首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   5846篇
  免费   138篇
  国内免费   117篇
电工技术   247篇
综合类   249篇
化学工业   824篇
金属工艺   240篇
机械仪表   510篇
建筑科学   373篇
矿业工程   499篇
能源动力   388篇
轻工业   453篇
水利工程   64篇
石油天然气   140篇
武器工业   38篇
无线电   250篇
一般工业技术   390篇
冶金工业   146篇
原子能技术   81篇
自动化技术   1209篇
  2024年   4篇
  2023年   41篇
  2022年   93篇
  2021年   115篇
  2020年   115篇
  2019年   109篇
  2018年   105篇
  2017年   141篇
  2016年   153篇
  2015年   151篇
  2014年   244篇
  2013年   376篇
  2012年   260篇
  2011年   391篇
  2010年   245篇
  2009年   319篇
  2008年   320篇
  2007年   291篇
  2006年   296篇
  2005年   278篇
  2004年   288篇
  2003年   243篇
  2002年   216篇
  2001年   157篇
  2000年   127篇
  1999年   140篇
  1998年   151篇
  1997年   105篇
  1996年   100篇
  1995年   93篇
  1994年   78篇
  1993年   79篇
  1992年   53篇
  1991年   48篇
  1990年   27篇
  1989年   33篇
  1988年   21篇
  1987年   21篇
  1986年   16篇
  1985年   24篇
  1984年   8篇
  1983年   7篇
  1982年   12篇
  1981年   2篇
  1979年   2篇
  1977年   2篇
  1974年   1篇
排序方式: 共有6101条查询结果,搜索用时 15 毫秒
1.
The performance of gallium promoted cobalt-ceria catalysts for ethanol steam reforming (ESR) was studied using H2O/C2H5OH = 6/1 mol/mol at 500 °C. The catalysts were synthetized via cerium-gallium co-precipitation and wetness impregnation of cobalt. A detailed characterization by N2-physisorption, XRD, H2-TPR and TEM allowed the normalization of contact time and rationalization of the role of each catalysts component for ESR. The gallium promoted catalyst, Co/Ce90Ga10Ox, was more efficient for the ethanol conversion to H2 and CO2, and the production of oxygenated by-products (such as, acetaldehyde and acetone) than Co/CeO2. The catalytic performance is explained assuming that: (i) bare ceria is able to dehydrogenate ethanol to ethylene; (ii) Ce–O–Ga interface catalyzes ethanol reforming; (iii) both Ce–O–Co and Ce–O–Ga interfaces takes part in acetone production; and (iv) cobalt sites further allow C–C scission. It is suggested that a cooperative role between Co and Ce–O–Ga sites enhance the H2 and CO2 yields under ESR conditions.  相似文献   
2.
Alkaline aqueous solution of sodium borohydride NaBH4 (denoted SB-fuel) is an indirect fuel when it is used to generate H2 by hydrolysis, with the as-generated H2 feeding a fuel cell, and it is a direct fuel when it is an anodic fuel of a direct fuel cell. However, SB-fuel suffers from a major drawback: NaBH4 spontaneously hydrolyzes. Our study falls within this context. We studied the instability, at the NMR scale and over 12 weeks, of a series of SB-fuels (initial NaBH4 concentration from 3.65 to 31.22 wt%, NaOH concentration from 1 to 16 M, and temperature between ?15 and 60 °C) to find the conditions at which SB-fuel can be stored for weeks in relative safety. We found that SB-fuel with a NaOH concentration of ≥8 M is relatively stable under cold conditions (?15 and 4 °C). In these conditions, NaBH4 is not prevented from hydrolyzing, but the reaction is significantly mitigated. Otherwise, our study highlights the gaps in our understanding of the SB-fuel, emphasizes SB-fuel is a new concept of fuel (it should not be seen as any current fuel), and points out the challenges for attaining higher technology readiness levels.  相似文献   
3.
Gd2O3:Eu3+@CsPbBr3 quantum dots (QDs) mesoporous hollow nanocomposites with good luminescent properties and high stability were built. Among which, the hollow Gd2O3:Eu3+ spheres and CsPbBr3 QDs were prepared by urea homogeneous precipitation and hot-injection method, respectively. Finally, the Gd2O3:Eu3+@CsPbBr3 QDs shell–core compounds were constructed through mechanical stirring. The structure, morphology, stability and luminescent properties were studied by Fourier transform infrared spectroscopy (FT-IR), differential scanning calorimetry/thermogravity (DSC/TG), X-ray diffraction (XRD), field-emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), photoluminescence excitation/photoluminescence (PLE/PL) and life decay tools. Compared to the original CsPbBr3 QDs, Gd2O3:Eu3+@CsPbBr3 QDs display better photostability, thermal stability and current stability. The resulting Gd2O3:Eu3+@CsPbBr3 QDs composite exhibits good yellow emission. The Gd2O3:Eu3+@CsPbBr3 QDs mixed silicone resin was directly coated on the blue LED chip, then the w-LED device with the color coordinate of (0.31, 0.32) was successfully assembled. The Gd2O3:Eu3+@CsPbBr3 QDs compounds with excellent luminescent properties and stability are expected to be widely used in lighting and display areas.  相似文献   
4.
Power conversion efficiency (PCE) and stability are two important properties of perovskite solar cells (PSCs). Particularly, defects in the perovskite films could cause the generation of trap states, thereby increasing the nonradiative recombination. To address this issue, suitable dopants can be incorporated to react with non-bonded atoms or surface dangling bonds to passivate the defects. Herein, we introduced TiI4 into CH3NH3PbI3 (MAPbI3) film and obtained a dense and uniform morphology with large crystal grains and low defect density. The champion cell based on 0.5% TiI4-doped MAPbI3 achieved a PCE as high as 20.55%, which is superior to those based on pristine MAPbI3 (17.64%). Moreover, the optimal solar cell showed remarkable stability without encapsulation. It retained 88.03% of its initial PCE after 300 h of storage in ambient. This work demonstrates TiI4 as a new and effective passivator for MAPbI3 film.  相似文献   
5.
