首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   58279篇
  免费   4236篇
  国内免费   2182篇
电工技术   2624篇
技术理论   1篇
综合类   4004篇
化学工业   15995篇
金属工艺   3250篇
机械仪表   2743篇
建筑科学   5995篇
矿业工程   2023篇
能源动力   4188篇
轻工业   3836篇
水利工程   1011篇
石油天然气   1710篇
武器工业   764篇
无线电   2469篇
一般工业技术   9080篇
冶金工业   3044篇
原子能技术   568篇
自动化技术   1392篇
  2024年   41篇
  2023年   752篇
  2022年   1484篇
  2021年   1946篇
  2020年   1892篇
  2019年   1456篇
  2018年   1184篇
  2017年   1660篇
  2016年   1531篇
  2015年   1498篇
  2014年   2827篇
  2013年   2853篇
  2012年   3906篇
  2011年   4156篇
  2010年   3328篇
  2009年   3496篇
  2008年   2974篇
  2007年   4296篇
  2006年   3736篇
  2005年   3412篇
  2004年   2815篇
  2003年   2607篇
  2002年   2073篇
  2001年   1706篇
  2000年   1471篇
  1999年   1171篇
  1998年   916篇
  1997年   714篇
  1996年   638篇
  1995年   503篇
  1994年   478篇
  1993年   355篇
  1992年   225篇
  1991年   159篇
  1990年   111篇
  1989年   91篇
  1988年   74篇
  1987年   32篇
  1986年   25篇
  1985年   23篇
  1984年   10篇
  1983年   12篇
  1982年   9篇
  1981年   5篇
  1980年   9篇
  1975年   3篇
  1963年   3篇
  1959年   4篇
  1956年   3篇
  1955年   4篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
手性是指物质分子互成镜像但无法重合的性质,手性对映体在生物体内因不同的手性识别而呈现截然不同的作用,所以手性识别在生命科学、医药、食品及材料等领域均具有十分重要的科学意义。手性电化学传感器由于具有制备简单、检测快速和响应灵敏等优点而引起广泛的关注。手性识别材料是构建手性电化学传感器的基础,因此有关手性识别材料的研究在手性电化学检测中尤为重要。综述了近五年手性电化学传感器的研究进展,详细介绍了多种手性识别材料的具体应用,并对该领域的发展前景进行了展望,旨在为今后手性电化学传感器的设计提供参考。  相似文献   
2.
3.

Fe-based bulk metallic glasses (BMGs) with high boron content have potential application as a coating material used in the framework for storing spent nuclear fuels to support their safe long-term disposal. The high glass forming ability (GFA) and large supercooled liquid region are therefore required for such Fe-based BMGs in either the glassy powder fabrication or the subsequent coating spraying. In order to meet these requirements, the influence of Nb content on the GFA of Fe57Cr10Zr8B18Mo7−xNbx (x=1–5, at.%) alloys was investigated, as Nb has positive roles in GFA and thermal stability of BMGs. The results indicate that a fully amorphous phase in the as-cast samples with 3 mm in diameter is obtained for both the Fe57Cr10Zr8B18Mo5Nb2 and Fe57Cr10Zr8B18Mo4Nb3 alloys. The corresponding supercooled liquid regions of the two BMGs are 78 K and 71 K, respectively. The mechanism for improving their GFA was analyzed based on the principle of metal solidification, the parameters for glass formation and thermal properties of the alloys. The compression strength and Vicker’s hardness of the two BMGs are 1,950 MPa and 1,310 HV, 2,062 MPa and 1,180 HV, respectively. The developed BMGs with high B content, good GFA, and very high hardness can be used as coating materials to the framework for spent nuclear fuels.

