Preparation and electrochemical characterization of Ti-based amorphous metallic glass with high strength

Ti-based amorphous metallic glasses have excellent mechanical, physical, and chemical properties, which is an important development direction and research hotspot of metal composite reinforcement. As a stable, simple, efficient, and large-scale preparation technology of metallic powders, the gas atomization process provides an effective way of preparing amorphous metallic glasses. In this study, the controllable fabrication of a Ti-based amorphous powder, with high efficiency, has been realized by using gas atomization. The scanning electron microscope, energy-dispersive spectrometer, and X-ray diffraction are used to analyze surface morphology, element distribution, and phase structure, respectively. A microhardness tester is used to measure the mechanical property. An electrochemical workstation is used to characterize corrosion behavior. The results show that as-prepared microparticles are more uniform and exhibit good amorphous characteristics. The mechanical test shows that the hardness of amorphous powder is significantly increased as compared with that before preparation, which has the prospect of being an important part of engineering reinforced materials. Further electrochemical measurement shows that the corrosion resistance of the as-prepared sample is also significantly improved. This study has laid a solid foundation for expanding applications of Ti-based metallic glasses, especially in heavy-duty and corrosive domains.     

高压雾化特性及降尘技术试验研究

通过对不同压力条件下孔径为0.15mm的撞针式高压雾化喷嘴的雾化粒径进行分析,并利用自制的高压雾化降尘试验系统对不同压力条件下的雾化降尘效果进行测试,通过降尘试验结果与雾化效果进行定性、定量分析,指出高压雾化压力与雾化粒径及降尘效果有着正向联系,但雾化压力增加到一定程度,降尘效果增加不再明显,试验研究数据表明该型号高压雾化喷嘴的最佳工作条件应为6MPa。     

两种3D打印用雾化Ti-6Al-4V粉末的对比研究

本研究分别利用水冷铜坩埚真空感应熔炼气雾化(VIGA-CC)和等离子旋转电极(PREP)两种技术制备出球形Ti-6Al-4V合金粉末,作者利用SEM、同步辐射CT扫描-三维重建和氩气含量测试等分析手段对不同粒径的Ti-6Al-4V合金粉末的孔洞缺陷和氩气含量、硬度值进行了表征。实验结果表明, VIGA-CC粉末粒度分布宽,细粉收得率较多,粉末粒度分布在40~180 μm之间, PREP粉末的粒度分布较窄,主要集中在110~180 μm之间；金属粉末内部的孔隙率、气体含量和孔尺寸随着粉末粒度的增大而增大,且同一粒径范围内VIGA-CC粉末的气孔概率多于PREP粉末；随着粉末粒径减小,粉末截面组织逐渐细化,其硬度值逐渐升高,整体上VIGA-CC粉末硬度值高于PREP粉末。     

小桐子油及其生物柴油在旋流喷嘴中雾化特性数值模拟

为了掌握入射压力对生物质燃油在旋流喷嘴中雾化特性的影响规律,在不同入射压力条件下,采用Fluent数值模拟的方法对小桐子油和小桐子生物柴油进行雾化过程模拟仿真研究。结果表明:使用的旋流雾化喷嘴比普通喷嘴对索特平均直径(D32)有更好的优化效果,内螺旋结构增强了雾化的湍流强度,使得气液两相混合及对雾化液滴的破碎效果更好;在等温条件下,不同入射压力对D32、雾化总表面积、雾化速度、雾化贯穿距影响较大。入射压力越大,D32越小;入射压力越大,雾化总表面积、雾化速度、雾化贯穿距越大。入射压力对D32的影响存在临界值,即小桐子油雾化入射压力达到0.8 MPa、小桐子生物柴油雾化入射压力达到0.7 MPa后,D32趋于稳定,不会随入射压力的增大继续减小;通过曲线拟合及雾滴粒径数量密度分析,得到了不同入射压力距离喷嘴不同位置处轴向D32变化的拟合方程及雾化液滴不同粒径数量密度分布情况。     

Investigations on Emission Characteristics of a Liquid-Fueled Trapped Vortex Combustor

The combustion and emission formation process of liquid fuel in the trapped vortex combustor(TVC)are very complicated.A trapped vortex combustor with replaceable bluff-bodies was designed to investigate these processes.The bluff-body widths varied from 0.021 m to 0.036 m.Experimental tests were carried out.Liquid RP-3 aviation kerosene was used in the tests.Emissions were measured under atmospheric pressure.The combustion process was analyzed theoretically in the viewpoints of relative evaporation time,mixing time and reaction time.Numerical simulations were also conducted to help analyze the formation and depletion processes of pollutants in TVC.The results reveal that atomization was a critical factor for formation and depletion processes of pollutants.By controlling mixing speed of burned and unburned gases and thus fuel-air uniformity,turbulence intensity could also affect emission levels.In addition,residence time also affected the emissions by affecting combustion completeness and the time for NOx formation.All these factors were combined in a complicated way to affect combustion process and pollutant emissions.     

