全文获取类型
收费全文 | 14709篇 |
免费 | 2805篇 |
国内免费 | 1606篇 |
专业分类
电工技术 | 517篇 |
综合类 | 778篇 |
化学工业 | 2454篇 |
金属工艺 | 295篇 |
机械仪表 | 2003篇 |
建筑科学 | 523篇 |
矿业工程 | 181篇 |
能源动力 | 354篇 |
轻工业 | 6338篇 |
水利工程 | 185篇 |
石油天然气 | 414篇 |
武器工业 | 83篇 |
无线电 | 801篇 |
一般工业技术 | 1248篇 |
冶金工业 | 1768篇 |
原子能技术 | 444篇 |
自动化技术 | 734篇 |
出版年
2024年 | 35篇 |
2023年 | 345篇 |
2022年 | 718篇 |
2021年 | 1134篇 |
2020年 | 852篇 |
2019年 | 925篇 |
2018年 | 891篇 |
2017年 | 828篇 |
2016年 | 959篇 |
2015年 | 830篇 |
2014年 | 1156篇 |
2013年 | 1303篇 |
2012年 | 1227篇 |
2011年 | 1196篇 |
2010年 | 769篇 |
2009年 | 738篇 |
2008年 | 604篇 |
2007年 | 778篇 |
2006年 | 658篇 |
2005年 | 523篇 |
2004年 | 426篇 |
2003年 | 381篇 |
2002年 | 286篇 |
2001年 | 188篇 |
2000年 | 184篇 |
1999年 | 149篇 |
1998年 | 146篇 |
1997年 | 116篇 |
1996年 | 109篇 |
1995年 | 115篇 |
1994年 | 75篇 |
1993年 | 61篇 |
1992年 | 55篇 |
1991年 | 46篇 |
1990年 | 39篇 |
1989年 | 37篇 |
1988年 | 23篇 |
1987年 | 15篇 |
1986年 | 17篇 |
1985年 | 16篇 |
1984年 | 17篇 |
1983年 | 8篇 |
1982年 | 41篇 |
1981年 | 63篇 |
1980年 | 25篇 |
1979年 | 5篇 |
1976年 | 1篇 |
1973年 | 1篇 |
1972年 | 1篇 |
1959年 | 3篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
醌类化合物是PM2.5中的一类有害物质。本研究建立了纸喷雾离子化衍生质谱法快速测定PM2.5中的醌类污染物。通过衍生化反应在醌化合物中引入氨基,提高醌在纸喷雾中的离子化效率。随后对衍生化试剂种类、电压、喷雾溶剂种类等反应条件进行优化。在最优实验条件下,采用内标法定量分析1,4-苯醌、甲基对苯醌、1,4-萘醌和1,4-蒽醌,4种化合物均呈现较好的线性关系,其检出限分别为4.49、20.89、0.13、0.17 ng。利用该方法分析PM2.5实际样品中的萘醌和蒽醌,均获得了较好的定性和定量结果。 相似文献
2.
Olga Yu Kurapova Sergey M. Shugurov Evgenia A. Vasil'eva Daniil A. Savelev Vladimir G. Konakov Sergey I. Lopatin 《Ceramics International》2021,47(8):11072-11079
Ceria-based solid solutions are important materials for high- and medium-temperature electrochemical applications. However, the stabilities of both binary and ternary ceria-based solid solutions are insufficient at elevated temperatures, which limits their application as solid electrolytes or SOFC cathodes. Data on the high-temperature stability of ceria-based ceramics are unavailable in the literature. In the present study, we report a thermodynamic stability investigation of Y2O3-CeO2 and Y2O3-ZrO2-CeO2 solid solutions. The thermal prehistories of binary and ternary systems were investigated using STA, XRD, and ESCA techniques. The vaporization processes were investigated in the temperature range of 1577–2227°С via the Knudsen effusion mass spectrometry technique. Using data on the component activity in solid-phase thermodynamic properties of Y2O3-CeO2 solid solutions, which is represented as the Gibbs energy, the excess Gibbs energy was calculated as a function of the ceria mol. %. It was shown that the reduction of Ce4+ to Ce3+ in Y2O3-CeO2 and Y2O3-ZrO2-CeO2 solid solutions corresponds to less-negative Gibbs energy compared to ZrO2-CeO2 solid solutions. 相似文献
3.
4.
为缓解我国水、能源和粮食资源紧张问题,促进资源可持续利用,构建水-能源-粮食系统,利用耦合协调度模型对我国的30个省(自治区、直辖市)进行测算,并利用空间杜宾模型分析主要影响因素。结果表明:2003—2017年,我国能源、粮食评价[JP]指数高于水资源评价指数,系统综合评价指数逐年递增;大部分省份耦合协调度处于初级协调水平且呈现逐年上升的态势,个别省份耦合协调度濒临失调;耦合协调度空间自相关性较强,虽有明显波动,但是呈现逐年加强的态势;影响耦合协调度的主要因素有从业人口数、固定资产投资额、人均生产总值、人口总数、[JP]文盲人口占比、工业污染排放、城镇化。 相似文献
5.