  相似文献   
4.
Mutations in the Na-K-2Cl co-transporter NKCC2 lead to type I Bartter syndrome, a life-threatening kidney disease. We previously showed that export from the ER constitutes the limiting step in NKCC2 maturation and cell surface expression. Yet, the molecular mechanisms involved in this process remain obscure. Here, we report the identification of chaperone stress 70 protein (STCH) and the stress-inducible heat shock protein 70 (Hsp70), as two novel binding partners of the ER-resident form of NKCC2. STCH knock-down increased total NKCC2 expression whereas Hsp70 knock-down or its inhibition by YM-01 had the opposite effect. Accordingly, overexpressing of STCH and Hsp70 exerted opposite actions on total protein abundance of NKCC2 and its folding mutants. Cycloheximide chase assay showed that in cells over-expressing STCH, NKCC2 stability and maturation are heavily impaired. In contrast to STCH, Hsp70 co-expression increased NKCC2 maturation. Interestingly, treatment by protein degradation inhibitors revealed that in addition to the proteasome, the ER associated degradation (ERAD) of NKCC2 mediated by STCH, involves also the ER-to-lysosome-associated degradation pathway. In summary, our data are consistent with STCH and Hsp70 having differential and antagonistic effects with regard to NKCC2 biogenesis. These findings may have an impact on our understanding and potential treatment of diseases related to aberrant NKCC2 trafficking and expression.  相似文献   
5.
临界通量是膜过程中一种重要的污染特性指标。采用阶梯汲取液浓度递增法测定不同污染物、架桥离子浓度及膜面流速对正渗透(FO)膜过程临界通量的影响。结果表明,海藻酸钠(SA)、腐殖酸(HA)及二氧化硅(SiO2)污染时FO膜临界通量值分别为29.32, 46.35和32.17 L/(m2?h);随Ca2+浓度由0 mmol/L增大至10 mmol/L,SA污染下FO膜的临界通量由29.22 L/(m2?h)显著降低至9.48 L/(m2?h),原因为Ca2+与SA分子中的羧基的螯合作用及Ca2+在膜?污染物之间的架桥作用;此外,当膜面流速从5 cm/s增至15 cm/s时,SA-Ca2+污染下的FO膜临界通量由9.48 L/(m2?h)提高至31.59 L/(m2?h),表明改善膜表面湍动有利于提高临界通量,扩大操作通量范围。  相似文献   
6.
介绍了高分子材料导热性能影响因素研究进展,重点阐释了聚合物基体的结构特性(链结构、分子间相互作用、取向、结晶度等)、导热填料(种类、含量、形态、尺寸等)以及制备方法等对高分子材料导热性能的影响。  相似文献   
7.
Pervaporation (PV) is a membrane technology that holds great promise for industrial applications. To better understand the PV mechanism, PV dehydrations of various types of organic solvents (methanol, ethanol, iso-propanol, tert-butanol, and acetone) were performed on five types of organosilica and two types of silicon carbide-based membranes, all with different pore sizes. Water permeance was dependent on the types of organic aqueous solutions, which suggested that organic solvents penetrated the pores and hindered the permeation of water. In addition, water permeance of various types of membranes in PV was well correlated with hydrogen permeance in single-gas permeation. Furthermore, a clear correlation was obtained between the permeance ratio in PV and that in single-gas permeation, which was confirmed via the modified-gas translation model. These correlations make it possible to use single-gas permeation properties to predict PV performance.  相似文献   
8.
张璐璐  谭伯川  李文坡 《化工学报》2021,72(10):5402-5411
采用简单的一步电沉积方法制备了Cu2+掺杂的MnO2材料。通过XRD、SEM、TEM等方法对材料进行了表征,结果表明其具有蓬松多孔的纳米结构,作为电池正极材料时有利于Zn2+的存储,具有较高的电池容量。与未掺杂样品相比Cu2+掺杂的MnO2材料有更好的电化学性能,在电流密度为200 mA/g时,比容量达到235 mAh/g,增加了47.8%,阻抗也由997.3 Ω降到了564.3 Ω。  相似文献   
9.
王欣  赵鹏  李清扬  田平芳 《化工学报》2021,72(5):2426-2435
半导体合成生物学是研究半导体技术与合成生物学之间协同作用的一门交叉学科。其涉及的活细胞-半导体材料杂合体系具有独特的能量和信号转导机制,不仅维持活细胞的代谢能力,而且保留半导体材料的光电学物理特性,在化工、通讯、计算、能源及医疗等领域具有广阔的应用前景。综述了半导体合成生物学在生物催化、智能生物传感以及新型DNA数据存储领域的最新研究进展,讨论了目前研究面临的技术难题及解决方案,旨在为合成生物学和半导体技术这两个影响化工发展的领域提供有价值的参考。  相似文献   
10.
ABSTRACT

The hydrophobic polyether sulfone membranes were prepared by the sol-gel method to be applied in an air gap membrane distillation setup for desalination. The surface modifications were carried out using Trimethylsilyl chloride (TMSCl) and Methyltrimethoxysilane (MTMS) solutions. The membranes were characterized using Attenuated Total Reflection Infrared (ATR-IR) spectroscopy, Scanning Electron Microscopy (SEM), and Optical Contact Angle (OCA) methods. The effects of membrane preparation as well as operating conditions such as temperature difference, salt concentration, feed rotation speed, and cold-side temperature on membrane performance were investigated using central composite design method. It was found that feed temperature has the largest effect among the parameters on the permeation flux. The flow rate and salt rejection of the membrane in the optimum conditions were 4.47 Kg m?2 h?1 and 99.37%, respectively.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号