Co?N graphene encapsulated cobalt catalyst for H2O2 decomposition under acidic conditions

Hydrogen peroxide (H₂O₂) has been listed as one of the 100 most important chemicals in the world. However, huge amount of residual H₂O₂ is hard to timely decomposed into O₂ and H₂O under acidic condition, easily resulting in explosion hazard. Here, we reported a core–shell structure catalyst, that is graphene with Co N structure encapsulated Co nanoparticles. Co N graphene shell serves as the active site for the H₂O₂ decomposition, and Co core further enhance this decomposition. Benefiting from it, the H₂O₂ decomposition were close to 100% after 6 cycles without pH adjustment, which increased 6 orders of magnitude compared with no catalyst. At the same time, the O₂ generation reached 99.67% in 2 h with little metal leaching, and ·OH has been greatly inhibited to only 0.08%. This work can cleanly remove H₂O₂ with little deep oxidation and protect the process of H₂O₂ utilization to achieve a safer world.     

Analytical approach on magnetohydrodynamic Casson fluid flow past a stretching sheet via Adomian decomposition method

Flow phenomena of three-dimensional conducting Casson fluid through a stretching sheet are proposed in the present investigation with the impact of the magnetic parameter in a permeable medium. The adaptation of particular transformations is useful to modify the governing equations into their nondimensional as well as the ordinary form. However, these transformed equations are nonlinear and approximate analytical methods for the solution of the complex form of governing equations. In particular, the Adomian decomposition method is proposed for the solution. The behavior of several variables, such as the magnetic and porous matrix, on the flow profile as well as the rate of shear stress, are discussed via graphs and tables. The conformity of the current result with the earlier study shows a road map for further investigation. The major concluding remarks are; the retardation in the velocity distribution is rendered due to an increase in the Casson parameter moreover, the Casson parameter favors in reducing the rate of shear stress coefficient in magnitude.     

臭氧氧化技术在有色金属湿法冶金中的应用研究进展

臭氧是一种氧化性极强、多功能化的绿色氧化剂。本文综述了臭氧氧化技术在有色金属湿法冶金领域的研究进展和应用现状,重点介绍了在贵金属、重金属、稀有金属及轻金属等有色金属湿法冶金领域的应用研究。详细探讨了臭氧的强氧化性对低品位金属矿和难冶金属矿浸出、溶液中低价态金属离子氧化沉淀、溶液净化除杂等方面的作用机理,并对目前面临的问题进行简要叙述,对其在有色金属湿法冶金领域的应用前景进行了展望。     

基于LP与小波包的复杂机电系统监测序列混沌降噪方法

针对流程工业生产系统监测数据存在强噪声和混沌性的特点,提出了一种局部投影方法(Local Projection Method)与小波包方法相结合的信号降噪方法。该方法先利用局部投影方法从动力学系统嵌入流形的角度进行多次迭代降噪,并根据关联维数来判定迭代终止;再利用小波包方法从频率的角度进行降噪,抑制高频噪声的干扰,取得了较好的降噪效果。用Lorenz时间序列进行仿真验证,对仿真时间序列加入不同程度的噪声,对比分析小波包、局部投影与该方法降噪后的相空间、SNR值和最大Lyapunov指数,证明了该方法对于中高强度噪声具有更好的降噪效果。并将该方法用于某压缩机组的实际监测数据降噪,评估三种方法的降噪效果,进一步验证了该方法的优越性。     

基于边缘和局部熵融合的视觉安全性评估方法

针对基于局部熵进行加密图像视觉安全性评估存在块效应的局限性，引入图像的边缘特征，通过共有边缘来衡量加密图像与原始图像的边缘相似度，消除了块效应。由于局部熵对加密等级低的图像不敏感，边缘相似度对加密等级高的图像不敏感，将两个评估方法进行自适应融合，提出[SLEES]（Local Entropy and Edge Similarity，[SLEES]）指标。通过改变图像像素位置和图像像素值的加密方式处理图像和视频帧进行测试，实验结果表明，[SLEES]指标相比传统评估指标有更好的鲁棒性，评估范围更广。     

