全文获取类型
收费全文 | 1014篇 |
免费 | 111篇 |
国内免费 | 36篇 |
专业分类
电工技术 | 10篇 |
综合类 | 58篇 |
化学工业 | 548篇 |
金属工艺 | 28篇 |
机械仪表 | 17篇 |
建筑科学 | 2篇 |
矿业工程 | 4篇 |
能源动力 | 10篇 |
轻工业 | 169篇 |
石油天然气 | 46篇 |
武器工业 | 2篇 |
无线电 | 59篇 |
一般工业技术 | 195篇 |
冶金工业 | 9篇 |
原子能技术 | 3篇 |
自动化技术 | 1篇 |
出版年
2024年 | 4篇 |
2023年 | 20篇 |
2022年 | 18篇 |
2021年 | 28篇 |
2020年 | 38篇 |
2019年 | 38篇 |
2018年 | 40篇 |
2017年 | 44篇 |
2016年 | 41篇 |
2015年 | 40篇 |
2014年 | 48篇 |
2013年 | 67篇 |
2012年 | 87篇 |
2011年 | 60篇 |
2010年 | 57篇 |
2009年 | 53篇 |
2008年 | 38篇 |
2007年 | 44篇 |
2006年 | 39篇 |
2005年 | 44篇 |
2004年 | 51篇 |
2003年 | 47篇 |
2002年 | 31篇 |
2001年 | 17篇 |
2000年 | 19篇 |
1999年 | 13篇 |
1998年 | 17篇 |
1997年 | 7篇 |
1996年 | 10篇 |
1995年 | 10篇 |
1994年 | 9篇 |
1993年 | 19篇 |
1992年 | 11篇 |
1991年 | 13篇 |
1990年 | 4篇 |
1989年 | 5篇 |
1988年 | 2篇 |
1986年 | 1篇 |
1985年 | 7篇 |
1984年 | 5篇 |
1983年 | 7篇 |
1982年 | 7篇 |
1981年 | 1篇 |
排序方式: 共有1161条查询结果,搜索用时 15 毫秒
1.
以硅渣和玻璃粉为原料,采用粉体直接烧结法制备多孔材料,研究了烧结温度(700~900℃)、烧结时间(15~120min)和升温速率(10~100℃·min^-1)对多孔材料表观密度、气孔率、物相组成、抗压强度的影响。结果表明:气孔结构均匀性随烧结温度的升高而降低;表观密度随烧结温度的升高先减小后增大,随保温时间的延长而增大,随升温速率的增大而减小,气孔率的变化趋势与表观密度的相反;多孔材料的主要物相为玻璃相和硅、SiC、SiO2、Ca2Al2SiO7等结晶相,且结晶度随烧结温度的升高而降低;抗压强度随烧结温度的升高呈先增大后减小的趋势;当烧结温度为750℃,升温速率为30℃·min^-1,烧结时间为30 min时,多孔材料的主晶相为硅和Ca2Al2SiO7,抗压强度最大(1.60MPa),表观密度为0.43g·cm^-3,气孔率为80%。 相似文献
2.
Cellulose dissolved in ionic liquid (1‐(carboxymethyl)pyridinium chloride)/water (60/40 w/w) mixture is regenerated in various non‐solvents, namely water, ethanol, methanol and acetone, to gain more insight into the contribution of non‐solvent medium to the morphology of regenerated cellulose. To this end, the initial and regenerated celluloses were characterized with respect to crystallinity, thermal stability, chemical structure and surface morphology using wide‐angle X‐ray diffraction, thermogravimetric analysis, Fourier transform infrared spectroscopy and scanning electron microscopy. According to the results, regardless of non‐solvent type, all regenerated samples have the same chemical structure and lower crystallinity in comparison to the initial cellulose, making them a promising candidate for efficient biofuel production based on enzymatic hydrolysis of cellulose. The reduction in crystallinity of regenerated samples is explained based on the potential of the non‐solvent to break the hydrogen bonds between cellulose chains and ionic liquid molecules as well as the affinity of water and non‐solvent which can be evaluated based on Hansen solubility parameter. The latter also determines the phase‐separation mechanism during the regeneration process, which in turn affects surface morphology of the regenerated cellulose. The pivotal effect of regenerated cellulose crystallinity on its thermal stability is also demonstrated. Regenerated cellulose with lower crystallinity is more susceptible to molecular rearrangement during heating and hence exhibits enhanced thermal stability. © 2019 Society of Chemical Industry 相似文献
3.
Here we show a general method to improve the crystallinity of carbon nitride nanosheets by using melamine crystals as reactants for the high temperature synthesis. Additionally, the crystals were calcined in a sealed ampoule, which provides a pressurized environment, yielding crystalline carbon nitride nanosheets that display altered morphology and photophysical properties compared to the reference materials. Electronic microscopy, optical and photoelectrochemical measurements prove the modifications of parameters such like band structure, charge recombination or inter-layer distance. The new growth strategy presented here opens many opportunities for the design of crystalline materials with tailored properties for different applications. 相似文献
4.
