PBAT‒PLA膜袋受控需氧堆肥条件下的降解研究

目的 通过对广泛使用的PBAT–PLA生物降解膜袋在受控需氧堆肥条件下的降解机制研究，为生物降解塑料的大规模推广提供重要理论基础。方法 根据GB/T 19277.1—2011，在(58±2)℃需氧条件下，对PBAT–PLA膜袋进行为期160 d的生物降解测试(即工业堆肥)，并以常见的可降解材料微晶纤维素作为参比样品。对降解前后的材料进行红外、扫描电镜、能谱分析，并结合其所在堆肥样本的脂肪酶活性，从多角度探寻降解机制。结果 PBAT–PLA膜袋与微晶纤维素所在的堆肥脂肪酶活性都达到空白堆肥的3倍以上。红外显示由微晶纤维素水分子吸附、糖环打开、基团氧化形成的吸收峰加强，PBAT–PLA膜袋中的酯键峰明显减弱;扫描电镜发现降解的PBAT–PLA膜袋表面覆盖了微生物膜;能谱分析发现，碳元素大幅减少，氧元素增加。结论 微生物在PBAT–PLA膜袋表面生长形成生物膜，分泌大量脂肪酶，水解PBAT–PLA的酯键，使聚合物降解为不同链长的中间体或小分子，同时伴随着氧化，随后被作为碳源，在相关微生物体内被代谢利用，形成最终产物。     

稳产国Ⅵ柴油并兼产喷气燃料技术方案的工业应用

介绍了浙江石油化工有限公司新建的3 Mt/a柴油加氢精制装置，其配套使用中国石化石油化工科学研究院有限公司开发的催化剂级配技术，并实施了可根据原料供应及市场产品需求情况灵活调整切换的2种生产技术方案。1 a的安稳生产运行结果表明:该装置以直馏柴油为主原料，通过分馏塔的馏分切割及其侧线抽出，实现了稳产国Ⅵ柴油并兼产喷气燃料技术方案的工业化应用；在实施以兼产喷气燃料为主的生产技术方案时，通过调整常一线柴油的掺炼量，不仅可以生产含硫量小于10.0 μg/g的精制柴油产品，同时兼产所得到的喷气燃料产品含硫量小于0.5 μg/g，赛波特颜色号值大于30；在实施主产精制柴油组分方案时，通过掺炼质量分数为20%~40%的催化柴油，并使所提炼得到的精制柴油组分含硫量小于6.0 μg/g的前提下，这些精制柴油组分产品既可直接作为满足国Ⅵ柴油产品出厂待售，也可作为柴油调和组分储存待用于产品的进一步优化。     

Improving accuracy of automatic optical inspection with machine learning

Electronic devices require the printed circuit board(PCB)to support the whole structure,but the assembly of PCBs suffers from welding problem of the electronic components such as surface mounted devices(SMDs)resistors.The automated optical inspection(AOI)machine,widely used in industrial production,can take the image of PCBs and examine the welding issue.However,the AOI machine could commit false negative errors and dedicated technicians have to be employed to pick out those misjudged PCBs.This paper proposes a machine learning based method to improve the accuracy of AOI.In particular,we propose an adjacent pixel RGB value based method to pre-process the image from the AOI machine and build a customized deep learning model to classify the image.We present a practical scheme including two machine learning procedures to mitigate AOI errors.We conduct experiments with the real dataset from a production line for three months,the experimental results show that our method can reduce the rate of misjudgment from 0.3%–0.5%to 0.02%–0.03%,which is meaningful for thousands of PCBs each containing thousands of electronic components in practice.     

Effect of baking in different ovens on the quality and structural characteristics of saltine crackers

The aim of the study was to evaluate the physical and microstructural characteristics of crackers baked in four different industrial baking ovens (indirect radiation-cyclotherm, indirect convection, hybrid and industrial tunnel-ITO). Indirect convection and cyclotherm ovens provide the highest (5685.43 ± 51 W m⁻²) and the lowest (4860 ± 38.87 W m⁻²) amount of heat flux, respectively. Despite the amount of heat flux, indirect convection led to crackers with the highest moisture (7.86% vs. 4.82% in clyclotherm) and specific volume, but the lowest hardness. Cyclotherm resulted in crackers with lower specific volume, surface area, porosity, smooth and regular surface. Conversely, the hybrid and ITO ovens showed closer heat flux, leading to crackers with similar moisture content, texture parameters, specific volume, browning and inner porosity. Overall results show the potential of baking using different ovens for modifying the quality parameters of the crackers.     

