全文获取类型
收费全文 | 17705篇 |
免费 | 2762篇 |
国内免费 | 1442篇 |
专业分类
电工技术 | 2324篇 |
技术理论 | 2篇 |
综合类 | 1833篇 |
化学工业 | 3187篇 |
金属工艺 | 752篇 |
机械仪表 | 1767篇 |
建筑科学 | 1493篇 |
矿业工程 | 744篇 |
能源动力 | 613篇 |
轻工业 | 282篇 |
水利工程 | 629篇 |
石油天然气 | 683篇 |
武器工业 | 283篇 |
无线电 | 2345篇 |
一般工业技术 | 2342篇 |
冶金工业 | 429篇 |
原子能技术 | 203篇 |
自动化技术 | 1998篇 |
出版年
2024年 | 81篇 |
2023年 | 445篇 |
2022年 | 630篇 |
2021年 | 780篇 |
2020年 | 876篇 |
2019年 | 713篇 |
2018年 | 665篇 |
2017年 | 786篇 |
2016年 | 765篇 |
2015年 | 901篇 |
2014年 | 1137篇 |
2013年 | 1205篇 |
2012年 | 1442篇 |
2011年 | 1512篇 |
2010年 | 1031篇 |
2009年 | 1049篇 |
2008年 | 952篇 |
2007年 | 1110篇 |
2006年 | 946篇 |
2005年 | 828篇 |
2004年 | 690篇 |
2003年 | 558篇 |
2002年 | 473篇 |
2001年 | 385篇 |
2000年 | 330篇 |
1999年 | 282篇 |
1998年 | 230篇 |
1997年 | 182篇 |
1996年 | 187篇 |
1995年 | 151篇 |
1994年 | 135篇 |
1993年 | 94篇 |
1992年 | 94篇 |
1991年 | 67篇 |
1990年 | 52篇 |
1989年 | 44篇 |
1988年 | 32篇 |
1987年 | 10篇 |
1986年 | 5篇 |
1985年 | 5篇 |
1984年 | 8篇 |
1983年 | 4篇 |
1982年 | 7篇 |
1980年 | 5篇 |
1979年 | 8篇 |
1978年 | 3篇 |
1962年 | 1篇 |
1961年 | 1篇 |
1959年 | 2篇 |
1951年 | 6篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
The coupling of reaction and diffusion between neighboring active sites in the catalyst pore leads to the spatiotemporal fluctuation in component concentration, which is very important to catalyst performance and hence its optimal design. Molecular dynamics simulation with hard-sphere and pseudo-particle modeling has previously revealed the non-stochastic concentration fluctuation of the reactant/product near isolated active site due to such coupling, using a simple model reaction of A → B in 2D pores. The topic is further developed in this work by studying the concentration fluctuation due to such coupling between neighboring active sites in 3D pores. Two 3D pore models containing an isolated active site and two adjacent active sites were constructed, respectively. For the isolated site, the concentration fluctuation intensifies for larger pores, but the product yield decreases, and for a given pore size, the product yield reaches a peak at a certain reactant concentration. For two neighboring sites, their distance (d) is found to have little effect on the reaction, but significant to the diffusion. For the same reaction competing at both sites, larger d leads to more efficient diffusion and better overall performance. However, for sequential reactions at the two sites, higher overall performance presents at a smaller d. The results should be helpful to the catalyst design and reaction control in the relevant processes. 相似文献
2.
为缓解我国水、能源和粮食资源紧张问题,促进资源可持续利用,构建水-能源-粮食系统,利用耦合协调度模型对我国的30个省(自治区、直辖市)进行测算,并利用空间杜宾模型分析主要影响因素。结果表明:2003—2017年,我国能源、粮食评价[JP]指数高于水资源评价指数,系统综合评价指数逐年递增;大部分省份耦合协调度处于初级协调水平且呈现逐年上升的态势,个别省份耦合协调度濒临失调;耦合协调度空间自相关性较强,虽有明显波动,但是呈现逐年加强的态势;影响耦合协调度的主要因素有从业人口数、固定资产投资额、人均生产总值、人口总数、[JP]文盲人口占比、工业污染排放、城镇化。 相似文献
3.
《International Journal of Hydrogen Energy》2022,47(32):14580-14588
Recovery of hydrogen (H2) from H2-containing gas mixtures has great significance for energy conservation, cost reduction and benefit increase. However, the common separation methods have the ubiquitous problem due to phase equilibrium principle and results in the conflict between H2 concentration and H2 recovery rate in the product gas. Consequently, an innovative conception of hydrate-membrane coupling approach is proposed in this work. In the separation process, hydration and membrane permeation two separation driving forces coexist to achieve the aim of strengthening mass transfer kinetics. H2 and non-H2 components (hydrocarbons) are synchronously and directionally selected by membrane and hydrate to improve different phase compositions. Therefore, the gas in feed side could keep relatively high two separation driving forces (H2 fugacity and hydrocarbons fugacity). The results show that the coupling method could synchronously increase both the concentration and the recovery rate of H2 in the product gas. At the same time, the volume and concentration of the hydrocarbons in hydrate both increases effectively. It indicates that hydrate and membrane separation methods support each other in the separation process. The hydrate-membrane coupling method fundamentally solves the issue of the decreasing driving force resulting from single separation method and phase equilibrium relationship. 相似文献
4.
