全文获取类型
收费全文 | 579篇 |
免费 | 95篇 |
国内免费 | 15篇 |
专业分类
电工技术 | 8篇 |
综合类 | 29篇 |
化学工业 | 309篇 |
金属工艺 | 13篇 |
机械仪表 | 18篇 |
建筑科学 | 28篇 |
矿业工程 | 3篇 |
能源动力 | 3篇 |
轻工业 | 168篇 |
水利工程 | 2篇 |
石油天然气 | 6篇 |
武器工业 | 3篇 |
无线电 | 18篇 |
一般工业技术 | 75篇 |
冶金工业 | 1篇 |
原子能技术 | 1篇 |
自动化技术 | 4篇 |
出版年
2024年 | 5篇 |
2023年 | 13篇 |
2022年 | 22篇 |
2021年 | 30篇 |
2020年 | 26篇 |
2019年 | 25篇 |
2018年 | 20篇 |
2017年 | 27篇 |
2016年 | 21篇 |
2015年 | 31篇 |
2014年 | 40篇 |
2013年 | 45篇 |
2012年 | 43篇 |
2011年 | 43篇 |
2010年 | 29篇 |
2009年 | 31篇 |
2008年 | 20篇 |
2007年 | 30篇 |
2006年 | 38篇 |
2005年 | 22篇 |
2004年 | 21篇 |
2003年 | 17篇 |
2002年 | 16篇 |
2001年 | 6篇 |
2000年 | 19篇 |
1999年 | 9篇 |
1998年 | 13篇 |
1997年 | 8篇 |
1996年 | 6篇 |
1995年 | 4篇 |
1994年 | 2篇 |
1993年 | 1篇 |
1992年 | 2篇 |
1991年 | 1篇 |
1990年 | 1篇 |
1989年 | 1篇 |
1982年 | 1篇 |
排序方式: 共有689条查询结果,搜索用时 15 毫秒
1.
Poly[2‐methoxy‐5‐(2′‐ethyl‐hexyloxy)‐para‐phenylene vinylene] (MEH‐PPV)/silica nanoparticle hybrid films were prepared and characterised. Three kinds of materials were compared: parent MEH‐PPV, MEH‐PPV/silica (hybrid A films), and MEH‐PPV/coupling agent MSMA/silica (hybrid B films), in which MSMA is 3‐(trimethoxysilyl) propyl methacrylate. It was found that the hybrid B films could significantly prevent macrophase separation, as evidenced by scanning electron and fluorescence microscopy. Furthermore, the thermal characteristics of the hybrid films were largely improved in comparison with the parent MEH‐PPV. The UV‐visible absorption spectra suggested that the incorporation of MSMA‐modified silica into MEH‐PPV could confine the polymer chain between nanoparticles and thus increase the conjugation length. The photoluminescence (PL) studies also indicated enhancement of the PL intensity and quantum efficiency by incorporating just 2 wt% of MSMA‐modified silica into MEH‐PPV. However, hybrid A films did not show such enhancement of optoelectronic properties as the hybrid B films. The present study suggests the importance of the interface between the luminescent organic polymers and the inorganic silica on morphology and optoelectronic properties. Copyright © 2004 Society of Chemical Industry 相似文献
2.
Ruopei Xu Yue Qiu Siyi Tang Cheng Yang Yu Dai Dajie Zhang Yue Gao Kexiong Gao Longbo Luo Xiangyang Liu 《大分子材料与工程》2021,306(5):2000814
High performance fibers with high strength and toughness have great potential in composites, but contradiction between tensile strength and elongation at break makes the preparation to become a current challenge. Herein, an asymmetric structure of more flexible diamine, 3,4′-diaminodiphenyl ether (3,4′-ODA), is introduced into heterocyclic aramid (PBIA) fibers to replace rigid symmetric p-phenylenediamine (PDA). By studying the properties of copolymer (mPEBA) fibers with different ratios of diamine, it is found that the mPEBA fiber reached the optimal mechanical properties with the 30% content of 3,4′-ODA. Compared with homopolymerized heterocyclic aramid fibers, the tensile strength and elongation at break of mPEBA fiber are improved by 26.2% and 38.7%, respectively. Results of X-ray diffraction show that the introduction of 3,4′-ODA structure can increase stretchability of mPEBA fibers, improving the orientation degree during hot-drawing. Molecular dynamics simulations confirm that 3,4′-ODA structure undergoes a conformation transformation to form a straightened chain during hot-drawing, while symmetrical 4,4′-diaminodiphenyl ether (4,4′-ODA) cannot form the same conformation. The misplaced-nunchaku structure is formed based on the special meta-para position of 3,4′-ODA, achieving the synergy of high strength and high toughness. 相似文献
3.
