Ring‐opening polymerization of lactones initiated by diphenylzinc–coinitiator systems

Diphenylzinc, alone or in combination with water and butanone as coinitiators, was used as a polymerization initiator system for a variety of lactones at varying temperatures. The resulting data indicate that the course of the polymerization is greatly influenced by the lactone structure, as well as by the molar ratio of coinitiator to diphenylzinc. When used alone, diphenylzinc exhibited high activity as an initiator in δ‐valerolactone polymerizations, although it was less efficient when used in the β‐butyrolactone and the β‐propiolactone polymerizations. Activity in the polymerization of β‐lactones was increased by adding small amounts of butanone or water. It was also observed that the diphenylzinc–butanone combination was more effective than the diphenylzinc–water mixture in the polymerizations of β‐butyrolactone and β‐propiolactone. Copyright © 2003 Society of Chemical Industry     

黄河流域委属大河控制站站网布局分析检验与调整

简要论述了黄河流域委属大河控制站的基本情况，通过资料分析，按“直线原则”计算了黄河大河控制站布站数目的上、下限，并调查分析落实了各河段近期和中长期治理开发对水资料的需求，确定各河段测站数目的采用值；对照现有站数，结合测站位置，功能，测验，生活条件等，逐段逐站进行审查，综合评估，决定测站的撤，迁，留，并对密度不足的河段提出了设站意见。     

南水北调西线工程水环境影响分析

南水北调西线工程调水后，引水坝址下游局部河段水量明显减少，但影响范围和程度十分有限。随着两岸环保力度的加大，排污量的减少，径流量减少对局部江段水质的不利影响，可得到控制。预估调水后下游水质不会发生类别变化。     

马家河水电站的设计

马家河水电站通过在马家河和毛家河上游分别建底栏栅坝和低拱坝 ,经各自的引水系统将水引至两河口汇合流入前池发电。本文介绍了电站的开发方案 ,厂区、引水工程和取水枢纽的布置和设计     

Ring‐opening polymerization of D,L‐lactide by rare earth 2,6‐dimethylaryloxide

Ring‐opening polymerization of D,L ‐lactide (LA) has been successfully carried out by using rare earth 2,6‐dimethylaryloxide (Ln(ODMP)₃) as single component catalyst or initiator for the first time. The effects of different rare earth elements, solvents, monomers and catalyst concentration as well as polymerization temperature and time on the polymerization were investigated. The results show that La(ODMP)₃ exhibits higher activity to prepare poly(D,L ‐lactide) (PLA) with a viscosity molecular weight of 4.5 × 10⁴ g mol^?1 and the conversion of 97 % at 100 °C in 45 min. The catalytic activity of Ln(ODMP)₃ has following sequence: La > Nd > Sm > Gd > Er > Y. A kinetic study has indicated that the polymerization is first order with respect to both monomer and catalyst concentration. The apparent activation energy of the polymerization of LA with La(ODMP)₃ is 69.6 kJ mol^?1. The analyses of polymer ends indicate that the LA polymerization proceeds according to ‘coordination–insertion’ mechanism with selective cleavage of the acyl–oxygen bond of the monomer. Copyright © 2004 Society of Chemical Industry     

火焰图像特征在火灾数字图像识别中的运用

火焰尖角数目和圆形度是早期火灾火焰的主要特征,本文主要论述了如何在数学形态学基础上,利用火灾火焰的两个特点判断和识别早期火情。实验中,对火焰的二值图像进行开运算,即先腐蚀,再膨胀,目的是为了对火焰图像进行形态学滤波,去噪。从实验结果可以看出,该算法可以很好的识别火焰和干扰源。     

基于ANSYS有限元分析深水墩施工技术研究

介绍了丹江口二桥深水墩基础施工平台的设计，重点介绍利用ANSYS通用有限元程序对施工平台的施工过模拟分析，以及对分析结果的总结。     

苯并口恶嗪-环氧化合物-胺类催化剂体系开环聚合反应的研究

采用TLC，GPC，1H－NMR及IR等分析方法，对苯并恶嗪－环氧化合物－胺类催化剂体系的聚合反应进行了研究，表征了产物结构，并探讨了聚合反应机理，结果表明，苯并恶唪－环氧化合物体系在胺类催化剂如苄胺，咪唑的作用下，能发生开环聚合反应，生成低分子量的聚合物。     

落脚河水电站引水发电系统的调节保证计算分析

水轮发电机组在运行中遇到启动、正常停机、增减负荷、事故甩负荷等工况变化时，经常会引起引水发电系统的水力过渡过程，所以在设计中必须通过调节保证计算以选择合适的导叶调节规律及其调节时间，从而优化压力引水系统的运行工况，使水电站的水工建筑物布置既经济合理又安全可靠。     

黑河右岸溢洪洞左导墙优化试验

黑河水利枢纽右岸溢洪洞为缩短引渠左导墙的长度,减少施工开挖量,降低施工难度,减少工程投资,进行优化试验.通过对7种不同的方案对比分析,选择了合适的体型,满足了工程要求.