为分析地表径流速度对城市内涝的影响,采用一维地下排水管网与二维城区地形的动态耦合模型,选取大连市某排水区块作为研究区域,设置4种地表径流速度10种设计降雨场景,模拟分析在不同重现期设计降雨及不同地表径流速度下研究区的内涝积水特性。结果表明:随着地表径流速度降低,管道排水压力变小,管道排水达标率最高可提升48.05%,且降雨重现期越短,地表径流流速对管道排水压力的削减效果越明显;地表径流流速对检查井溢流量影响显著,随着地表径流速度降低,检查井溢流量峰值最高可减小2 750 m~3,峰现时间最长可滞后56 min,同时随着降雨重现期增长,地表径流流速对检查井溢流量的削减效果减弱;研究区低、高风险区淹没面积随地表径流速度降低,最高可分别减小1.64万、8.37万m~2,但中风险区淹没面积变化反复。 相似文献
6.
Xiao-Mei Sha Li-Jun Zhang Wen-Mei Chen Guang-Yao Wang Jin-Lin Li Zi-Zi Hu Zong-Cai Tu 《International Journal of Food Science & Technology》2022,57(3):1573-1586
Thermal action in extraction process had effects on characteristic tryptic peptides identification and gelling properties of porcine gelatin. SDS-PAGE, HPLC-LTQ/Orbitrap high-resolution mass spectrometry, texture analyser and rheometer were used to evaluate collagen depolymerisation degree, characteristic tryptic peptides and gelling properties of gelatins prepared in various thermal actions. Results showed that with increasing temperature and time, depolymerisation degree enlarged, while gel strength, gelling and melting temperature decreased. Mass spectra showed that 47 and 49 common characteristic tryptic peptides were identified in gelatins extracted at 50 °C and 100 °C with various times, respectively. Moreover, 34 common characteristic tryptic peptides were identified in all gelatin samples. Further comparison between this work and our previous investigations yielded 20 common characteristic tryptic peptides, which stably exist in various thermal actions. These common characteristic tryptic peptides may be very helpful for the accurate authentication of porcine gelatin. 相似文献
7.
《Journal of dairy science》2022,105(1):140-153
A multiparameter study was performed to evaluate the effect of fondaco, a traditional ripening cellar without any artificial temperature and relative humidity control, on the chemical, microbiological, and sensory characteristics of Protected Geographical Indication Canestrato di Moliterno cheese. Ripening in such a nonconventional environment was associated with lower counts of lactococci, lactobacilli, and total viable bacteria, and higher presence of enterococci, in comparison with ripening in a controlled maturation room. Moreover, fondaco cheese underwent accelerated maturation, as demonstrated by faster casein degradation, greater accumulation of free AA, and higher formation of volatile organic compounds. Secondary proteolysis, as assessed by liquid chromatography-mass spectrometry of free AA and low molecular weight peptides, did not show any qualitative difference among cheeses, but fondaco samples evidenced an advanced level of peptidolysis. On the other hand, significant qualitative differences were observed in the free fatty acid profiles and in the sensory characteristics. Principal component analysis showed a clear separation of the fondaco and control cheeses, indicating that ripening in the natural room conferred unique sensory features to the product. 相似文献
8.
《International Journal of Hydrogen Energy》2022,47(18):10228-10238
The utilization of biological-, electrode- and conductive material-mediated direct interspecies electron transfer (DIET) between exoelectrogenic bacteria and methanogenic archaea for enhancing methane productivity is widely reported in the literature. However, two cardinal questions are still controversial, i.e., which applied voltage value would be more recommended to enhance methane generation? and how the DIET over IIET has the upper hand in enhancing methane productivity? Herein, the influence of different applied voltages to promote biological-, conductive- and electrode-mediated DIET was investigated in MEC-AD reactors with conductive material. Polarized bioelectrodes induced electrode-mediated DIET (eDIET) and biological DIET (bDIET), in addition to cDIET (conductive material-mediated DIET), improved the methane yield to 315.40 mL/g CODr with an applied voltage of 0.9 V. Whereas further increase of applied voltage 1.2 V, lessened methane production efficiency due to high-voltage inhibition and adverse effect on DIET promotion. The anaerobic digestion coupled microbial electrolysis cells with optimal electric potential selectively promotes the DIET through polarized electrodes were confirmed through microbial analysis. As the contribution of DIET increased to 80%, the methane yield increased, and the substrate residue decreased, resulting in a significant improvement in methane production. 相似文献
9.
《International Journal of Hydrogen Energy》2022,47(6):3781-3790
A novel heterostructure of g-C3N4/ZnO/Bi4O5Br2 (ZB-3) was designed, and used in the microbial coupled photocatalytic fuel cell (MPFC). It can effectively improve electron utilization efficiency and pollutant degradation using this double Z-scheme heterojunction structure. The current–time (I–t) curves demonstrated that the current density of ZB-3 was higher than that of ZnO, ZnO/Bi4O5Br2 (ZB-1), g-C3N4/ZnO (ZB-2). Electrochemical impedance spectroscopy (EIS) indicated ZB-3 possessed the minimum charge-transfer resistance. This MPFC for degrading rhodamine B (RhB) and tetracycline (TC) under different conditions were developed using these materials. Even in the dark condition, MPFC with g-C3N4/ZnO/Bi4O5Br2 demonstrated 93% and 82% degradation efficiency for RhB and TC, respectively. Furthermore, the electron transport mechanism of the MPFC and ZB-3 were proposed. It paves the approach for more efficient pollutant degradation via MFC photocatalysis. 相似文献
10.