全文获取类型
收费全文 | 38728篇 |
免费 | 4456篇 |
国内免费 | 1508篇 |
专业分类
电工技术 | 977篇 |
综合类 | 2378篇 |
化学工业 | 9764篇 |
金属工艺 | 943篇 |
机械仪表 | 1332篇 |
建筑科学 | 1821篇 |
矿业工程 | 458篇 |
能源动力 | 971篇 |
轻工业 | 11880篇 |
水利工程 | 256篇 |
石油天然气 | 1734篇 |
武器工业 | 132篇 |
无线电 | 4275篇 |
一般工业技术 | 3973篇 |
冶金工业 | 1143篇 |
原子能技术 | 468篇 |
自动化技术 | 2187篇 |
出版年
2024年 | 122篇 |
2023年 | 825篇 |
2022年 | 1192篇 |
2021年 | 1731篇 |
2020年 | 1622篇 |
2019年 | 1551篇 |
2018年 | 1430篇 |
2017年 | 1637篇 |
2016年 | 1771篇 |
2015年 | 1723篇 |
2014年 | 2457篇 |
2013年 | 2669篇 |
2012年 | 2966篇 |
2011年 | 3068篇 |
2010年 | 2236篇 |
2009年 | 2245篇 |
2008年 | 1924篇 |
2007年 | 2216篇 |
2006年 | 1964篇 |
2005年 | 1525篇 |
2004年 | 1297篇 |
2003年 | 1163篇 |
2002年 | 898篇 |
2001年 | 747篇 |
2000年 | 644篇 |
1999年 | 484篇 |
1998年 | 387篇 |
1997年 | 315篇 |
1996年 | 273篇 |
1995年 | 247篇 |
1994年 | 247篇 |
1993年 | 215篇 |
1992年 | 163篇 |
1991年 | 115篇 |
1990年 | 117篇 |
1989年 | 78篇 |
1988年 | 68篇 |
1987年 | 44篇 |
1986年 | 54篇 |
1985年 | 42篇 |
1984年 | 47篇 |
1983年 | 31篇 |
1982年 | 27篇 |
1980年 | 24篇 |
1976年 | 6篇 |
1964年 | 7篇 |
1959年 | 10篇 |
1958年 | 6篇 |
1956年 | 5篇 |
1951年 | 6篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
1.
2.
《Ceramics International》2022,48(6):7605-7612
In recent work, pure α-Fe2O3 (F-1) and series of 5% Cu doped Fe2O3 (CF-5) , 10% Cu doped Fe2O3 (CF-10) and 15% Cu doped Fe2O3 (CF-15) nanoparticles by facile chemical coprecipitation method were synthesized to study the effect of concentration of doping for photocatalytic activity. As prepared F-1, CF-5, CF-10, CF-15 nanoparticles were subjected to X-ray diffraction (XRD) and Fourier transform infra-red (FTIR) techniques to analyse the structural and functional groups features. These characterization techniques confirmed the successful doping of Cu 2+ ions in α-Fe2O3. The crystallite size of synthesized samples was calculated by Scherrer formula. Gradually decline in crystallite size from 18 to 15 nm was observed for undoped to doped samples. Scanning electron microscopic (SEM) analysis expressed that doping of Cu reduced the aggregation of particles and enhanced the surface area of nanoparticles. UV–Visible spectroscopic analysis of synthesized samples was used to calculate the bandgap energy of F-1, CF-5, CF-10, CF-15 nanoparticles i.e., 2.0, 1.7, 1.5, 1.4eV respectively. Narrowing bandgap energy of doped hematite supported to perform excellent photocatalytic activity. Maximum degradation of methylene blue was recorded via CF-10 within 140 min. Higher degradation rate of methylene blue by optimal concentration of CF-10 is due to effective electron trapping ability of photocatalyst. 相似文献
3.
4.