《Ceramics International》2022,48(5):5876-5891
Hybrid lead halide perovskite solar cells (PSCs) have experienced a rapid development in the past decade and a certified efficiency up to 25.5% has been achieved. However, the presence of toxic lead component and the inherent poor thermal stability of the organic cations in the hybrid lead halide perovskites obstruct the commercial applications of their corresponding photovoltaic devices. Therefore, fabricating high-efficient all-inorganic lead-free PSCs is a promising direction. This review summarizes the related research progress, which mainly focuses on the structural and optoelectronic properties of inorganic lead-free perovskites and devices. In particular, the strategies for improving the properties and stability of Cs–Sn perovskites, as well as enhancing the photovoltaic performance of the corresponding devices are highlighted. An outlook of challenges and future directions regarding to all-inorganic lead-free PSCs are also proposed.  相似文献   
6.
《Ceramics International》2021,47(18):25769-25776
Lithium-sulfur battery cathodes still remain a challenge on capacity decay due to the shuttle effect even though a series of strategies have been tried. Here we report a novel matryoshka-like CuS@void@Co3O4 architecture of double micro-cubes (μ-cubes) that locks sulfur between the CuS core and the Co3O4 shell. Plenty of existing spaces between the μ-cubes suffice a high loading of sulfur and volumetric accommodation. The robust, double closed cubes configuration greatly enhances the confinement of polysulfides. In parallel, the CuS core increases the electronic conductivity and contributes to additional capacity, while the Co3O4 shell ensures a better interface activity. A high Li+ ion diffusion coefficient is obtained during the sulfur and lithium sulfide transformation. The constructed battery displays an initial capacity up to 1480 mAh g−1, and a Coulombic efficiency (CE) exceeding 99%. A capacity retention higher than 500 mAh g−1 with a CE larger than 99.8% after cycling 400 times at 0.2 C are achieved. In addition, under a temperature of −5 °C, a high capacity of 700 mAh g−1 at 0.2 C after 200 cycles is achieved, indicating a good low-temperature tolerance.  相似文献   
7.
在传统等截面双边四梁微加速度计结构上,以变极距式电容传感器为对象,设计一种菱形变截面梁。为增加梁的稳定性,满足加速度计对不同方向刚度要求,并提高灵敏度,建立加速度计数学理论模型,推导出灵敏度与刚度的关系。建立梁的纯弯曲模型,并基于静电驱动原理,推导出静电刚度公式,确定满足静电刚度小于机械刚度的条件下加速度计量程。结果显示,菱形变截面梁减小了梁的应力集中,使梁两方向的刚度最大化,提高了加速度计灵敏度。  相似文献   
8.
为了提高四轮转向(4WS)汽车的操纵稳定性和主动安全性,建立汽车二自由度四轮转向模型和系统状态方程,应用LQR最优控制理论建立了以横摆角速度和质心侧偏角为优化目标的四轮转向线性控制二次型最优控制模型,并基于路径跟踪策略建立预瞄驾驶员方向控制模型。基于"人-车-路"闭环控制系统,在Matlab/Simulink、CarSim联合仿真环境下对普通前轮转向、前后轮转角比例控制、LQR控制的控制效果进行验证。结果表明:LQR控制器能够很好地改善汽车质心侧偏角和横摆角速度的动态响应特性,高速控制效果最佳,基于LQR控制的4WS汽车具有更好的道路循迹能力、高速稳定性和主动安全性。  相似文献   
9.
高端军事应用环境对测温传感器提出了小结构、高精度、良好的长期稳定性等要求,采用溅射方式制备的薄膜铂电阻元件成为了首选。通过分析薄膜铂电阻元件的结构、工艺,探讨影响稳定性的主要因素,包括薄膜缺陷、杂质、电迁移、结构封装应用与温度应力等。选择薄膜铂电阻在水三相点下的电阻值作为稳定性的比较基准,设计了一款不大于3mK的高精度测试系统。通过对薄膜铂电阻元件进行高温电寿命试验和温度冲击试验,评估得出薄膜铂电阻元件长期稳定性达到10mK,满足设计需求。  相似文献   
10.
Nickel-based catalyst is highly active for hydrogen production through methane cracking reaction at moderate reaction temperature. However, Ni catalyst is easily deactivated by carbon encapsulation. In order to solve this problem, this research studies the effect of nickel precursors—nickel acetate (NA), nickel carbonate (NC) and nickel nitrate (NN)—on the activity and stability of nickel/bimodal porous silica (Ni/BPS) catalyst in methane cracking reaction. It was found that these nickel precursor solutions had different pH values, resulting in different interactions between surface silanol groups of BPS supports and Ni. Among these catalysts, Ni(NC)/BPS catalyst exhibited high nickel dispersion and weak interaction between Ni and BPS support; it then gave the highest CH4 conversion and better stability compared to the other catalysts. In addition, H2 yield of Ni(NC)/BPS catalyst was 2.90 and 1.40 times higher than those of Ni(NA)/BPS and Ni(NN)/BPS catalysts, respectively. Moreover, carbon nanofibers were grown in Ni(NC)/BPS and Ni(NN)/BPS catalysts, whereas carbon nanotubes were formed on Ni(NA)/BPS catalyst, due to the different nickel particle sizes, dispersions, and Ni—BPS support interactions.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号