全文获取类型
收费全文 | 4181篇 |
免费 | 496篇 |
国内免费 | 127篇 |
专业分类
电工技术 | 84篇 |
技术理论 | 1篇 |
综合类 | 279篇 |
化学工业 | 1520篇 |
金属工艺 | 112篇 |
机械仪表 | 103篇 |
建筑科学 | 397篇 |
矿业工程 | 196篇 |
能源动力 | 155篇 |
轻工业 | 1010篇 |
水利工程 | 40篇 |
石油天然气 | 132篇 |
武器工业 | 6篇 |
无线电 | 48篇 |
一般工业技术 | 275篇 |
冶金工业 | 363篇 |
原子能技术 | 26篇 |
自动化技术 | 57篇 |
出版年
2024年 | 30篇 |
2023年 | 115篇 |
2022年 | 125篇 |
2021年 | 191篇 |
2020年 | 169篇 |
2019年 | 131篇 |
2018年 | 116篇 |
2017年 | 127篇 |
2016年 | 190篇 |
2015年 | 166篇 |
2014年 | 334篇 |
2013年 | 320篇 |
2012年 | 350篇 |
2011年 | 375篇 |
2010年 | 273篇 |
2009年 | 279篇 |
2008年 | 183篇 |
2007年 | 225篇 |
2006年 | 211篇 |
2005年 | 190篇 |
2004年 | 156篇 |
2003年 | 133篇 |
2002年 | 125篇 |
2001年 | 87篇 |
2000年 | 34篇 |
1999年 | 45篇 |
1998年 | 29篇 |
1997年 | 25篇 |
1996年 | 12篇 |
1995年 | 16篇 |
1994年 | 7篇 |
1993年 | 7篇 |
1992年 | 5篇 |
1991年 | 4篇 |
1990年 | 3篇 |
1989年 | 2篇 |
1988年 | 2篇 |
1987年 | 1篇 |
1986年 | 2篇 |
1985年 | 2篇 |
1984年 | 2篇 |
1983年 | 1篇 |
1982年 | 3篇 |
1981年 | 1篇 |
排序方式: 共有4804条查询结果,搜索用时 15 毫秒
1.
In the chemical industry large amounts of saline wastewater occur. Its disposal into rivers is a considerable burden to the ecosystem. To strive for a circular economy and enable a viable raw material recycling, energy-efficient concentration processes are requisite. High-pressure reverse osmosis meets this criterion, but its industrial application demands suitable membrane elements that withstand the exceptional operation conditions and provide sufficient performance. Hence, new requirements regarding the design of spiral-wound elements arise. To identify those, specific performance-limiting effects need a better understanding. 相似文献
2.
Thea Lyseid Authen Andreas Wilden Jenny Halleröd Dimitri Schneider Fabian Kreft Giuseppe Modolo 《溶剂提取与离子交换》2021,39(1):1-17
ABSTRACT Studies have been performed with the purpose of determining the optimal solvent composition of a Chalmers grouped actinide extraction (CHALMEX) solvent for the selective co-extraction of transuranic elements in a novel Grouped ActiNide EXtraction (GANEX) process. The solvent is composed of 6,6’-bis(5,5,8,8-tetramethyl-5,6,7,8-tetrahydro-benzo-[1,2,4]-triazin-3-yl)-[2,2’]-bipyridine (CyMe4-BTBP) and tri-n-butyl phosphate (TBP) in phenyl trifluoromethyl sulfone (FS-13). The performance of the system has been shown to significantly depend on the ratios of the two extracting agents and the diluent to one another. Furthermore, the performance of the determined optimal solvent (10 mM CyMe4-BTBP in 30% v/v TBP and 70% v/v FS-13) on various simulated PUREX raffinate solutions was tested. It was found that the solvent extracts all transuranic elements with high efficiency and good selectivity with regard to most other elements (fission products/activation products) present in the simulated PUREX raffinate solutions. Moreover, the solvent was found to extract a significant amount of acid. Palladium, silver, and cadmium were co-extracted along with the TRU-radionuclides, which has also been observed in other similar CHALMEX systems. The extraction of plutonium and uranium was preserved for all tested simulated PUREX raffinate solutions compared to experiments using trace amounts. 相似文献
3.
