The Clausius inequality corrected for heat transfer involving radiation

The objective of this paper is to prove that the Clausius inequality must be re-stated to have general applicability for heat transfer involving radiative fluxes. The integrand (đQ/T) of the Clausius expression applies to heat conduction and convection, but does not hold for most radiative transfer scenarios, with the exception of reversible infinitesimal net blackbody radiation transfer. In other cases involving radiative transfer, the equality holds for a cycle even though irreversible heat addition by radiative transfer occurs. This is without the erroneous presumption of entropy destruction anywhere in the cycle. Thus, the Clausius inequality indicates reversibility for a cycle that includes an irreversible process. Further, in some radiative cases the quantity đQ/T, where T is the boundary temperature, is not the entropy transfer at the system boundary, and in fact, primarily represents entropy production within the system. It is also clear that in another case considered, the quantity đQ/T had no physical meaning whatsoever. Consequently, the Clausius expression has been re-stated so that it is applicable to cycles with processes involving any form of heat transfer. A new integrand (đQ_cc/T + đS_Net,Rad) is presented, allowing the Clausius inequality to generally apply to all heat transfer scenarios. The work in this paper emphasizes the need to re-state other fundamental equations allowing applicability to all heat transfer processes, and draws attention to the unique character of radiative entropy calculations.     

Coupling of free surface and groundwater flows

In this paper we present some preliminary results about the coupling of shallow water equations for free surface flows and Darcy equation for groundwater flows. A suitable set of interface conditions is discussed: the Beavers and Joseph formula for the bottom stress is used. An iterative algorithm to solve the coupled problem is proposed and some numerical results are presented.     

参数三次B样条曲线的一种整体光顺方法

本文在能量法的基础上，提出了一种新的目标函数，给出了参数三次Ｂ样条曲线的一种新的整体光顺方法。利用这种方法得到的曲线不仅具有较小的应变能，而且曲率变化比较均匀，具有很好的光顺效果。该方法能推广到对曲面的光顺。     

石油企业办社会的“悖理行为”辨疑

企业办社会虽与市场经济的客观要求相悖，但石油企业大量办社会的事实仍揭示了所具备的理性面。认为国家作为不受所有者监督的代理者对石油企业的要求，石油企业的行业特性以及在传统体制下长期运作所成的定热是石油企业办社会的主要原因。     

Crystallization behavior of star-shaped poly(ethylene oxide) with cubic silsesquioxane (CSSQ) core

The crystallization behavior of well-defined star-shaped cubic silsesquioxane-poly(ethylene oxide) (CSSQ-PEO) and linear PEO were studied in terms of differential scanning calorimetry (DSC) and wide-angle X-ray scattering (WAXS). It was found in DSC analysis that the glass transition temperature (T_g) and the crystallization temperature (T_c) of CSSQ-PEO are different from those of linear PEO. The presence of CSSQ in PEO reduced the overall crystallization growth rate. This effect can be ascribed to the reduction of the mobility of the PEO crystallites in the presence of CSSQ and the star structure of the polymer. The Ozawa method is qualitatively satisfactory for describing the nonisothermal crystallizations of linear PEO and CSSQ-PEO. The presence of CSSQ leads to the diffusion- and nucleation-controlled mechanisms in the crystallization process of CSSQ-PEO whilst only the nucleation-controlled mechanism was observed in the case of linear PEO. The apparent activation energy required for crystallization was calculated using the Kissinger method. The isothermal crystallization morphology of PEO and CSSQ-PEO were also examined by cross-polarizing optical microscopy (CPOM). The CPOM images indicated the spherulite growth is slower in CSSQ-PEO as compared to linear PEO. It was also investigated that more number of PEO spherulites in CSSQ-PEO were observed, which sizes are markedly smaller than the spherulites developed in linear PEO. Wide-angle X-ray scattering (WAXS) studies showed that the crystallization peaks for linear PEO and CSSQ-PEO appeared at different temperature revealing the crystallization process and crystal growth rate are different from each other. However, no significant distortion of the crystal structure of PEO was evaluated in the presence of CSSQ.     

Law,liability and expert systems

This paper examines some of the possible legal implications of the production, marketing and use of expert systems. The relevance of a legally useful definition of expert systems, comprising systems designed for use both by laymen and professionals, is related to the distinctions inherent in the legal doctrine underlying provision of goods and provision of services. The liability of the sellers and users of, and contributors to, expert systems are examined in terms of professional malpractice as well as product liability. A recurring theme indicates that legislators may be inclined to restrict possibilities of liability suits in order to avoid disincentives to the creation of expert systems.     

工程招投标中的违法现象及对策

在分析工程招投标中的违法现象及产生原因的基础上，提出相应对策和减少违法投标的措施。     

立方相GaN的持续光电导

研究了金属有机物化学气相外延 (MOVPE)方法生长的非故意掺杂的立方相 Ga N的持续光电导效应 .在六方相 Ga N中普遍认为持续光电导效应与黄光发射有关 ,而实验则显示在立方 Ga N中 ,持续光电导效应与其中的六方相 Ga N夹杂有关系 ,而与黄光发射没有关系 .文中提出 ,立方相 Ga N与其中的六方相 Ga N夹杂之间的势垒引起的空间载流子分离是导致持续光电导现象的物理原因 .通过建立势垒限制复合模型 ,解释了立方相 Ga N的持续光电导现象的物理过程 ,并对光电导衰减过程的动力学作了分析 .对实验数据拟合的结果证明以上的模型和推导是与实验相符的 .     

A new ‘Tailor-made’ methodology for the mechanical behaviour analysis of rubber-like materials: II. Application to the hyperelastic behaviour characterization of a carbon-black filled natural rubber vulcanizate

The purpose of this paper is the modelling of the mechanical behaviour of an elastomeric material, through detailed experimental and numerical procedures, specific to large strains. The experimental technique is based on in-plane kinematics measurements using a speckle extensometer, from which the whole two-dimensional field of in-plane displacements is obtained by a digital image processing [Polymer (2002)]. This part of the work concerns the identification of the constitutive equation for a carbon black natural rubber (NR) vulcanizate. We start by quoting some theoretical considerations relative to rubber elasticity and stress-softening effect, which is the counterpart of the filler reinforcement. Then, we describe the experimental procedure and present data for both non-preconditioned and preconditioned samples. Next, the identification of the constitutive law parameters using a minimization algorithm is driven. Finally, we present the validation of the constitutive model, by its implementation into the finite element code SYSTUS and the numerical simulation of the response of a double edge notched tensile (DENT) specimen.     

SIMILARITY LAW OF FLUCTUATING PRESSURE WITHIN HYDRAULIC JUMP AREA

Through a series of model tests of five scales for 2-D free hydraulic jump, the da-ta of fluctuating pressure acting on the floor level within the hydraulic jump were obtained. Dur-ing the experiments, Froude number varied from 2.94 to 8.61, and Reynolds number rangedfrom 2×10~4 to 6×10~5. Experiment results indicate that the amplitude scale of fluctuating pres-sure is the length scale of model, i. e. P'=L, which agrees with gravity similarity law: Thefrequency scale of the fluctuating pressure is a unity i. e., f=1, which does not satisfy thegravity similarity law.