从蚕的生命到艺术：中国古代生命观的哲学表达

中国考古出土的蚕业实物及蚕的艺术形象比较丰富,蚕的艺术形象如蚕纹、陶蚕蛹、牙雕蚕、玉石蚕、铜蚕、金蚕等,可统称为"蚕的模拟形态"。对蚕的模拟形态的功用,已有的诸多解释都有待完善。研究表明,蚕的模拟形态或艺术形象表达的功用或为饰品,或为装饰图案,或有待进一步考究。但无论哪种功用,用"蚕"这一形象都蕴含了特有的用意。通过对中国古代生命观的考察,文章认为蚕的艺术形象折射出相应的中国古代哲学生命观,即中国古人追求的死而复生、生生不息、羽化成仙、长乐无极等观念。     

S/Se dual-doping promotes the formation of active Ni/Fe oxyhydroxide for oxygen evolution reaction of (sea)water splitting

Surface reconstruction produces metal oxyhydroxide (1OOH) active sites, and promoting surface reconstruction is essential for the design of OER electrocatalysts. In this paper, we reported that a large amount of active NiFeOOH was generated in-situ on the surface of nickel-iron sulfide selenide, thus exposing more active sites and efficiently catalyzing OER. In 1 M KOH solution, NiFeOOH(S,Se) achieves an ultra-low overpotential of 195 mV at the current density of 10 mA cm^?2, and the Tafel slope is only 31.99 mV dec^?1, showing excellent catalytic performance. When the current density is 100  mA cm^?2, the over-potential of NiFeOOH(S,Se) in KOH + seawater solution is 239 mV, which is almost equivalent to 231 mV in KOH solution. The excellent OER stability of the NiFeOOH(S,Se) catalyst in alkaline electrolytes was confirmed, and the overpotential did not change significantly after 4 days of testing in KOH + seawater solution.     

Optimized Biocatalytic Synthesis of 2-Selenopyrimidine Nucleosides by Transglycosylation**

Selenium-modified nucleosides are powerful tools to study the structure and function of nucleic acids and their protein interactions. The widespread application of 2-selenopyrimidine nucleosides is currently limited by low yields in established synthetic routes. Herein, we describe the optimization of the synthesis of 2-Se-uridine and 2-Se-thymidine derivatives by thermostable nucleoside phosphorylases in transglycosylation reactions using natural uridine or thymidine as sugar donors. Reactions were performed at 60 or 80 °C and at pH 9 under hypoxic conditions to improve the solubility and stability of the 2-Se-nucleobases in aqueous media. To optimize the conversion, the reaction equilibria in analytical transglycosylation reactions were studied. The equilibrium constants of phosphorolysis of the 2-Se-pyrimidines were between 5 and 10, and therefore differ by an order of magnitude from the equilibrium constants of any other known case. Hence, the thermodynamic properties of the target nucleosides are inherently unfavorable, and this complicates their synthesis significantly. A tenfold excess of sugar donor was needed to achieve 40−48 % conversion to the target nucleoside. Scale-up of the optimized conditions provided four Se-containing nucleosides in 6–40 % isolated yield, which compares favorably to established chemical routes.     

Irradiation-induced large bubble formation and grain growth in super nano-grained ceramic

In this work, 0.5TRPO•0.5Gd₂Zr₂O₇ ceramic with an average grain size of only ∼15 nm was prepared by a high pressure (5 GPa/520 °C) sintering method. Phase evolutions and microstructure changes of the as-fabricated super nano and micron-grained ceramics under a high-dose displacement damage induced by 300 keV Kr²⁺ ions were investigated. The results show that the super nano-grained ceramic has low degree of amorphization, obvious grain growth (2–3 times in grain size) and big Kr bubbles (10–68 nm) formation after irradiation. The micron-grained ceramic was severely amorphized after irradiation and many microcracks were formed parallel to its surface. The formation mechanism of Kr bubbles in the super nano-grained ceramic is on account of grain boundary diffusion and migration induced by the accumulation of the injecting Kr ions and irradiation defects. Nevertheless, microcracks formed in the micron-grained sample are caused by the accumulation of Kr atoms.     

