全文获取类型
收费全文 | 46809篇 |
免费 | 5391篇 |
国内免费 | 2964篇 |
专业分类
电工技术 | 2786篇 |
综合类 | 4627篇 |
化学工业 | 7179篇 |
金属工艺 | 1851篇 |
机械仪表 | 3353篇 |
建筑科学 | 4928篇 |
矿业工程 | 1259篇 |
能源动力 | 1984篇 |
轻工业 | 1985篇 |
水利工程 | 1711篇 |
石油天然气 | 2146篇 |
武器工业 | 514篇 |
无线电 | 8353篇 |
一般工业技术 | 6648篇 |
冶金工业 | 1153篇 |
原子能技术 | 1197篇 |
自动化技术 | 3490篇 |
出版年
2024年 | 195篇 |
2023年 | 695篇 |
2022年 | 1239篇 |
2021年 | 1472篇 |
2020年 | 1673篇 |
2019年 | 1473篇 |
2018年 | 1361篇 |
2017年 | 1837篇 |
2016年 | 1845篇 |
2015年 | 1953篇 |
2014年 | 2804篇 |
2013年 | 3042篇 |
2012年 | 3300篇 |
2011年 | 3469篇 |
2010年 | 2662篇 |
2009年 | 2810篇 |
2008年 | 2568篇 |
2007年 | 2912篇 |
2006年 | 2626篇 |
2005年 | 2254篇 |
2004年 | 1883篇 |
2003年 | 1665篇 |
2002年 | 1391篇 |
2001年 | 1207篇 |
2000年 | 1106篇 |
1999年 | 888篇 |
1998年 | 741篇 |
1997年 | 664篇 |
1996年 | 572篇 |
1995年 | 505篇 |
1994年 | 454篇 |
1993年 | 357篇 |
1992年 | 282篇 |
1991年 | 243篇 |
1990年 | 231篇 |
1989年 | 180篇 |
1988年 | 123篇 |
1987年 | 73篇 |
1986年 | 66篇 |
1985年 | 78篇 |
1984年 | 71篇 |
1983年 | 41篇 |
1982年 | 62篇 |
1981年 | 15篇 |
1980年 | 19篇 |
1979年 | 8篇 |
1976年 | 9篇 |
1974年 | 5篇 |
1959年 | 8篇 |
1951年 | 4篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
《Advanced Powder Technology》2020,31(12):4585-4597
Focussing on visible light active ferrites for high performance removal of noxious pollutants, we report the synthesis of Mg0.5NixZn0.5-xFe2O4 (x = 0.1, 0.2, 0.3, 0.4, & 0.5) ferrite nanoparticle for degradation of reactive blue-19 (RB-19). Lattice parameters calculated using intense X-ray diffraction (XRD) peaks and Nelson-Riley plots (N-R plot) are in well agreement with each other. The sample Mg0.5Ni0.4Zn0.1Fe2O4 (M5N4) exhibits best performance with 99.5% RB-19 degradation in 90 min under visible light. Photoluminescence (PL) results confirm that recombination of charge carriers is highly reduced in the photocatalyst. Scavenging experiments suggest that O2− radicals were the dominant species responsible for photocatalytic performance. The photocatalytic mechanism was explained in terms of dopant driven shifting of conduction bands and valence bands (calculated by Mott-Schottky plots). The thermodynamic probability of radical generation along with role of redox cycles of metal ions has been discussed in the mechanism. The dye degradation was ascertained by detection of intermediates via mass spectrometry analysis and a possible degradation route was also predicted. The findings in this work provide intriguing opportunities to modify the electronic band structure of spinel ferrites for visible and solar light photocatalytic activity for environmental detoxification. 相似文献
2.