为了解决传统教学无法全面培养人才的问题,采用"课程融合+时空耦合+过程结合"的方式开展人才培养研究。以注射模设计与制造生产过程为导向,构建大项目牵引下的跨越课程、跨越学期的课程融合新模式,利用信息通信技术及互联网平台,将互联网与传统教学进行深度融合,创造新的教学生态,构建多元多维互动的时空耦合教学新关系,以全方位评价为引导,构建课程多元多维的评价新机制。以3个班级为对象开展不同模式下的教学,对试验班级成绩进行分析,研究结果表明:课程融合+时空耦合+过程结合新模式培养的学生更好地完成了综合项目,获得了较好的教学效果。 相似文献
5.
Suzuki-Miyaura (S-M) is regarded the most powerful way for synthesis biaryls, triaryls, or incorporating of substituted aryl moieties in organic preparation by the cross-coupling of aryl boronic acid with aryl halides using the Pd catalyst. This work reports the combining of the hydrothermal and microwave-assisted protocol to convert the glucose to magnetic carbon spheres (Fe3O4-CSPs) decorated with Pd nanoparticles (NPs) as the catalyst for Suzuki-Miyaura cross-coupling reactions. The physicochemical properties in the produced composite were examined using FESEM, HRTEM, nitrogen isotherms, Raman spectroscopy, FTIR, XPS, and XRD. The as-fabricated composite Pd/Fe3O4-CSPs is mostly spherical with a core–shell structure and possesses a great surface area of 253.2 m2·g-1. Its catalytic performance demonstrates that the composite has excellent stability and high tolerance Suzuki-Miyaura cross-coupling reactions in 30 min at 80 ℃. Both activated and deactivated aryl halides provided excellent yield. The as-fabricated catalyst was recycled for up to four catalytic cycles without a substantial decline in performance. Moreover, this research offers a facile roadmap for synthesizing Pd/Fe3O4-CSPs composites and promoting the practical implementation of Pd/Fe3O4-CSPs catalysts for organic transformation processes. 相似文献
6.
7.
Matrix Manipulation of Directly-Synthesized PbS Quantum Dot Inks Enabled by Coordination Engineering
Fei Li Yang Liu Guozheng Shi Wei Chen Renjun Guo Dong Liu Yaohong Zhang Yongjie Wang Xing Meng Xuliang Zhang You Lv Wei Deng Qing Zhang Yao Shi Yifan Chen Kai Wang Qing Shen Zeke Liu Peter Müller-Buschbaum Wanli Ma 《Advanced functional materials》2021,31(45):2104457
The direct-synthesis of conductive PbS quantum dot (QD) ink is facile, scalable, and low-cost, boosting the future commercialization of optoelectronics based on colloidal QDs. However, manipulating the QD matrix structures still is a challenge, which limits the corresponding QD solar cell performance. Here, for the first time a coordination-engineering strategy to finely adjust the matrix thickness around the QDs is presented, in which halogen salts are introduced into the reaction to convert the excessive insulating lead iodide into soluble iodoplumbate species. As a result, the obtained QD film exhibits shrunk insulating shells, leading to higher charge carrier transport and superior surface passivation compared to the control devices. A significantly improved power-conversion efficiency from 10.52% to 12.12% can be achieved after the matrix engineering. Therefore, the work shows high significance in promoting the practical application of directly synthesized PbS QD inks in large-area low-cost optoelectronic devices. 相似文献
8.
《Ceramics International》2022,48(7):9527-9533
In this work, a magnetodielectric coupling observed in barium titanate–cobalt ferrite composites synthesized using high-energy ball milling assisted via a thermal treatment is discussed. Vibrating sample magnetometry and dielectric spectroscopy showed that multiferroic composites possess both ferromagnetic and dielectric behaviors inherited from the parent ferromagnetic cobalt ferrite and ferroelectric barium titanate phases. The magnetocapacitance (up to 35%) recorded for x = 0.3, (1-x)BaTiO3–xCoFe2O4, can be attributed to the spin-dependent filtering mechanism. The composite with the aforementioned composition exhibited a homogeneous matrix–particle composite microstructure, which was achieved via high-energy ball milling during the mixing stage. 相似文献
9.
A new design method was proposed in this article to insert transmission zeros in the broadband filters. In this method, the coupling line was connected to a certain position on the resonator. And then the coupling strength was adjusted by the connecting position. The open end of the resonator was hung and then the cross‐coupling was introduced to realize transmission zeros. This coupling method could add an adjustable parameter to improve the freedom of design and convenient to insert the transmission zeros. To verify this method, a highly selective coupled‐line microstrip filter with two transmission zeros was designed, fabricated, and measured. The measured results were in good agreement with the simulated ones. The return and insertion losses of the broadband filter were better than 18 and 2 dB, respectively. The relative bandwidth of the filter (FBW) was more than 68%. The rectangular coefficient (30 dB:1 dB) was less than 1.21. 相似文献
10.
采用有限元分析方法,研究了一种n型压电半导体纳米线(氧化锌)的电热耦合性能,分析了外部温度对氧化锌纳米线内部机械场、电场及电流场分布的影响,并讨论了本构方程线性化对电学参数的影响。研究结果表明,温度对氧化锌纳米线的电场、载流子浓度和电流密度影响很大,采用线性本构和非线性本构求得的电场、电子浓度和电流密度最大相差分别为24%,32%和68%,基于非线性本构分析压电半导体的电学性能会引起很大误差。该研究结果可为压电半导体器件利用温度调控电场、电流提供理论依据。 相似文献