Eitan Oksenberg Calvin Fai Ivan G. Scheblykin Ernesto Joselevich Eva L. Unger Thomas Unold Charles Hages Aboma Merdasa 《Advanced functional materials》2021,31(22):2010704
Understanding energy transport in metal halide perovskites is essential to effectively guide further optimization of materials and device designs. However, difficulties to disentangle charge carrier diffusion, photon recycling, and photon transport have led to contradicting reports and uncertainty regarding which mechanism dominates. In this study, monocrystalline CsPbBr3 nanowires serve as 1D model systems to help unravel the respective contribution of energy transport processes in metal-halide perovskites. Spatially, temporally, and spectrally resolved photoluminescence (PL) microscopy reveals characteristic signatures of each transport mechanism from which a robust model describing the PL signal accounting for carrier diffusion, photon propagation, and photon recycling is developed. For the investigated CsPbBr3 nanowires, an ambipolar carrier mobility of μ = 35 cm2 V−1 s−1 is determined, and is found that charge carrier diffusion dominates the energy transport process over photon recycling. Moreover, the general applicability of the developed model is demonstrated on different perovskite compounds by applying it to data provided in previous related reports, from which clarity is gained as to why conflicting reports exist. These findings, therefore, serve as a useful tool to assist future studies aimed at characterizing energy transport mechanisms in semiconductor nanowires using PL. 相似文献
4.
含镓电子废弃物通常可分为废弃电子产品及其生产过程中产生的含镓废料两类,由于伴生重金属、易燃有机物等有害物质而具有环境和资源的双重属性,其资源循环近年来受到广泛关注。镓在电子废弃物中主要以化合物形式赋存,具有伴生元素多、物理化学性质稳定等特征。本工作系统梳理了含镓电子废弃物回收处理现状,总结了湿法冶金、火法冶金及生物冶金等技术在回收不同种类的含镓电子废弃物的应用,并通过对比不同物理化学属性的含镓物料使用回收技术以及分离、净化方式的不同,指出了目前现存的回收含镓电子废料的技术问题及未来的发展方向。 相似文献
5.
Peng Li Haibin Jiang Ariel Barr Zhichu Ren Rui Gao Hua Wang Weiwei Fan Meifang Zhu Guiyin Xu Ju Li 《Advanced functional materials》2021,31(51):2105845
Mercury, lead, and cadmium are among the most toxic and carcinogenic heavy metal ions (HMIs), posing serious threats to the sustainability of aquatic ecosystems and public health. There is an urgent need to remove these ions from water by a cheap but green process. Traditional methods have insufficient removal efficiency and reusability. Structurally robust, large surface-area adsorbents functionalized with high-selectivity affinity to HMIs are attractive filter materials. Here, an adsorbent prepared by vulcanization of polyacrylonitrile (PAN), a nitrogen-rich polymer, is reported, giving rise to PAN-S nanoparticles with cyclic π-conjugated backbone and electronic conductivity. PAN-S can be coated on ultra-robust melamine (ML) foam by simple dipping and drying. In agreement with hard/soft acid/base theory, N- and S-containing soft Lewis bases have strong binding to Hg2+, Pb2+, Cu2+, and Cd2+, with extraordinary capture efficiency and performance stability. Furthermore, the used filters, when collected and electrochemically biased in a recycling bath, can release the HMIs into the bath and electrodeposit on the counter-electrode as metallic Hg0, Pb0, Cu0, and Cd0, and the PAN-S@ML filter can then be reused at least 6 times as new. The electronically conductive PAN-S@ML filter can be fabricated cheaply and holds promise for scale-up applications. 相似文献
6.