雾化溶液除湿系统最适液滴特性

液滴特性是影响雾化溶液除湿系统性能的关键因素，但目前适用于该类除湿系统的最佳液滴特性尚不明确。为此，本文基于雾化溶液除湿过程所遵循的质量、能量平衡，借助数值模拟及正交设计，以超声波雾化溶液除湿系统（UADS）为例，对除湿剂液滴在各典型粒径、温度、质量分数等特性组合下的除湿性能进行研究。结果表明：随着液滴粒径的减小、溶液质量分数的增加以及液滴温度的降低，雾化除湿系统性能虽均有所提升，但其改善作用依次减弱；通过正交设计优化液滴特性组合，可显著提升雾化除湿系统性能。与液滴优化前相比，UADS系统在本文所得最适液滴特性下的性能，比传统典型性能（除湿速率为7.5g/s，除湿效率为48.5%）大幅提升，除湿速率提升31.04%，除湿效率改善达24.63%。研究可为雾化溶液除湿系统液滴特性的合理优选，并进一步提高系统的除湿性能及经济性提供积极参考。     

Refinement of primary carbides in AISI DC 53 cold work tool steel by thin section copper permanent mould casting and water atomization

In this study, as alternative methods to conventional production methods involving thin section copper permanent mould casting (fast solidification) and water atomization (rapid solidification) of AISI DC 53 cold work tool steel have been investigated. Thin slabs obtained by copper mould casting was homogenized at 1150 °C for one hour and then hot rolling was be applied. After hot rolling, conventional heat treatment have been applied to thin slabs. The same heat treatment procedure have been performed for a commercially available AISI DC 53 which is manufactured by thick section ingot casting and rolling. In order to investigate also the effect of rapid solidification on AISI DC 53 tool steel, steel powder was produced by water atomization technique. Experiments have revealed that thin steel slabs in permanent copper mould and rapidly solidified tool steel powder by water atomization have a more refined primary M₇C₃ carbides than commercially available steel.     

内热型超声雾化溶液再生系统最优内热量的研究

基于质量守恒、能量守恒定律，建立了内热型超声雾化溶液再生系统（IH-UARS）的再生性能预测模型并进行了充分的实验验证，通过研究不同内热量下IH-UARS的再生性能及其变化规律，寻求系统所需的最佳内热量并明确其可能的影响因素。结果表明：IH-UARS系统存在最优的内热量范围，使其再生系统性能最佳；所需最优内热量随着再生溶液流量增大呈显著的对数增长，但受空气流量的影响较弱；在该研究中的标准工况下，IH-UARS所需最优内热量约为275~350 W。此外研究发现：内热量的增长有益于促进初始浓度较高的溶液进一步浓缩再生，如当IH-UARS中内热量增至800 W时，其初始浓度为36%的溶液比24%的溶液浓度增量指标改善幅度高37%。研究所得结果可对提高溶液再生性能及经济性提供积极参考。     

纳米结构9Cr-ODS钢的制备工艺

本文对利用雾化法直接制备出Y、Ti过饱和固溶的粉体合金,经短时机械合金化和热等静压成型制备纳米结构9Cr-ODS钢技术进行了研究.采用扫描电镜和X射线衍射研究雾化合金粉与短时球磨后雾化合金粉的形貌特征与组织的演化.通过高分辨透射电镜和电子背散射衍射研究热固化成型后ODS钢的微观组织.测试了雾化粉和球磨8 h合金粉热固化成型样品的应力-应变曲线.结果表明,用短时球磨雾化粉制备的ODS钢晶粒尺寸更加细小、形成高密度纳米尺寸的析出相.与常规方法制备的ODS钢相比,抗拉强度略高、塑性显著提高、球磨时间大幅缩短.