Electro-copolymerisation of indene and styrene

Electroinitiated cationic copolymerisation of indene and styrene was investigated by constant potential electrolysis. Effects of copolymerisation potential and temperature on the copolymer composition and the reactivity ratios are discussed. The reactivity ratios of the monomers were calculated according to the integrated Lewis-Mayo equation.     

Copolymerization of bromophenylmaleimide with ethyl or butyl methacrylate

N‐p‐Bromophenylmaleimide (BrPMI) does not polymerize in solution by conventional free radical mechanism. However, it readily polymerized in bulk when mixed with a free radical initiator and heated in a microwave oven for 7–8 min. Copolymerization of ethyl methacrylate or butyl methacrylate with BrPMI was conducted in dioxane. The copolymers were characterized by IR and ¹H NMR spectroscopy and gel permeation chromatography. The monomer reactivity ratios were calculated by a non‐linear least‐square analysis. Thermal analysis indicated a great improvement in thermal stability of the copolymers compared with the methacrylate homopolymers. BrPMI was also polymerized in bulk in the DSC pan, which allowed the calculation of the activation energy of its polymerization. Copyright © 2003 Society of Chemical Industry     

Cost-Benefit Analysis of Residential Energy-Efficiency Upgrades in Phoenix, Arizona

With worldwide energy consumption rising, there is a need to reduce energy use of the housing stock. While this general idea is well-known, there is an overwhelming amount of product data and manufacturers claims through which the homebuilder or designer must sort to make informed selections of energy-efficient upgrades. The main objective of this research was to identify cost effective–energy efficient upgrades from a group of 16 commonly available choices, and rank them according to the most beneficial for the least cost. This study was conducted in Phoenix, Arizona, and included a sample of 30 production-style homes typical of the Phoenix metropolitan area. Energy-simulation software was used to perform energy evaluations and derive the benefits of each upgrade. The cost of each upgrade was obtained from a database of national average costs and from a local context. Differences in the selection of beneficial upgrades vary dramatically with the source of the cost information. This research provides a generic methodology that can be used by builders and designers to select appropriate energy-efficient upgrades for a given geographic area that will provide high operating benefits relative to the amount of capital investment.     

Effect of plate aspect ratio on the recovery of deuterium from water-isotope mixture in flat-plate thermal diffusion columns with transverse sampling streams

The optimal plate aspect ratios for the best recovery of deuterium from water-isotope mixture in flat-plate thermal diffusion columns with transverse sampling streams have been determined. The maximum recovery and maximum production rate are achieved without changing the total expenditure, while the design with minimum plate surface area results in minimizing the total expense.     

高厚径比盲孔电镀

盲孔能够大大的增加板的密度,从而减小板面积。介绍了有关高厚径比盲孔电镀的有关工艺,从激光钻孔、金属化孔和电镀几个方面对孔径4mil以上的盲孔电镀进行了研究。     

APPLICATION OF SITE-SPECIFIC NATURAL ISOTOPE FRACTIONATION (SNIF-NMR) OF HYDROGEN TO THE CHARACTERIZATION OF EUROPEAN BEERS

More than one hundred samples of European beers have been investigated by the new SNIF-NMR method which is based on 2H NMR at the natural abundance level and enables site-specific natural isotope fractionation factors in ethanol to be determined. The relative (R) and absolute (D/H)_i, parameters are shown to be characteristic of the country where the beers are brewed and the observed variations are explained in terms of cereal composition, water resource, and manufacturing processing (fermentation, yeast, temperature cycle). These new parameters find analytical and mechanistic applications in the identification of a beer and in the investigation of a fermentation process.