Zi-Zi Li Lei Lei Min-Xi Huo Zi-Rui Liu Xin-Quan Yang Yu-Lin Wang Yang Yuan 《International Journal of Food Science & Technology》2021,56(1):269-277
The objective of this paper was to investigate the complex of grape seed procyanidins (GSP) with zein hydrolysate (ZH). The interaction was determined using isothermal titration calorimetry (ITC) and fluorescence spectroscopy. The particle size, ζ-potential, scanning electronic microscopy (SEM) and stability test of the ZH-GSP complex were measured. The results of ITC, particle size and SEM suggested that there was a hydrogen bond-dominated interaction between GSP and ZH, and the ZH-GSP complex presented as a spherical shape with particle size of 234 nm, polydispersity index of 0.11 and ζ-potential of −46.4 mV. The results of the fluorescence spectroscopy showed that the fluorescence quenching effect of GSP on ZH was GSP concentration-dependent and the quenching process was mainly static quenching. The ZH-GSP complex had better physical stability in aqueous solution, and their solution was more stable than GSP solution under illumination and high-temperature treatment at 75°C. 相似文献
7.
8.
以某典型废玻璃回收厂区作为研究对象, 监测和分析了车间及厂区内部的噪声强度、空气颗粒物(PM2.5、PM10) 浓度等环境指标, 点位布设涵盖了车间入口、人工分拣、物料筛分、破碎、干法清洗等关键工艺环节; 其次, 解析了空气颗粒物的组分及形貌特征, 并对其在厂区及车间内部的时空分布特征进行了研究; 此外, 利用噪声控制模型模拟并分析了隔声罩对噪声的控制作用。结果表明, 生产车间中工作态的空气颗粒物浓度显著高于非工作态, 其中干法清洗区浓度最高, 其PM2.5 浓度为3.725 mg/m3, PM10浓度为4.055 mg/m3; 噪声监测结果显示生产车间内噪声强度较高, 达到99.5 dB, 而引入隔声罩后噪声强度可降至67 dB, 结果表明, 隔声罩可有效控制频率为125~1 000 Hz 的噪声。该研究可为废玻璃的绿色、高效回收处置提供理论基础和实践经验。 相似文献
9.
10.
Pamela Rodrigues Passos Severino Natália Ferreira Braga Guilherme Ferreira de Melo Morgado Juliano Marini Orestes Ferro Fábio Roberto Passador Larissa Stieven Montagna 《应用聚合物科学杂志》2021,138(24):50559
Prepreg is a pre-impregnated composite fiber where a thermoset polymer matrix material is present. Before being used, these materials are kept at low temperatures and have a low-density polyethylene (LDPE) film for your protection. The increase in the use of structural composites based on prepregs causes an increase in the amount of protective LDPE film. This material is usually discarded or incinerated and can cause great damage to the environment. Thus, the present work aimed to study the feasibility of recycling up to 100% of protective LDPE (rLDPE) to develop blends-based nanocomposites with rLDPE/virgin LDPE (60/40, 70/30, 80/20, 90/10 and 100/0) with the addition of 5 wt% of compatibilizer agent (maleic anhydride grafted LDPE, LDPE-g-MA), and 1 wt% of bentonite (BNT) using a co-rotational twin-screw extruder, followed by hot pressing in a hydropneumatic press and die-cutting. Water absorption test, thermal aging resistance, morphological characterization by scanning electron microscopy, mechanical properties by Izod impact strength and tensile tests, and differential scanning calorimetry were performed. By the results, it was possible to verify the viability of 100% of the recycling of rLDPE. The results showed a good distribution of 1 wt% of BNT in the matrix, better mechanical properties when compared with virgin LDPE. Furthermore, the thermal properties, water absorption test, and thermal aging resistance showed no statistical differences between the samples. These results confirm the effectiveness and the environmental gain in the use of the recycled material. 相似文献