇
  2011年   1568篇
  2010年   989篇
  2009年   928篇
  2008年   829篇
  2007年   817篇
  2006年   725篇
  2005年   562篇
  2004年   501篇
  2003年   516篇
  2002年   464篇
  2001年   288篇
  2000年   254篇
  1999年   197篇
  1998年   235篇
  1997年   169篇
  1996年   129篇
  1995年   132篇
  1994年   87篇
  1993年   82篇
  1992年   68篇
  1991年   73篇
  1990年   65篇
  1989年   35篇
  1988年   22篇
  1987年   30篇
  1986年   20篇
  1985年   31篇
  1984年   41篇
  1983年   19篇
  1982年   32篇
  1981年   9篇
  1980年   30篇
  1979年   5篇
  1978年   9篇
  1977年   5篇
  1975年   9篇
  1951年   6篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
We investigated the effect of various amounts of liquid phase on microstructure development during sintering and the resulting magnetic permeability of MnZn ferrite (MZF) samples. Our results revealed that the microstructure and the final magnetic permeability depend on the thickness of the liquid-phase film during sintering. The solution-reprecipitation (S-R) process, which is associated with an intensive microstructure development in MZF, starts when a continuous liquid-phase film of critical thickness δo, which wets the MZF grains, is formed. The solid-state sintering that takes place before the formation of the continuous liquid-phase film is essential for the final microstructure of MZF.  相似文献   
2.
Non‐isothermal processing of lignocellulosic materials in aqueous media (autohydrolysis reaction) under mild conditions leads to solutions containing valuable chemicals (oligosaccharides, sugars and acetic acid) and other, undesired, compounds (belonging to the extractive and acid‐soluble lignin fractions) which have to be removed in further purification treatments. Liquors obtained by non‐isothermal autohydrolysis of Eucalyptus globulus wood and corncobs under a variety of operational conditions were extracted with ethyl acetate in order to remove non‐saccharide components, and the suitability of the fraction dissolved in the organic phase was assayed for possible utilisation as an antioxidant. The yield and antioxidant activity of ethyl acetate extracts (measured by the α,α‐diphenyl‐β‐picrylhydrazyl (DPPH) radical scavenging capacity) showed a strong dependence on the autohydrolysis conditions. The antioxidant activity of extracts obtained under selected operational conditions compared well with synthetic antioxidants. © 2003 Society of Chemical Industry  相似文献   
3.
本文运用一典型的人工神经网络模型─“反向传播”模型,对高氧化态(Ⅱ─Ⅳ)三核金属簇合物的构型分布进行了分析,得到了较好的分类、预报结果为化合物结构分析提供了新的工具。  相似文献   
4.
ABSTRACT: The traditional small-scale production of boucané, a cured smoked pork-belly product from Réunion, involves several unit operations that are performed in a single step. The aim of this study was to highligh the impact of 4 unit operations (salting, drying, cooking, and smoking) on stability, color, and flavor development in processed pork. These characateristics are the 3 main criteria of boucané's quality. Mass transfer, color, and volatile compounds were measured, analyzed, and compared in 4 products. Results indicated that a major quantity of volatile compounds detected in the processed meat were derived from the smoking process. Color variations were mainly explained by muscle pigment modification due to the cooking process, and by the input of volatile compounds of smoke.  相似文献   
5.
LiFePO4 is a potential candidate for the cathode material of the lithium secondary batteries. A co-precipitation method was adopted to prepare LiFePO4 because it is simple and cheap. Nitrogen gas was needed to prevent oxidation of Fe2+ in the aqueous solution. The co-precipitated precursor shows the high reactivity with the reductive gas, and the single phase of LiFePO4 is successfully synthesized with the aid of carbon under less reductive conditions. LiFePO4 fine powder prepared by co-precipitation method shows high rate capability, impressive specific capacity and cycle property.  相似文献   
6.
7.
