Melting process and melt structure of fly ash/magnesium slag blends for the production of inorganic fibers

Fiber production from inorganic industrial solid wastes is an effective waste management strategy. Because of cost considerations, most enterprises generally use local solid wastes as raw materials to produce fibers. In this study, we explored the feasibility of producing fibers using fly ash and magnesium slag. The results show that the melting temperature of the blends composed of fly ash, magnesium slag, and a small amount of calcined dolomite first decreased and then increased with an increase in acidity coefficient (M_k) from 1.0 to 2.4_. The samples could form a eutectic system in the M_k range of 1.4–1.8, and therefore have a relatively low melting temperature in this M_k range. Fly ash could react with magnesium slag and calcined dolomite to form akermanite, gehlenite-magnesium, and anorthite at temperatures close to the melting temperature; therefore, these crystalline phases were the main reaction products formed in the samples with M_k values lower than 1.80. Anorthite reacted further with some Na-containing and Si-containing spieces to produce labradorite. Thus, the content of anorthite and labradorite rapidly increased and they became the major crystal phases in the blend samples with M_k values greater than 1.80. MAS-NMR spectroscopic analysis revealed that the network structure of the melts depended on the ratio of bridging oxygen to non-bridging oxygen; a high ratio of bridging oxygen to non-bridging oxygen could lead to the formation of a dense network structure in the melt. The blends of fly ash and magnesium slag can be used to produce wool fibers and continuous fibers. In addition, the suitable temperature ranges for the production of both types of fibers were determined. The drawing temperature for continuous fiber production depended on the degree of polymerization and structure of the melt.     

机械活化对粉煤灰提铝影响研究

为提高粉煤灰中铝提取率, 采用机械活化对粉煤灰进行预处理, 探讨了机械活化对粉煤灰焙烧-酸浸效果的影响。结果表明: 机械活化能提高粉煤灰比表面积、增加反应活性点, 促进活化反应的进行; 通过机械活化, 在Na₂CO₃与Al₂O₃物质的量比1.6、850 ℃下焙烧50 min后酸浸, 铝浸出率达到91.58%。     

Preparation of magnetic zeolite/chitosan composite using silane as modifier for adsorption of Cr(VI) from aqueous solutions

This study aimed to prepare an efficient, cost-effective, and separable magnetic zeolite/chitosan composite (MZFA/CS) adsorbent from solid waste to deal with the water pollution of Cr(VI). The MZFA/CS was characterized by X-ray fluorescence (XRF), Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD), and vibrating sample magnetometer (VSM) techniques. Then, the effect of pH, temperature, initial concentration of Cr(VI) ions, and contact time was considered in the study. For a sorbent dose of 0.1 g in 50 mL of a Cr(VI) solution, at a contact time of 30 min, temperature of 30°C, and a pH of 3, an adsorption capacity (q_e) of 16.96 mg g⁻¹ was achieved. Adsorption kinetics and isotherm data obtained for all adsorption systems were well-fitted by pseudo-second-order and Langmuir models, respectively. The thermodynamic study suggested that the adsorption process is spontaneous and endothermic in nature. In summary, the adsorbent with better separability (Ms = 16.83 emu g⁻¹) and adsorbability was successfully fabricated.     

Effect of partial replacement of geopolymer binder materials on the fresh and mechanical properties: A review

The growth of demand for concrete raises concerns about the consumption of natural resources and ordinary Portland cement. Geopolymer composites show promise as a sustainable alternative for conventional cement concrete. Considering the wide range of potential geopolymer composites applications (including suitability for transportation infrastructure, underwater applications, repair and rehabilitation of structures as well as recent developments in 3D printing), the desired fresh and mechanical properties of the geopolymer composite may vary between applications: for example, rapid setting can be a merit for certain applications and a demerit for others. Therefore, the desired fresh and mechanical properties (e.g., workability, setting time, compressive strength, etc.) can be controlled for a given geopolymer source material through its partial substitution by natural or by-product materials. Recognizing the critical role of various replacement materials in enhancing the potential applications of geopolymer composites, the present review was undertaken to quantify and understand the effect of partial replacement by fly ash, metakaolin, kaolin, red mud, slag, ordinary Portland cement, and silica fume on the setting time, workability, compressive strength and flexural strength of various source materials addressed in the literature. The review also provides insights into research gaps in the field to promote future research.     