《Journal of the European Ceramic Society》2020,40(8):3348-3353
Large transduction coefficient () is difficult to obtain in piezoelectric ceramics because these two parameters show opposite trends with compositional modifications. Herein, the Pb(Zr0.53Ti0.47)O3 ceramic powders were calcinated under different temperatures (A:830 °C, B:860 °C, and C:890 °C), and then mixed together according to different weight ratios (1A:1B:1C, 1A:2B:1C, 1A:2B:3C and 3A:2B:1C) for ceramics preparation. Both d33 and g33 are improved successfully, and the transduction coefficient with the weight ratio of 1A:2B:3C reaches up to 17,500 × 10−15 m2/N, which is 60 % higher than that with the powders calcinated under 830 °C, and at least twice those of commercial PZT-4, PZT-5A and PZT-8 ceramics. The improved transduction coefficient is owing to the enhanced piezoelectric constant and spontaneous polarization resulted from the increased grain size, relative density and the fraction of tetragonal phase. These results indicate that this is a simple but effective way to tailor the transduction coefficient in piezoelectric ceramics. 相似文献
3.
The structure and properties of high density polyethylene (HDPE) functionalized by ultraviolet irradiation at different light intensities in air were studied by electron analysis, FTIR spectroscopy, contact angle with water, differential scanning calorimetry and mechanical properties measurement. The results show that oxygen‐containing groups such as C?O, C—O and C(?O)O were introduced onto the molecular chain of HDPE following irradiation, and the rate and efficiency of HDPE functionalization increased with enhancement of irradiation intensity. After irradiation, the melting temperature, contact angle with water and notched impact strength of HDPE decreased, the degree of crystallinity increased, and their variation amplitude increased with irradiation intensity. Compared with HDPE, the yield strength of HDPE irradiated at lower light intensity (32 W m?2 and 45 W m?2) increases monotonically with irradiation time, and the yield strength of HDPE irradiated at higher light intensity (78 W m?2) increases up to 48 h and then decreased with further increase in irradiation time. The irradiated HDPE behaved as a compatibilizer in HDPE/polycarbonate (PC) blends, and the interface bonding between HDPE and PC was ameliorated. After adding 20 wt% HDPE irradiated at 78 W m?2 irradiation intensity for 24 h to HDPE/PC blends, the tensile yield strength and notched Izod impact strength of the blend were increased from 26.3 MPa and 51 J m?1 to 30.2 MPa and 158 J m?1, respectively. Copyright © 2003 Society of Chemical Industry 相似文献
4.
讨论了输出终端带不等式约束情形的多输入多输出系统,说明了这些约束可以通过修改输入柔化系数而使其得以满足,在柔化系数的选择范围确定过程中,为了避免矩阵求逆,采用利用已知数据辨识参数的方法来确定柔化系数,从而使得问题简化。降低了计算量且加快了收敛速度。 相似文献
5.
为了提高非稳定渗流计算的计算精度 ,通过数学分析得到了水位传导系数随时间变化时 ,一类非稳定渗流井流模型的半解析解 ,并进行了计算比较 相似文献
6.
Ph. D. Candidate:Chen Xue-fengState Key Laboratory of Offshore Coastal Engineering Dalian University of Technology Dalian China e-mail: cxfeng @ student dlut. edu.cn 《水动力学研究与进展(B辑)》2003,15(6)
The reflection coefficient of perforated caissons and the total horizontal forces acting on them were experimentally and numerically analyzed and discussed when wave propagates normally. To consider the viscosity effect of fluid and nonlinear action of waves on structures, the VOF (Volume Of Fluid) method combined with the k-ε turbulence model was used to simulate the interaction between waves and structures. Governing equations were solved with the finite difference method. Through 2D experimental study in the wave flume, the empirical relationship between the reflection coefficient of perforated caissons and the main affecting factors were obtained from the experimental data using the least square method. Also the correlation between the ratio of the total horizontal force acting on perforated caisson and the force acting on solid caisson and the main affecting factors were regressed from the experimental data. 相似文献
7.
