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1.
《Ceramics International》2021,47(23):33106-33119
K9 optical glass is one of the typical components in optical systems. However, because of its poor fracture resistance, it is difficult to polish it with ultra-precision and high-efficiency and without any surface damage simultaneously. The emergence of the obliquely axial ultrasonic vibration-assisted polishing (UVAP) method can solve this problem which encounters in polishing efficiency and shape accuracy. However, due to the unclear material removal profile (MRP) mechanism, obliquely axial UVAP is not widely used in the processing field. This paper introduces the obliquely axial UVAP method in research processes, mainly focusing on the fixed point MRP analysis of the obliquely axial UVAP. Based on Hertz's contact theory, polishing pressure, the length of the semi-long axis (LLA) and the length of the semi-short axis (LSA) of the contact area are calculated under ultrasonic vibration conditions. Meanwhile, the relative linear velocity distribution of the oblique polishing tool in the instantaneous contact area is modeled by mathematical geometry method. A novel model of the MRP distribution for obliquely axial UVAP is proposed following the Preston equation. Subsequently, a series of polishing experiments were carried out to verify this model. The results show that the numerical model has good agreement with the experimental results on MRP, LLA, LSA, material removal depth and material removal rate (MRR). In addition, the material removal capability can be significantly improved by larger ultrasonic amplitude and larger oblique angle. This model not only more clearly elucidates the processing mechanism of obliquely axial UVAP, but also provides theoretical support for the polishing of free-form optical lenses. 相似文献
2.
Dr. Laurent David Dr. Mark Wenlock Dr. Patrick Barton Dr. Andreas Ritzén 《ChemMedChem》2021,16(17):2669-2685
Chameleonic properties, i. e., the capacity of a molecule to hide polarity in non-polar environments and expose it in water, help achieving sufficient permeability and solubility for drug molecules with high MW. We present models of experimental measures of polarity for a set of 24 FDA approved drugs (MW 405-1113) and one PROTAC (MW 1034). Conformational ensembles in aqueous and non-polar environments were generated using molecular dynamics. A linear regression model that predicts chromatographic apparent polarity (EPSA) with a mean unsigned error of 10 Å2 was derived based on separate terms for donor, acceptor, and total molecular SASA. A good correlation (R2=0.92) with an experimental measure of hydrogen bond donor potential, Δlog Poct-tol, was found for the mean hydrogen bond donor SASA of the conformational ensemble scaled with Abraham's A hydrogen bond acidity. Two quantitative measures of chameleonic behaviour, the chameleonic efficiency indices, are introduced. We envision that the methods presented herein will be useful to triage designed molecules and prioritize those with the best chance of achieving acceptable permeability and solubility. 相似文献
3.
糖尿病视网膜病变是世界上致盲率最高的眼科疾病,早期诊断可以显著降低患者失明的概率。深度学习方法可以提取医学图像的隐含特征,并完成图像的检测任务,因此应用深度学习实现糖尿病视网膜病灶检测成为研究热点。主要从数据集介绍、全监督检测方法、非完全监督检测方法、小样本问题的处理和模型可解释性五个方面进行详细总结,重点整理各类方法的基本思想、网络结构形式、改进方案及优缺点总结等内容,结合当前检测方法所面临的挑战,对其未来研究方向进行展望。 相似文献
4.
为了促进油茶产业的发展以及开发新的蛋白胶黏剂,以油茶籽蛋白为原料(蛋白质含量36%,纤维含量15%),采用碱(NaOH)对其进行降解处理,并与交联剂混合作为胶黏剂应用于胶合板的热压中。考察了NaOH加量对油茶籽蛋白水解度和降解液甲醛反应能力、黏度和胶黏剂胶合性能的影响,并对降解前后油茶籽蛋白进行了红外表征。结果表明:NaOH可使油茶籽蛋白有效降解,并产生活性基团和活性点;随着NaOH加量的增加,油茶籽蛋白水解度和降解液甲醛反应能力呈先急剧增加后缓慢增加的趋势,降解液黏度呈先增加后急剧减小再缓慢减小的趋势;所制备的胶合板的湿状胶合强度总体呈先增加后减小的变化趋势。NaOH加量为7%时,油茶籽蛋白降解液具有较高的反应活性、较大的内聚强度、较好的施胶性能和优良的胶合性能。 相似文献
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柯探1井是部署在新疆阿克苏地区柯坪县的一口风险探井,在寒武系沙依力克组钻遇高钙盐水层,持续不断地钙侵导致重晶石沉降,发生了卡钻等一系列井下故障。为优化复杂地质条件下钻井液配方,现场开展多种试验,提出了钙盐水层钻井液等一系列钻井液配方:①三开配浆即用海泡石代替现在的膨润土,控制好低密度固相,为转换四开饱和盐水钻井液做好准备;②除聚合物之外,常见的淀粉比较适合该区块;③除应用纯碱和小苏打除钙外,使用一些硅酸钾,能预防钙侵,生成的硅酸钙对井壁稳定、防塌有一定的帮助,同时钾离子可以提高钻井液的抑制性;④采用质量较好的白沥青,实现快速优质钻进。现场应用表明,四开高钙盐水层,电测无阻卡,井径规则,套管一次性下到位,钻井液性能满足固井施工要求,现场施工效果良好。 相似文献
9.
Reliable joints of Ti3SiC2 ceramic and TC11 alloy were diffusion bonded with a 50 μm thick Cu interlayer. The typical interfacial structure of the diffusion boned joint, which was dependent on the interdiffusion and chemical reactions between Al, Si and Ti atoms from the base materials and Cu interlayer, was TC11/α-Ti + β-Ti + Ti2Cu + TiCu/Ti5Si4 + TiSiCu/Cu(s, s)/Ti3SiC2. The influence of bonding temperature and time on the interfacial structure and mechanical properties of Ti3SiC2/Cu/TC11 joint was analyzed. With the increase of bonding temperature and time, the joint shear strength was gradually increased due to enhanced atomic diffusion. However, the thickness of Ti5Si4 and TiSiCu layers with high microhardness increased for a long holding time, resulting in the reduction of bonding strength. The maximum shear strength of 251 ± 6 MPa was obtained for the joint diffusion bonded at 850 °C for 60 min, and fracture primarily occurred at the diffusion layer adjacent to the Ti3SiC2 substrate. This work provided an economical and convenient solution for broadening the engineering application of Ti3SiC2 ceramic. 相似文献
10.
《中国有色金属学会会刊》2021,31(10):3063-3074
The transient liquid phase (TLP) bonding of CoCuFeMnNi high entropy alloy (HEA) was studied. The TLP bonding was performed using AWS BNi-2 interlayer at 1050 °C with the TLP bonding time of 20, 60, 180 and 240 min. The effect of bonding time on the joint microstructure was characterized by SEM and EDS. Microstructural results confirmed that complete isothermal solidification occurred approximately at 240 min of bonding time. For samples bonded at 20, 60 and 180 min, athermal solidification zone was formed in the bonding area which included Cr-rich boride and Mn3Si intermetallic compound. For all samples, the γ solid solution was formed in the isothermal solidification zone of the bonding zone. To evaluate the effect of TLP bonding time on mechanical properties of joints, the shear strength and micro-hardness of joints were measured. The results indicated a decrement of micro-hardness in the bonding zone and an increment of micro-hardness in the adjacent zone of joints. The minimum and maximum values of shear strength were 100 and 180 MPa for joints with the bonding time of 20 and 240 min, respectively. 相似文献