Ring‐opening polymerization of lactones initiated by diphenylzinc–coinitiator systems

Diphenylzinc, alone or in combination with water and butanone as coinitiators, was used as a polymerization initiator system for a variety of lactones at varying temperatures. The resulting data indicate that the course of the polymerization is greatly influenced by the lactone structure, as well as by the molar ratio of coinitiator to diphenylzinc. When used alone, diphenylzinc exhibited high activity as an initiator in δ‐valerolactone polymerizations, although it was less efficient when used in the β‐butyrolactone and the β‐propiolactone polymerizations. Activity in the polymerization of β‐lactones was increased by adding small amounts of butanone or water. It was also observed that the diphenylzinc–butanone combination was more effective than the diphenylzinc–water mixture in the polymerizations of β‐butyrolactone and β‐propiolactone. Copyright © 2003 Society of Chemical Industry     

黄河流域委属大河控制站站网布局分析检验与调整

简要论述了黄河流域委属大河控制站的基本情况，通过资料分析，按“直线原则”计算了黄河大河控制站布站数目的上、下限，并调查分析落实了各河段近期和中长期治理开发对水资料的需求，确定各河段测站数目的采用值；对照现有站数，结合测站位置，功能，测验，生活条件等，逐段逐站进行审查，综合评估，决定测站的撤，迁，留，并对密度不足的河段提出了设站意见。     

马家河水电站的设计

马家河水电站通过在马家河和毛家河上游分别建底栏栅坝和低拱坝 ,经各自的引水系统将水引至两河口汇合流入前池发电。本文介绍了电站的开发方案 ,厂区、引水工程和取水枢纽的布置和设计     

Ring‐opening polymerization of D,L‐lactide by rare earth 2,6‐dimethylaryloxide

Ring‐opening polymerization of D,L ‐lactide (LA) has been successfully carried out by using rare earth 2,6‐dimethylaryloxide (Ln(ODMP)₃) as single component catalyst or initiator for the first time. The effects of different rare earth elements, solvents, monomers and catalyst concentration as well as polymerization temperature and time on the polymerization were investigated. The results show that La(ODMP)₃ exhibits higher activity to prepare poly(D,L ‐lactide) (PLA) with a viscosity molecular weight of 4.5 × 10⁴ g mol^?1 and the conversion of 97 % at 100 °C in 45 min. The catalytic activity of Ln(ODMP)₃ has following sequence: La > Nd > Sm > Gd > Er > Y. A kinetic study has indicated that the polymerization is first order with respect to both monomer and catalyst concentration. The apparent activation energy of the polymerization of LA with La(ODMP)₃ is 69.6 kJ mol^?1. The analyses of polymer ends indicate that the LA polymerization proceeds according to ‘coordination–insertion’ mechanism with selective cleavage of the acyl–oxygen bond of the monomer. Copyright © 2004 Society of Chemical Industry     

火焰图像特征在火灾数字图像识别中的运用

火焰尖角数目和圆形度是早期火灾火焰的主要特征,本文主要论述了如何在数学形态学基础上,利用火灾火焰的两个特点判断和识别早期火情。实验中,对火焰的二值图像进行开运算,即先腐蚀,再膨胀,目的是为了对火焰图像进行形态学滤波,去噪。从实验结果可以看出,该算法可以很好的识别火焰和干扰源。     

苯并口恶嗪-环氧化合物-胺类催化剂体系开环聚合反应的研究

采用TLC，GPC，1H－NMR及IR等分析方法，对苯并恶嗪－环氧化合物－胺类催化剂体系的聚合反应进行了研究，表征了产物结构，并探讨了聚合反应机理，结果表明，苯并恶唪－环氧化合物体系在胺类催化剂如苄胺，咪唑的作用下，能发生开环聚合反应，生成低分子量的聚合物。     

黑河右岸溢洪洞左导墙优化试验

黑河水利枢纽右岸溢洪洞为缩短引渠左导墙的长度,减少施工开挖量,降低施工难度,减少工程投资,进行优化试验.通过对7种不同的方案对比分析,选择了合适的体型,满足了工程要求.     

针梁台车在大花水水电站引水隧洞混凝土衬砌施工中的改进

大花水水电站引水隧洞由于前期开挖工期略有滞后，为加快施工进度，结合全圆断面的施工特点，大部分引水隧洞采用了全圆针梁穿行式钢模台车进行混凝土衬砌。通过各参建单位对针梁台车的运用和改进，有效地提高了引水隧洞混凝土的衬砌速度，并确保了工程质量。     

Determining stress intensity factors of composites using crack opening displacement

The main purpose of this paper is to find the mixed-mode stress intensity factors of composite materials using the crack opening displacement (COD). First, a series solution of the composite material with a crack was used to evaluate COD values. Then, the least-squares method was used to calculate mixed-mode stress intensity factors. This algorithm can be applied to any method that generates or measures COD values. The major advantage of this method is that COD values very near the crack tip are not necessary. Both finite element simulations and laboratory experiments were applied to validate this least-squares method with acceptable accuracy if the even terms of the series solution are removed.     

浅谈南水北调工程中招标代理机构的自身建设

在市场经济条件下,随着水利工程建设市场的不断规范和完善,招标代理机构如何在市场竞争中开展招标代理业务,其自身建设就显得尤为重要。现结合南水北调工程实际,提出了招标代理机构应从法律意识、诚实信用、专业特长、激励机制和沟通协调等5个方面加强自身建设,以便能在南水北调工程建设中更好地发挥作用。