B. Ma P.I. Djurovich S. Garon B. Alleyne M.E. Thompson 《Advanced functional materials》2006,16(18):2438-2446
Efficient blue‐, green‐, and red‐light‐emitting organic diodes are fabricated using binuclear platinum complexes as phosphorescent dopants. The series of complexes used here have pyrazolate bridging ligands and the general formula C∧NPt(μ‐pz)2PtC∧N (where C∧N = 2‐(4′,6′‐difluorophenyl)pyridinato‐N,C2′, pz = pyrazole ( 1 ), 3‐methyl‐5‐tert‐butylpyrazole ( 2 ), and 3,5‐bis(tert‐butyl)pyrazole ( 3 )). The Pt–Pt distance in the complexes, which decreases in the order 1 > 2 > 3 , solely determines the electroluminescence color of the organic light‐emitting diodes (OLEDs). Blue OLEDs fabricated using 8 % 1 doped into a 3,5‐bis(N‐carbazolyl)benzene (mCP) host have a quantum efficiency of 4.3 % at 120 Cd m–2, a brightness of 3900 Cd m–2 at 12 V, and Commission Internationale de L'Eclairage (CIE) coordinates of (0.11, 0.24). Green and red OLEDs fabricated with 2 and 3 , respectively, also give high quantum efficiencies (~ 6.7 %), with CIE coordinates of (0.31, 0.63) and (0.59, 0.46), respectively. The current‐density–voltage characteristics of devices made using dopants 2 and 3 indicate that hole trapping is enhanced by short Pt–Pt distances (< 3.1 Å). Blue electrophosphorescence is achieved by taking advantage of the binuclear molecular geometry in order to suppress dopant intermolecular interactions. No evidence of low‐energy emission from aggregate states is observed in OLEDs made with 50 % 1 doped into mCP. OLEDs made using 100 % 1 as an emissive layer display red luminescence, which is believed to originate from distorted complexes with compressed Pt–Pt separations located in defect sites within the neat film. White OLEDs are fabricated using 1 and 3 in three different device architectures, either with one or two dopants in dual emissive layers or both dopants in a single emissive layer. All the white OLEDs have high quantum efficiency (~ 5 %) and brightness (~ 600 Cd m–2 at 10 V). 相似文献
8.
An experimental technique together with a numerical model is proposed with which the diffusion coefficient and the sorption isotherm of water in paint can be measured. Inside a closed vessel, paint films are on stainless-steel plates. Water is present as water vapour in the air and in the paint. After blowing dry or wet air through the vessel for some time, the situation moves to a new equilibrium. The relative humidity of the air inside the vessel is measured as a function of time. From fitting the theoretical/numerical model against the experimental values, follow the diffusion coefficient and the sorption isotherm of water in the paint. The results show large scattering. When the independently measured sorption isotherm is used as an input parameter in the model, the fitting procedure gives much smaller scattering for the diffusion coefficient. 相似文献
9.
Cs-K混合蒸气中Cs(8D)+K(4S)碰撞能量转移 总被引:3,自引:3,他引:0
在Cs-K混合蒸气中,两步激发Cs原子到8D态,观察了Cs(8D) K(4S)→Cs(5D) K(4P)碰撞能量合并逆过程(REP,reverse energy pooling)。应用双调制技术探测K(4P)原子发射的荧光,基态K原子密度用光学吸收方法测量。得到了REP速率系数,讨论了其它过程对速率系数的影响. 相似文献
10.
Adriana Brancaccio Giovanni Leone Rocco Pierri 《AEUE-International Journal of Electronics and Communications》2004,58(6):382-390
In this paper, by applying a non linear model for the electromagnetic inverse scattering, a technique for the dielectric profiling of a planarly layered medium is investigated and applied to void localization and diagnostics inside a homogeneous lossless slab (one-dimensional geometry). Data are collected under plane wave multifrequency normal incidence. Suitable finite dimensional representations for the unknown functions are introduced and their influence on the model is discussed. The resulting functional equation is solved by the method of weighted residuals and the solution algorithm amounts to minimizing a non quadratic function, where particular attention is devoted to reduce the occurrence of local minima. Finally, the inversion algorithm is validated by applications to both simulated and experimental data. 相似文献