P(DBF-VA)型柴油低温流动性改进剂的研制

针对新疆地产柴油蜡含量较高的特点,以游离基聚合法合成了富马酸双链混合酯和醋酸乙烯酯共聚物型[P(DBF-VA)]柴油低温流动改进剂,利用正交实验研究了单体配比,引发剂用量,溶剂用量,聚合温度对聚合物降冷滤效果的影响。共聚物用IR进行表征,利用XRD初步探讨了该降凝剂的降凝机理。结果表明:该剂能使吐哈—10~#、0~#柴油冷滤点降低10℃和7℃;使独山子0~#柴油冷滤点下降12℃;使石化0~#柴油冷滤点下降8℃;使克拉玛依0~#柴油的冷滤点下降8℃。     

Photocatalytic evolution of hydrogen over mesoporous TiO2 supported NiO photocatalyst prepared by single-step sol–gel process with surfactant template

Photocatalytic activity of mesoporous titania supported nickel oxide photocatalyst synthesized by single-step sol–gel (SSSG) process combined with surfactant-assisted template method was investigated for hydrogen evolution from an aqueous methanol solution, in comparison with one prepared by conventional incipient wetness impregnation (IWI) method. In single-step sol–gel process, nickel precursor was introduced into the titania sol prepared with the aid of a surfactant template behaving as pore-controlling agent to attain meso-scaled pore. The single-step sol–gel photocatalyst was experimentally found to enhance the photocatalytic evolution of hydrogen rather than the impregnated one. The optimum level of nickel loading in photocatalytic activity test for single-step sol–gel method was slightly higher than that for incipient wetness impregnation method. Characterization results demonstrated the significant modification of physical characteristics of the single-step sol–gel photocatalyst, anticipated to relating to the observation of higher photocatalytic hydrogen evolution activity.     

PPV Nanotube Sensor Arrays for Explosives Identification by Excitation Wavelength Regulation

The development of sensitive materials for standard and improvised explosives is greatly significant to homeland security. In this paper, the phosphotungstate (NaPT) doped polyphenylene vinylene (PPV) nanotube arrays (NTAs), with excellent optical response, chemical stability, and larger specific surface area, are successfully fabricated by means of the “precursor film” infiltration method. The efficient charge carriers' separation of PPV NTAs can be achieved by doping NaPT to realize the photoelectric detection of explosive vapors. In addition, the identification of six explosives, including ammonium nitrate (AN), dinitrotoluence (DNT), picric acid (PA), p-nitrotoluene (PNT), triacetone triperoxide (TATP), and trinitrotoluene (TNT), can also be realized through the fingerprint atlas. Moreover, the adsorption energy and excited oscillator intensity has also been employed to explain the interaction between NaPT doped PPV nanotube arrays and various explosive molecules. Obviously, the NaPT doped PPV developed has the potential to be used as an explosive sensor.     

喹喔啉类衍生物与甲基噻吩共聚物的合成及性质

在二价镍配合物催化下,2,5-二溴-3-甲基噻吩格氏试剂与5,8-二溴-萘基喹喔啉和5,8-二溴-菲基喹喔啉共聚,得到相应的喹喔啉类共轭共聚物,收率分别为65%和68%。通过FT IR、1H-NM R对聚合物及中间体的结构进行了表征。聚合物的循环伏安图中,分别在0.66 V(Epa)/0.37 V(Epc)(Copo ly-m er I),0.78 V(Epa)/-0.06V(Epc)和1.26(Epa)/0.46(Epc)(Copo lym erⅡ)处观察到氧化还原峰,表明该类聚合物有电化学活性。在紫外-可见光谱中,分别在263 nm,323 nm处(Copo lym erⅠ)和299 nm,402 nm处(Copo lym erⅡ)出现吸收峰。所得聚合物分别在504 nm和513 nm处出现荧光最大发射峰。     

基于场景的面向方面软件体系结构度量方法

软件体系结构的评估为提高软件质量、控制系统复杂性提供保证,但多数单纯基于场景或基于度量的评估技术普遍存在度量角度单一的问题.针对该问题,结合场景技术提出了一种支持面向方面软件体系结构的度量方法.通过一组度量指标对体系结构进行度量并量化其结构特征;引入场景更细粒度地刻画体系结构的质量属性,考察场景在体系结构中的映射程度.最后对某保险案例的体系结构设计方案进行对比与选择,验证了方法的可行性及实用价值.两种技术的结合为更全面地进行面向方面软件体系结构的评估提供支持与参考.     

麻黄碱旋光异构化新工艺研究

介绍了将盐酸L-麻黄碱直接经过乙酰异构化、酸化水解工艺过程异构化为盐酸D-伪麻黄碱的新工艺,其工艺的优化条件是盐酸L-麻黄碱与乙酸酐的配比(摩尔比)为1∶3.5,酰化异构化温度100℃,酰化异构化时间7 h。酸化水解步骤所加入的浓盐酸(36.5%)与原料的配比(摩尔比)1.5∶1,酸化水解温度90℃,酸化水解时间8 h,产品盐酸D-伪麻黄碱收率大于98%。     

可信网络中基于信誉和风险评估的动态信任模型*

针对可信网络不能有效处理恶意节点攻击的问题,综合考虑信任度评估的动态性和风险性,提出一种新的基于信誉和风险评估的动态信任模型。该模型引入惩罚机制、风险机制和推荐实体信任度更新机制,以评估信任关系的复杂性,通过构建直接信任树以存储节点的交互关系,并采用改进的回溯法寻找最佳推荐路径。仿真结果表明,该模型在有效抑制恶意节点上较已有模型有一定的改进。     

OFDM系统相关矩阵的分块结构及同步算法

根据载波加权可增强OFDM系统周期平稳性,实现系统盲同步的基本原理,分析了OFDM系统相关矩阵的分块结构,给出相应系统的盲同步算法.该方法通过检测相关矩阵的分块Toep litz矩阵结构,实现系统定时和载频偏差的估计.同时,在特定系统同步性能交换误码率的情况下通过分析载波加权、系统误码率和载频同步误差之间的互相制约关系,进一步给出了载波加权的确定方法.实验仿真结果表明,采用分块相关矩阵的同步方案与采用循环谱的同步方案相比,可获得更好的系统载频和定时同步效果.     

Formation of bulk ferromagnetic nanostructured Fe_(40)Ni_(40)P_(14)B_6 alloys by metastable liquid spinodal decomposition

Nanostructured Fe40Ni40P14B6 alloy ingots of 3―5 mm in diameter could be synthesized by a metastable liquid state spinodal decomposition method. For undercooling T> 260 K, the microstructure of the undercooled specimen had exhibited liquid state spinodal decomposition in the undercooled liquid state. The microstructure could be described as two intertwining networks with small grains dispersed in them. For undercooling T>290 K, the overall microstructure of the specimen changed into a granular morphology. T...