A Highly Sensitive,Reversible, and Bidirectional Humidity Actuator by Calcium Carbonate Ionic Oligomers Incorporated Poly(Vinylidene Fluoride)

Sensitivity and multi-directional motivation are major two factors for developing optimized humidity-response materials, which are promising for sensing, energy production, etc. Organic functional groups are commonly used as the water sensitive units through hydrogen bond interactions with water molecules in actuators. The multi-coordination ability of inorganic ions implies that the inorganic ionic compounds are potentially superior water sensitive units. However, the particle forms of inorganic ionic compounds produced by classical nucleation limit the number of exposed ions to interact with water. Recent progress on the inorganic ionic oligomers has broken through the limitation of classical nucleation, and realized the molecular-scaled incorporation of inorganic ionic compounds into an organic matrix. Here, the incorporation of hydrophilic calcium carbonate ionic oligomers into hydrophobic poly(vinylidene fluoride) (PVDF) is demonstrated. The ultra-small calcium carbonate oligomers within a PVDF film endow it with an ultra-sensitive, reversible, and bidirectional response. The motivation ability is superior to other bidirectional humidity-actuators at present, which realizes self-motivation on an ice surface, converting the chemical potential energy of the humidity gradient from ice to kinetic energy.     

水电站大型竖井施工安全风险控制措施研究

竖井是大型水电工程中广泛采用的重要建筑物,但竖井的传统施工方法存在施工程序复杂、人工劳动强度大、施工效率不高等特点,同时还存在较大的安全风险。通过对杨房沟水电站大型竖井施工过程的研究,总结出精细化控制爆破、小溜渣井施工方式,同时也设计了一套用于运输的综合提升系统。采用上述创新方法不仅减少了繁琐的施工程序,降低了安全施工风险,而且大量采用机械化手段进一步提高了施工效率,确保了该工程竖井施工的安全风险可控。相关措施可为类似工程的竖井施工提供较好的借鉴作用。     

金沙江上游水电站应对白格堰塞湖灾害的措施及经验

2018年10月、11月,西藏自治区昌都市江达县白格村两次发生山体滑坡造成金沙江断流并形成白格堰塞湖,给金沙江上游沿岸人民生产生活设施造成巨大安全威胁和超过百亿元的经济损失。华电金沙江上游水电开发有限公司组织所属企业及参建单位快速应对,采取撤离避让、工程防护、人工干预、生产恢复,推动后续处置、风险评估等措施,最大限度减轻了对金沙江上游叶巴滩、拉哇、巴塘、苏洼龙等在建水电站的灾害损失和后续影响,为类似灾害的处置提供借鉴经验。     

汽轮机运行调节方式优化策略探析

分析了汽轮机的喷嘴调节、节流调节、旁通调节、定压调节和滑压调节等几种基本调节方式的特点,指出现役燃煤火电机组多因调节方式单一而普遍存在着调峰能力不足、负荷响应迟缓以及因长期偏离设计工况致使运行安全经济性下降等诸多问题,提出了通过调节方式的优化组合,采用(节流)定压-滑压-(喷嘴)定压-旁通调节的复合调节方式,以实现煤电机组安全、经济、灵活、快速地参与电网的深度调峰,破解具有强随机波动性的新能源电量规模化并网的困境。     

New cardo silylated poly(azomethine)s containing 9,9′‐diphenylfluorene units as materials with Brønsted acid‐dependent fluorescence

Aromatic poly(azomethine)s have been studied due to their attractive properties such as high thermal stability, semiconducting behavior and the ability to coordinate species with their imine units (C?N). In this paper, the synthesis and characterization of two novel silylated poly(azomethine)s containing cardo units are reported. These materials were highly soluble in organic solvents such as chloroform and m‐cresol and were thermally stable, and PAzMC1 exhibited a high glass transition temperature value (287 °C), while that for PAzMC2 was not observed. UV–visible spectrophotometry revealed absorption bands related to the aromatic backbone of both PAzMCs, 300–285 nm in tetrahydrofuran and 310–301 nm in dimethylsulfoxide, and bands attributed to the conjugated imine unit at around 350 nm. In order to investigate the phenomenon of the emission of fluorescence promoted by dopant agents with regard to potential optoelectronic applications, the materials were doped with H₂SO₄ and their optical and electrochemical properties investigated. Thus, the absorption band of the imine group was suppressed due to the nitrogen atoms being protonated. Fluorescence spectroscopy analysis developed in dilute solutions of polymers showed no emission from the undoped polymers, whereas the acid‐doped species emitted fluorescence in the UV and violet regions (322 nm). Cyclic voltammetry measurements were carried out and HOMO–LUMO energies were estimated. This study provides a starting point for the development of new poly(azomethine)s with doping‐dependent emission. © 2019 Society of Chemical Industry     