研究了直接纺丝制取芳纶短纤维的新方法。讨论了纤维长度、直径及力学性能与纺丝条件的关系。发现影响纤维长度的主要因素是空气层高度和喷丝速度,影响纤维直径的主要因素为喷口直径及喷丝速度。此外,还用PPTA短纤维制成了均匀的PPTA"浆粕"纤维。 相似文献
4.
Tetrabutyl titanate was used as sol–gel precursor of a nanosized TiO2 coating to improve the photo‐stability of aramid fibers. The nanosized TiO2 coating was characterized by XRD and XPS. The influence of the TiO2 coating on photo‐stability of aramid fibers was investigated by an accelerated photo‐ageing method. The photo‐stability of aramid fiber showed obvious improvement after coating. After 156 h of UV exposure, the coated fibers showed less deterioration in mechanical properties with the retained tensile strength and elongation at break greater than 36 and 50% of the original values, respectively, whereas the uncoated fibers degraded completely and became powdery. SEM analysis showed no significant surface morphological change on the coated fiber after the exposure, while some latitudinal crack fractures appeared on the uncoated aramid fiber. The effect of the nanosized TiO2 coating was also well demonstrated by examining the difference of distributions of C1s in XPS deconvolution analysis on the surface of uncoated/coated fibers with increasing UV exposure time. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 3113–3119, 2007 相似文献
5.
利用KMnO4在酸性的环境中具有氧化性的特性对芳纶纤维进行表面改性研究,分析其表面形貌、强力以及拉伸性能的变化;采用扫描电子显微镜观察处理前后芳纶纤维的表面形态特征;以夹角余弦幅度法确定权重;利用模糊正交法的理论与方法处理试验数据,得出模糊综合评价值.从而得出最佳实验指标为:硫酸质量分数10%,KMnO4质量浓度5 g/L,处理温度为30℃,处理时间35 min. 相似文献
6.
以聚碳酸酯二元醇为软段,利用预聚体法制备了系列聚碳酸酯基聚氨酯/芳纶浆粕纤维(Aramid pulp)复合材料,研究了芳纶浆粕纤维对聚碳酸酯基聚氨酯弹性体(PUE)力学性能的影响。采用扫描电镜、X射线衍射、差示扫描量热分析、热重分析、红外光谱及电子拉伸机等测试仪器对聚氨酯复合材料的结构与性能进行了表征和分析。结果表明,芳纶浆粕纤维能有效实现对聚氨酯弹性体的增强作用,其中对撕裂强度的增强尤为突出。当芳纶浆粕纤维用量为0.5%时,复合材料的撕裂强度由106 k N/m提高到120 k N/m,表现出最好的力学性能;芳纶浆粕纤维在聚氨酯中分散均匀,提高了复合材料的热稳定性。 相似文献
7.
8.
9.
应用于高温气体过滤的Basofil过滤材料 总被引:1,自引:0,他引:1
AlasnC.Handermann 《产业用纺织品》2001,19(5):10-15
总结了Basofil滤料的物理性能、过滤效率的研究及其特性。除尘室现场试验结果表明 ,与 10 0 %间位芳纶滤料相比 ,Basofil滤料具有更低的压力降和更高透气性的优点 ,且具有相近或更长的使用寿命 相似文献
10.