BACKGROUND: In the framework of biological processes used for waste gas treatment, the impact of the inoculum size on the start‐up performance needs to be better evaluated. Moreover, only a few studies have investigated the behaviour of elimination capacity and biomass viability in a two‐phase partitioning bioreactor (TPPB) used for waste gas treatment. Lastly, the impact of ethanol as a co‐substrate remains misunderstood. RESULTS: Firstly, no benefit of inoculation with a high cellular density (>1.5 g L?1) was observed in terms of start‐up performance. Secondly, the TPPB was monitored for 38 days to characterise its behaviour under several operational conditions. The removal efficiency remained above 63% for an inlet concentration of 7 g isopropylbenzene (IPB) m?3 and at some time points reached 92% during an intermittent loading phase (10 h day?1), corresponding to a mean elimination capacity of 4 × 10?3 g L?1 min?1 (240 g m?3 h?1) for a mean IPB inlet load of 6.19 × 10?3 g L?1 min?1 (390 g m?3 h?1). Under continuous IPB loading, the performance of the TPPB declined, but the period of biomass acclimatisation to this operational condition was shorter than 5 days. The biomass grew to approximately 10 g L?1 but the cellular viability changed greatly during the experiment, suggesting an endorespiration phenomenon in the bioreactor. It was also shown that simultaneous degradation of IPB and ethanol occurred, suggesting that ethanol improves the biodegradation process without causing oxygen depletion. CONCLUSION: A water/silicone oil TPPB with ethanol as co‐substrate allowed the removal of a high inlet load of IPB during an experiment lasting 38 days. Copyright © 2008 Society of Chemical Industry  相似文献   
8.
镁钴铝类水滑石催化合成安息香甲醚   总被引:1,自引:0,他引:1  
采用共沉淀法制备了镁钴铝类水滑石化合物(MgCoAl-HTLcs),并用 X 射线衍射、扫描电子显微镜、NH_3程序升温脱附等方法对 MgCoAl-HTLcs 进行了表征,并以 MgCoAl-HTLcs 为催化剂催化苯甲醛与甲醇反应合成安息香甲醚,研究了n(Mg):n(Co):n(Al)、催化剂用量、原料配比、反应温度、反应时间对合成反应的影响。表征结果显示,MgCoAl-HTLcs 的晶相完整,表面主要为弱酸、弱碱性。催化合成安息香甲醚的适宜条件为:MgCoAl-HTLcs 催化剂用量0.10 g(约为原料总质量的0.23%),n(Mg):n(Co):n(Al)=0.4:1.6:1.0,V(苯甲醛):V(甲醇)=3:50,反应温度50℃,反应时间150 min。在此条件下,苯甲醛的平衡转化率达77.49%,安息香甲醚选择性接近100%。为洁净合成安息香甲醚开辟了一条新的途径。  相似文献   
9.
Mg-Si基热电化合物的研究现状   总被引:1,自引:0,他引:1  
重点综述了Mg-Si基热电化合物的基本特性,该体系热电材料的制备方法与掺杂改性的研究进展,并提出了要重点解决的问题。  相似文献   
10.
Aqueous molal solutions of xylose and lysine (initial pH 4–9) were refluxed either with control of the pH at 5–0 or without pH control (final pH 2–6). Analysis by gas chromatography (GC) and GC-mass spectrometry resulted in the identification of 58 and 28 compounds, respectively, from the two systems. Furans were the main reaction products in both systems and 2-furfural alone comprised 522 and 999 g kg?1 of the volatiles, respectively, from the systems with final pH values of 5–0 and 2–6. Maintaining the pH at 5–0 resulted in a higher yield and greater numbers of nitrogen-containing compounds, and monocyclic pyrroles, pyridines and 2,3-dihydro-l H-pyrrolizines were identified only in that system. Aliphatic compounds, alicyclic compounds, benzene derivatives. l-(2–furfuryl)pyrroles and pyrazines were also identified. This investigation is the first report of the formation of 2.3-dihydro-l H-pyrrolizines in a model system containing lysine as the amino compound; a possible mechanism is proposed.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号