西藏水电开发是应对治理揠塞湖的重要举措

西藏区域地质构造发育,又属于高震区,在局部强降雨强降雪等恶劣小气候条件下,自然灾害频发,在高山深谷的江河上尤其容易发生堰塞湖。2018年10月17日凌晨5:00左右,西藏林芝加拉村下游约6km处(大峡谷核心区、无人区)雅鲁藏布江(以下简称“雅江”)左岸发生大规模泥石流,造成干流断流,形成影响很大的雅江加拉村堰塞湖。堰塞湖的治理一直是个世界难题,本文从2018年10月17日治理分析加拉堰塞湖的实践,阐述从水电开发角度,在灾害区上游建设高坝大库拦水调蓄,水库下游再采取截弯取直方式引走来水,作为防治雅江大峡谷河段今后可能出现大型堰塞湖重要治理手段,防止大型堰塞湖造成水淹城乡和溃堰水淹下游灾难的发生,从而达到既推进雅江水电开发,又较好治理了大峡谷河段自然灾害,实现把水电开发建成“功在当代,利在千秋”的减灾防灾工程。     

引水式水电站变顶高尾水洞水力特性和体型优化

考虑引水式水电站常用的有压尾水洞和变顶高尾水洞两类布置型式,采用基于特征线法的有压管道瞬变流分析模型和适用于明满流过渡过程分析的改进狭缝法模型,分别分析系统的过渡过程特性和尾水洞体型参数的敏感性,研究不同的尾水洞型式下尾水系统的水力特性,进一步揭示了变顶高尾水洞的底宽、洞高和顶坡对尾水管进口最小内水压力的影响规律。结果表明,与增大面积的有压尾水洞比较,变顶高尾水洞是一种可行的布置型式,可有效提高尾水管进口的最小内水压力且水锤过程衰减较快;合理增大变顶高尾水洞底宽、洞高或顶坡均可不同程度地改善尾水管进口最小内水压力,其中顶坡的影响相对明显,为体型优化设计提供了参考依据。     

Polymer electrolytes and interfaces in solid-state lithium metal batteries

The polymer electrolyte based solid-state lithium metal batteries are the promising candidate for the high-energy electrochemical energy storage with high safety and stability. Moreover, the intrinsic properties of polymer electrolytes and interface contact between electrolyte and electrodes have played critical roles for determining the comprehensive performances of solid-state lithium metal batteries. In this review, the development of polymer electrolytes with the design strategies by functional units adjustments are firstly discussed. Then the interfaces between polymer electrolyte and cathode/anode, including the interface issues, remedy strategies for stabilizing the interface contact and reducing resistances, and the in-situ polymerization method for enhancing the compatibilities and assembling the batteries with favorable performances, have been introduced. Lastly, the perspectives on developing polymer electrolytes by functional units adjustment, and improving interface contact and stability by effective strategies for solid-state lithium metal batteries have been provided.     

水电工程下泄生态基流常用计算方法及软件开发

为了分析及确立生态基流,为水电工程环境影响评价提供依据,针对水电工程生态基流估算及决策过程繁复等问题,以2001—2015年水电工程环境影响评价及相关法律法规为基础,分析我国生态基流管理实践中使用最广泛的4种计算方法,即Tennant法、月基本流量法、最小流量法及7Q10法,并编制生态基流决策支持软件,并应用软件在汉江流域进行实例验证。结果表明,该软件能够提供多种计算方法及对比分析功能,可为水电工程下泄生态基流计算及决策提供计算平台。4种计算方法在汉江流域计算结果差异较大。总体而言,干流适合最小流量法及Tennant法,支流适合Tennant法。研究成果具有较大的实际应用和推广价值。