5.
Polymer crystallization under flow was investigated because final properties of polymers strongly depend on the crystalline structure and morphology formed during processing. In-situ synchrotron WAXS and SAXS were used to investigate the structure formation and morphological developments during quiescent and shear-induced crystallization of iPP with 3 different concentrations (0.01, 0.03 and 0.1 wt%) of β-nucleating agent. Under quiescent conditions, a high β-content was obtained at all those concentrations indicating the high β-nucleating efficiency of the nucleating agent. After application of shear, the β-nucleating ability at small concentration was retained, while at larger concentrations it was strongly retarded. Furthermore, the addition of β-nucleating agent was beneficial for the molecular alignment during processing, the anisotropic particles of β-nucleating agent were much more effective to align the molecular chains in the flow direction compared to isotropic ones. A crystallization scheme for the iPP β-nucleating agent under shear was proposed. 相似文献
6.
7.
以MgCl_2溶液作为电解质,利用电化学沉积方法制备了Mg(OH)_2晶体.研究了电流密度、MgCl_2浓度、沉积时间等因素对沉积产物生长速率、结晶度、微观形貌和孔径分布的影响.结果表明:上述各因素均不影响沉积产物(Mg(OH)_2)的物相组成;电流密度的增大加快了Mg(OH)_2的生长速率,但同时降低了Mg(OH)_2晶体的结晶度,增大了产物中的孔隙率与大孔体积;MgCl_2浓度对Mg(OH)_2结晶度及晶体颗粒大小的影响较小,存在使Mg(OH)_2生长速率达到最大值的最佳MgCl_2浓度;Mg(OH)_2质量随沉积时间增加呈线性增长,生长速率基本维持恒定. 相似文献
8.
通过差示扫描量热仪(DSC)、X射线衍射仪(XRD)对纯聚偏氟乙烯(PVDF)和PVDF/聚甲基丙烯酸甲酯(PMMA)共混物在不同降温速率下的非等温结晶行为和晶体结构进行表征和分析,并采用Jeziorny法和莫志深法研究了各组样品的非等温结晶动力学。结果表明,PMMA含量过多(PVDF/PMMA质量比为6/4和5/5)会完全抑制PVDF结晶;对于纯PVDF和可结晶的共混物(PVDF/PMMA质量比为9/1、8/2、7/3)样品,随着PMMA含量的增加,共混物结晶温度先升高后降低,结晶速率先少许增大后减小,说明少量PMMA起异相成核作用,可促进共混物结晶,而大量PMMA可明显阻碍分子重排,抑制其结晶;PMMA的加入可促进共混物晶体结构向低维转变;共混物晶体结构主要是α晶型,PMMA含量的增加不改变共混物的晶型,且使共混物结晶度先增大后减小。 相似文献
9.
采用差示扫描量热仪研究了滑石粉原位聚合对聚酯热熔胶非等温结晶性能的影响,并用Takhor方程和莫志深非等温结晶动力学新方程处理所得数据。结果表明:滑石粉原位聚合显著促进了聚酯热熔胶的结晶,提高了结晶速率,表现在结晶温度和结晶活化能大幅提高,当降温速率分别为5,10℃/min时,半结晶时间缩短50%以上。动力学分析表明:莫志深方程适合描述聚酯热熔胶的非等温结晶过程,在达到相同相对结晶度时,加入滑石粉的聚酯热熔胶所需降温速率更小,缩短了热熔胶涂覆后的冷却固化时间。 相似文献
10.
Low‐Temperature Processable High‐Performance Electrochemically Deposited p‐Type Cuprous Oxides Achieved by Incorporating a Small Amount of Antimony 下载免费PDF全文
Seung Ki Baek Yong Hun Kwon Jae Hui Shin Ho Seong Lee Hyung Koun Cho 《Advanced functional materials》2015,25(32):5214-5221
The development of an electrochemically robust method for the low‐temperature deposition of cuprous oxide (Cu2O) thin films with reliable and conductive p‐type characteristics could yield breakthroughs in earth abundant and ecofriendly all oxide‐based photoelectronic devices. The incorporation of the group‐V element antimony (Sb) in the solution‐based electrodeposition process has been investigated. A small amount of Sb (1.2 at%) in the Cu2O resulted in rapid nucleation and coalescence at the initial stage of electrochemical reaction, and finally made the surface morphology smooth in 2D. The growth behavior changed due to Sb addition and produced a strong diffraction intensity, single‐domain‐like diffraction patterns, and low angle tilt boundaries in the Cu2O:Sb film, implying extremely improved crystallinity. As a result, these films exhibited extraordinary optical transmittance and band‐to‐band photoluminescence emission as well as higher electrical conductivity. The Cu/Cu2O:Sb Schottky diode showed good rectifying characteristics and more sensible photoresponsibility. 相似文献