烧结时间对含铅玻璃制备微晶玻璃析晶及性能的影响

以铅玻璃与粉煤灰为原料，通过协同熔炼制备了微晶玻璃。通过XRD和SEM等手段研究了不同烧结时间下微晶玻璃的物相组成及显微结构，测定了微晶玻璃的密度、吸水率、维氏硬度和化学抗性。结果表明: 延长烧结时间对含铅玻璃加入量为40%(FG40)、50%(FG50)样品的晶相类型和晶化程度有影响，而对含铅玻璃加入量为60%(FG60)、70%(FG70)和80%(FG80)样品的影响较小。随着烧结时间延长，样品晶化程度提高，晶体长大，玻璃相减少。适宜的含铅玻璃加入量为50%~70%，对应的FG50、FG60、FG70样品最佳烧结时间分别为4 h、3 h、3 h。     

配加预处理脱硫灰对铁矿烧结基础特性的影响

 半干法脱硫灰堆弃处理占用土地且容易造成二次污染,将脱硫灰预处理后替代CaO熔剂配入烧结有望充分利用其中的熔剂组分,实现脱硫灰在钢铁企业的闭路资源化利用。研究了脱硫灰配加焦粉加热分解特性及替代CaO熔剂配加对铁矿粉烧结基础特性的影响。结果表明,配加1%焦粉可以有效提高脱硫灰分解率,减少CaSO₄的生成。随着预处理脱硫灰替代CaO比例的增加,铁矿粉同化温度和黏结相强度呈现先增加后减小的趋势;液相流动性呈现单调增加趋势,当替代比超过40%时,液相流动性形成了流动性很大的“假象”;黏结相微观结构表明,替代比例小于40%时,有利于烧结试样中铁酸钙的生成;综合考虑,最佳的替代比例应小于40%。     

气化灰基腻子粉的制备与性能研究

为实现气化灰综合利用和降低腻子粉制备成本，研究了利用气化灰替代水泥制备腻子粉的技术可行性。以气化灰和 42.5水泥为主要原料，配以少量的羟丙基甲基纤维素和可分散性乳胶粉，制备气化灰基腻子粉，实验考察原料配方变化对腻子粉的性能影响。研究结果表明：利用气化灰替代水泥制品制备腻子粉具有可行性。其中，气化灰替代 50%水泥时，腻子粉的粘结强度为 0.82 Mpa，各项性能均优于建筑外墙用腻子粉标准 JG/T 157—2009要求。在相同条件下，气化灰替代不超过 70%的水泥时，腻子粉的粘结强度及其他指标均满足建筑外墙用腻子粉标准 JG/T 157—2009要求。     

生物质电厂废弃物草木灰成分分析及成形

生物质热电厂焚烧废弃物的主要成分是草木灰，其产生量大、密度小。大量草木灰不经处理会造成环境污染问题。本文首先分析草木灰的化学成分，确定草木灰的肥料特征，通过添加NH₄H₂PO₄使草木灰的pH达到国家复合肥的相关标准。选用聚天冬氨酸（30%水溶液）作为复合肥的黏结剂，应用于草木灰复合肥的成形造粒，以增加其抗压强度和肥效。研究不同烘干时间、烘干温度、聚天冬氨酸添加量对草木灰复合肥抗压强度的影响规律，通过分析植物的形态及生理指标，进而研究草木灰复合肥的肥效。结果表明：最佳烘干条件为10h、140℃，聚天冬氨酸对草木灰的抗压强度有明显的增强作用，并且草木灰与聚天冬氨酸的复配比为6g∶1mL时肥效最好。此方法解决了元素循环中断、草木灰环境污染，在运输过程中草木灰复合肥易碎，纯草木灰肥效低等问题。     

窑灰作脱硫剂的水泥窑湿法脱硫系统优化

针对水泥窑生产工艺中生料磨启停工序引起的烟气温度、二氧化硫浓度对湿法脱硫系统的影响以及杂质对湿法脱硫系统设备和浆液储罐的影响,提出了优化设计方法和运行措施,以便达到较好的烟气脱硫效果。实践表明,该工艺综合循环利用窑灰作脱硫剂,不仅可将烟气中二氧化硫能够达标排放,而且脱硫副产物石膏可作为水泥缓凝剂添加料,有较好的工程应用价值。     

循环流化床脱硫灰用于水泥生产的研究

褐煤作燃料热电厂产生的循环流化床脱硫灰应用于我公司2 500 t/d新型干法窑生产线水泥生产，由于褐煤中全硫含量偏高且波动大，由此致使脱硫过程中脱硫剂比例变化波动也大，将熟料、矿渣、脱硫灰分别用小磨粉磨后进行试验，在试验基础上，除了对该脱硫灰超细粉磨外，同时必须要解决脱硫灰的均化和f-CaO消解问题，通过技术改造使系统设备、工艺更加适合采用脱硫灰复掺技术。