Chemical durability and surface alteration of lanthanide zirconates (A2Zr2O7: A = La-Yb)

Chemical durability of lanthanide zirconates (A₂Zr₂O₇) (A = La-Yb) under near-field environments is important for evaluating their application as potential nuclear waste forms. In this work, A₂Zr₂O₇ (A = La-Yb) are synthesized by spark plasma sintering with controlled microstructure and their chemical durability are evaluated in a nitric acid solution (pH = 1). Scanning transmission electron microscopy analysis reveals an amorphous passivation film either enriched with Zr or lanthanide. The complex chemistry of the passivation films can be correlated with a transition in corrosion mechanisms from a preferential release of lanthanide in La₂Zr₂O₇ to a preferential release of Zr in Er₂Zr₂O₇ and Yb₂Zr₂O₇. These results suggest a dominant mechanism of incongruent dissolution and surface reorganization for the formation of passivation films. Strong correlations are identified between the leaching rates and cation ionic size, ionic potential, electronegativity differences between A-site cation and Zr, and bonding valence sum of oxygen, suggesting important impacts of structural and bonding characteristics in controlling chemical durability of lanthanide zirconates.     

微结构模芯的精密磨削及其在微注塑成形中应用

针对微结构聚合物元器件的批量化生产与制造效率低等问题，采用精密修整成V形尖端的金刚石砂轮，在自润滑性和脱模性良好的钛硅碳陶瓷模芯表面加工制造出形状精度可控的V沟槽阵列结构，然后利用微注塑成形工艺将模芯表面的V沟槽阵列结构一次成形复制到聚合物表面，高效注塑成形制造出倒V形阵列结构的聚合物工件。分析了微模芯的表面加工质量与形状精度，研究了熔体温度、注射速度、保压压力、保压时间等微注塑成形工艺参数对微结构聚合物注塑成形角度偏差和填充率的影响。实验结果表明：通过微细磨削加工技术和微注塑成形工艺可以高效率、高精度地制造出规则整齐的微结构注塑工件，注射速度对微成形角度偏差的影响最大，保压压力对微成形填充率的影响最大，微结构模芯的微细磨削形状精度值为4.05 μm，微成形的最小角度偏差和最大填充率分别为1.47°和99.30%。     

实物地质资料展览展示研究——以国土资源实物地质资料中心为例

为了让国家馆藏实物地质资料资源“看得见、可获取、用得起、盘得活”,服务于拥有不同需求的专业人员和社会公众用户群体,在展览展示内容、展示方法和结构上有所创新,经过深入、系统地科学研究,理清了实物地质资料展览展示的特色,准确把握和定位了展览大纲,使实物展品、辅助展品、展示方式与展厅所在建筑物融为一体,全面科学地落实和确定了实物地质资料展品和布展方案,创新了实物地质资料展览展示技术方法,提出了以国家馆藏实物地质资料为基础的典型实物展示与多媒体全面展示相结合、模块化展览设计的技术思路,为实物地质资料展览展示的进一步研究提供了技术储备。     

河北、湖北、四川三省畜禽养殖场粪污样品中硒、钼含量的调查

目的 调查河北、湖北、四川三省畜禽养殖场粪污样品中硒、钼的含量。方法 采集河北、湖北、四川三省206个养殖场的422个样品, 干清粪和水泡粪样品经过65 ℃烘干至恒重后, 粉碎或研磨, 过0.25 mm样品筛, 进行微波消解处理后, 赶酸定容至50 mL容量瓶中, 用电感耦合等离子质谱仪对硒、钼元素进行测定。污水样直接进行微波消解处理后, 赶酸定容至50 mL容量瓶中, 用电感耦合等离子质谱仪对硒、钼元素进行测定。结果 3个省份的猪场、鸡场和牛场的干清粪样品中不同程度的检出了硒或钼的含量; 污水样品和水泡粪样品中均未检出硒和钼的含量。结论 河北、四川、湖北三省养猪场、养鸡场和养牛场的粪污再利用过程中可能会对环境造成一定的污染, 应当进行相应处理后再进行利用。