Hamid Ezzatpanah Vicente M. Gómez-López Tatiana Koutchma Farnoush Lavafpour Frank Moerman Mohammad Mohammadi Dele Raheem 《Comprehensive Reviews in Food Science and Food Safety》2022,21(2):904-941
Food- and waterborne viruses, such as human norovirus, hepatitis A virus, hepatitis E virus, rotaviruses, astroviruses, adenoviruses, and enteroviruses, are major contributors to all foodborne illnesses. Their small size, structure, and ability to clump and attach to inanimate surfaces make viruses challenging to reduce or eliminate, especially in the presence of inorganic or organic soils. Besides traditional wet and dry methods of disinfection using chemicals and heat, emerging physical nonthermal decontamination techniques (irradiation, ultraviolet, pulsed light, high hydrostatic pressure, cold atmospheric plasma, and pulsed electric field), novel virucidal surfaces, and bioactive compounds are examined for their potential to inactivate viruses on the surfaces of foods or food contact surfaces (tools, equipment, hands, etc.). Every disinfection technique is discussed based on its efficiency against viruses, specific advantages and disadvantages, and limitations. Structure, genomic organization, and molecular biology of different virus strains are reviewed, as they are key in determining these techniques effectiveness in controlling all or specific foodborne viruses. Selecting suitable viral decontamination techniques requires that their antiviral mechanism of action and ability to reduce virus infectivity must be taken into consideration. Furthermore, details about critical treatments parameters essential to control foodborne viruses in a food production environment are discussed, as they are also determinative in defining best disinfection and hygiene practices preventing viral infection after consuming a food product. 相似文献
5.
《Ceramics International》2022,48(8):10579-10591
In present study, we report a V doping fabrication method for obtaining rod-like MgO crystals decorated with a nanoflake layer. This novel structure has only been minimally reported in literature. Pure MgO and Mg2V2O7–MgO composite materials were obtained by precipitation and impregnation methods, with vanadium added concentrations of 0–9%. The influence of V doping on crystal structure and particle morphology of MgO was investigated by scanning electron microscopy (SEM). X-ray diffraction (XRD) analysis demonstrated that MgO has a cubic structure, while X-ray photoelectron spectroscopy (XPS) revealed that V5+ exists on the surface of MgO. The specific surface areas and pore sizes of MgO composites were calculated by BET and BJH analysis. These techniques revealed that specific surface area and pore size of MgO increased due to vanadium doping. The antibacterial effects of Mg2V2O7–MgO composite materials against Escherichia coli (E. coli) and Staphylococcus aureus (S. aureus) were assessed using a bacterial killing/colony-forming unit (CFU) assay and bacteriostatic ring method. Our results demonstrate that V doping dramatically improved antimicrobial properties of MgO, with 7 mol% doping inducing the best antibacterial activity. The antibacterial mechanisms of Mg2V2O7–MgO composite material were also proposed. 相似文献
6.
《International Journal of Hydrogen Energy》2022,47(59):24807-24816
Engineering alloy nanostructures with a combination of highly active noble metals (Pt and Pd) and less electronegative non-noble metal (Ni) is found to be crucial for improving surface reactivity by enriching with active Pt sites. Herein, a multi-skeletal PtPdNi nanodendrites (NDs) was successfully formed by a simple one-pot method with structure directing agent. The modification of Pt electronic structure and their interaction due to compressive strain were explored using benchmark characterization techniques, which showed that the PtPdNi NDs possess Pt-enriched surface, corroborating to more active catalyst sites for oxygen reduction reaction (ORR) in acidic medium. The PtPdNi NDs have a higher electrochemical surface area (63 m2 g?1) and an earlier onset potential (1.01 V) than PtPd NDs, PtNi NDs, and commercial Pt/C catalysts, indicating the outstanding ORR performance. The high mass and specific activities, as well as superior durability after accelerated degradation test (ADT), highlight the remarkable electrocatalytic performance of PtPdNi NDs over others. As a result, enhancing Pt utilization through the formation of PtPdNi NDs could be a reliable strategy to improve ORR electrocatalysis for polymer electrolyte membrane fuel cell (PEMFC) applications. 相似文献
7.
8.