Towards artificial intelligence at scale in the chemical industry

In the Industry 4.0 era, the chemical industry is embracing broad adoption of artificial intelligence (AI) and machine learning (ML) methods. This article provides a holistic view of how the industry is transforming digitally towards AI at scale. First, a historical perspective on how the industry used AI to aid humans in better decision-making is shown. Then state-of-the-art AI research addressing industrial needs on reliability and safety, process optimization, supply chain, material discovery, and reaction engineering is highlighted. Finally, a vision of the plant of the future is illustrated with critical components of AI-ready culture, model life cycle management, and renewed role of humans in chemical manufacturing.     

Co?N graphene encapsulated cobalt catalyst for H2O2 decomposition under acidic conditions

Hydrogen peroxide (H₂O₂) has been listed as one of the 100 most important chemicals in the world. However, huge amount of residual H₂O₂ is hard to timely decomposed into O₂ and H₂O under acidic condition, easily resulting in explosion hazard. Here, we reported a core–shell structure catalyst, that is graphene with Co N structure encapsulated Co nanoparticles. Co N graphene shell serves as the active site for the H₂O₂ decomposition, and Co core further enhance this decomposition. Benefiting from it, the H₂O₂ decomposition were close to 100% after 6 cycles without pH adjustment, which increased 6 orders of magnitude compared with no catalyst. At the same time, the O₂ generation reached 99.67% in 2 h with little metal leaching, and ·OH has been greatly inhibited to only 0.08%. This work can cleanly remove H₂O₂ with little deep oxidation and protect the process of H₂O₂ utilization to achieve a safer world.     

食品中非法添加工业染料危害的研究进展

工业染料主要用于纺织品、皮革制品和木制品的染色。由于价格低廉、着色力强、稳定性好,有时被非法作为着色剂使用。如何准确、灵敏和快速地检测食品中的工业染料在食品安全监管中十分重要。为了深入了解工业染料对人体的危害以及食品中工业染料检测方法和研究现状,本文综述了食品中几种工业染料的检测方法,着重阐述了食品中工业染料对人体的毒性作用,并列举了国内外食品中工业染料的检测实例,为食品中工业染料的检测和监管提供了参考与借鉴。     

无烟煤制工业燃气项目原料煤价与经济性的关系分析

针对我国建材行业传统使用的常压固定床煤气发生炉及化肥行业固定床间歇气化炉面临淘汰,无烟煤市场萎缩的情况,提出以晋城无烟煤为原料,利用赛鼎碎煤加压气化技术,生产适合建材行业大规模使用的工业燃气。以无烟煤为原料的河北沙河年产26亿m^3工业清洁燃气项目为基础,对无烟煤与天然气价格、项目经济性的关系进行了分析,结果表明,以晋城无烟块煤运到河北沙河的到厂价935元/t计算,盈亏平衡天然气价约2.26元/m^3;以沙河工业天然气到户售价2.5元/m^3计算,盈亏平衡到厂煤价约1 077元/t,项目经济性较好。     

以产业发展推动乡村振兴的对策探讨

通过乡村振兴,提高农民生活水平,达到产业兴旺、乡风文明、生活富足的主要目标,是农村经济的主要发展发向。产业发展是乡村振兴的基础,只有在产业发展中使乡村经济激活,才能带领广大农民实现脱贫致富。在产业发展的过程中,需要调节好政府与市场的关系,保证生产要素能够流入到农村中来,同时加强农村的基础设施建设,提高经营主体的综合素质,加强产业融合,不断发展新兴特色产业,最终推动乡村振兴。文章主要论述了农村产业发展中存在的一些问题以及对策。