大采高综放工作面强动压端头顶板控制技术

为了解决大采高综放工作面回风侧端头顶板控制问题,针对马道头矿8211工作面的地质情况,通过对回风顺槽超前注浆加固,提高超前支护范围和支护强度,并对回风侧端头三角区煤壁和顶板进行化学浆加固的技术方案,有效控制了顺槽超前区围岩变形和工作面回风侧端头三角区煤壁片帮,保证了工作面端头区顶板安全。     

Reduced basis method for managed pressure drilling based on a model with local nonlinearities

To circumvent restrictions of conventional drilling methods, such as slow control actions and inability to drill depleted reservoirs, a drilling method called managed pressure drilling (MPD) has been developed. In MPD, single-phase flow processes can be modeled as a feedback interconnection of a high-order linear system and a low-order nonlinear system. These nonlinearities appear locally both inside and at the boundaries of the computational domain. To obtain a fast simulation platform for real-time purposes (eg, online model-based controller implementation), model order reduction is required for MPD. However, the local nonlinearities render applying model order reduction techniques challenging. In this study, a new approach is proposed to deal with such nonlinearities within the reduced basis (RB) context and it is successfully tested on a model for MPD. Contrary to the classical RB technique, the proposed approach not only does not generate nonphysical spikes at the locations of these local nonlinearities but also yields high speedup factors. The obtained reduced-order model can be used for efficient online simulation and controller design for drilling systems with MPD.     

综放切顶沿空留巷围岩变形特征分析及防治

为了掌握高地应力条件下综放沿空留巷围岩变形与破坏特征，以古汉山矿1604工作面为工程背景，采用理论分析的手段研究分析了综放沿空留巷围岩变形破坏形成机制，并提出采用预裂爆破切缝、强帮护顶等围岩控制措施，总结了综放沿空留巷技术原理，确定了沿空留巷支护参数，最后在现场进行了工业性试验。研究结果表明:沿空留巷巷道整体稳定性好，顶底板最大移近量为240~320 mm，两帮最大移近量为360~410 mm，支护效果良好，成巷效果较好；解决了采掘接替紧张、巷道维护困难的难题，满足了安全生产需要，提高了煤矿生产效率。     

Structural optimization with an automatic mode identification method for tracking the local vibration mode

Traditional optimization methods, which take a specific order of modal frequency as the design constraint, could fail to obtain the desired solution because of modal substitution. An improved optimization model with continuous sizing variables is established to solve this problem, in which the minimum weight and a given local modal frequency are considered as the objective and the constraint. To capture accurately the expected mode of vibration, a local mode identification technique is proposed based on the strain energy ratio between the local area and the whole structure. With that scheme, an optimization system is developed, in which the local mode can be effectively identified and the constraint can be updated with it in the iteration process. Two numerical examples, of a reinforced plate and a satellite structure, are applied to illustrate the effectiveness and efficacy of the proposed method.     

伞帽用高铬铸铁在热强碱腐蚀环境下的磨损分析

针对氧化铝行业中常用的Cr28和Cr20高铬铸铁伞帽在相同工况条件下的磨损机理进行分析,并对比研究了实际生产中两种失效材料的成分、组织及性能。结果表明,伞帽部件在高温强碱腐蚀条件下受到外界冲刷时,磨损量由微切削磨损与变形磨损这两种机制共同决定。含铬量较高的Cr28高铬铸铁,其冲刷和抗腐蚀磨损性能均优于Cr20高铬铸铁。伞帽服役寿命主要受浆料和表层的铸铁材料两大因素影响。两种试验材料经淬火+回火处理后,基体组织中主要为回火马氏体+M₇C₃型碳化物+少量残留奥氏体,其中含铬量较高的Cr28高铬铸铁中共晶碳化物含量更高,且分布更加弥散,其平均硬度值为64.0 HRC,高于Cr20高铬铸铁的60.2 HRC。最终确定Cr28高铬铸铁作为伞帽材质更能满足氧化铝生产及设备检修周期的需要。