Li Cao Ying Wu Wenwen Li Zengmiao Zhang Yaping Niu Chenchen Li Shaobin Gu 《Journal of food science》2022,87(7):3248-3259
This study aimed to determine the main bioactive components of Cornus officinalis vinegar (COV) and assess the effects of COV on the body weight (BW) and hepatic steatosis in a nonalcoholic fatty liver disease (NAFLD) mouse model. Seven-week-old KM female mice were divided into five treatment groups: (1) Normal control (NC) group, (2) high fat diet (HFD) group, (3) low concentration treatment group (3.5% COV), (4) medium concentration treatment group (5.0% COV), and (5) high concentration treatment group (6.5% COV). Mice in the NC group were fed with a normal chow diet, and those in the other four groups were fed with a HFD known for causing obesity for 10 weeks. Then, mice in the three COV treatment groups were orally administered with COV once a day for 6 weeks. Results showed that the contents of loganin and morroniside in COV reached 16.82 and 51.17 µg/ml, respectively, and COV also contained multiple organic acids. COV significantly reduced BW, abdominal fat weight, liver weight, and the levels of glucose, triglyceride, and low-density lipoprotein cholesterol of serum and increased the levels of high-density lipoprotein cholesterol of serum (p < 0.05). COV also improved the liver function and anti-oxidant activity of liver (p < 0.05). COV treatments increased the interleukin-10 expression and reduced the tumor necrosis factor-α expression in the liver tissue of NAFLD mice (p < 0.05). Histopathological observation revealed that COV suppressed hepatic lipid accumulation and steatosis. The results suggest that COV may contribute to the alleviation of NAFLD and obesity. 相似文献
9.
《Ceramics International》2022,48(6):8297-8305
Pure and Sn/Fe co-doped (0.2 at.% Sn and 0.6 at.% Fe, 0.6 at.% Sn and 0.2 at.% Fe, 1.0 at.% Sn and 1.0 at.% Fe) TiO2 nanoparticles were synthesized via a sol-gel method and subsequently calcined at different temperatures. Furthermore, the particles were analyzed by TG-DSC, XRD, TEM, HRTEM, EDS, SAED and UV–Vis for investigating the influences of dopant and calcination temperature on the thermal effect, composition, morphology, energy band gap (Eg) and the degradation efficiency of methyl orange (MO) under various light irradiations respectively. Results indicated that Sn/Fe co-doping inhibited the crystallization transformation from anatase to rutile phase of TiO2 and decreased the Eg. The increased calcination temperature and Sn/Fe co-doped effect brought about the abnormal grain growth of TiO2 nanoparticles. 0.6 at.% Sn/0.2 at.% Fe and 1.0 at.% Sn/1.0 at.% Fe co-doped TiO2 nanoparticles presented better photocatalytic performance than pure and 0.2 at.% Sn/0.6 at.% Fe co-doped TiO2 nanoparticles under visible light irradiation mainly due to the decreased Eg. On the contrary, 0.2 at.% Sn and 0.6 at.% Fe co-doped TiO2 nanoparticles calcined at 650 °C showed the most excellent photocatalytic performance under UV light irradiation, which was about twice as large as that of pure TiO2 possibly due to the formed hybrid structure of anatase and rutile phase as well as the h+-mediated decomposition pathway. 相似文献
10.
《International Journal of Hydrogen Energy》2022,47(39):17214-17223
The photocatalytic evolution of H2 over La2O3 decorated TiO2 catalyst was examined under solar light. It was observed that during the course of the reaction, the transformation of La2O3/TiO2 into La2O3–TiO2–La2O2CO3 occurred and these species effectively suppressed electron-hole pair recombination by forming electron trapping centres on the surface, resulting in an increased visible light absorption and improved H2 yield. The 2 wt%La2O3/TiO2 nanocomposite demonstrated better H2 yield (~8.76 mmol (gcat)?1) than the bare TiO2 (~1.1 mmol (gcat)?1). The catalyst was stable even after several consecutive recycles with no substantial loss of hydrogen production rate. The H2 rates were correlated with the physicochemical characteristics of the catalysts examined by BET–SA, H2-TPR, XRD, UV-DRS, Raman spectroscopy, FTIR, HRTEM, EPR and PL spectroscopy. 相似文献