草酸钙在硫酸软骨素自组装膜上周期沉淀的研究

利用硫酸软骨素(chondroitin sulfate，CS)在云母基底上通过浇铸法制备的自组装膜为基底，诱导草酸钙在其上的凝集生长。发现当硫酸软骨素的浓度为1．Omg／ml时在该膜体系中可形成规整的周期性草酸钙环状沉淀。这种有序的环状结构可能是耗散结构的一种具体表现形式。利用原子力显微镜(atomic forcemicroscope，AFM)和傅立叶红外光谱仪对这种结构进行了表征，实验结果显示合适浓度下形成的CS膜在一定程度上可以抑制草酸钙的凝集结晶，表明高分子基质与无机离子间强烈的相互作用对无机盐的成核结晶有显著影响，为探讨结石的形成与抑制提供了一定的实验依据。     

New Reaction Engineering Concepts for Selective Oxidation Reactions

In order to enhance product yields in selective oxidation reactions, numerous reaction engineering concepts are being studied worldwide. Periodic operation has been investigated for decades, yet its application is limited to a few examples, such as the butane oxidation after DuPont or reverse-flow reactors for VOC removal. The use of microchannel reactors is a younger field, but it has already yielded promising results for process optimization. Catalytic wall reactors have proved to be a helpful tool for kinetic studies. On the laboratory scale, membrane reactors have displayed favorable behavior in selective oxidation. The Na vapor-catalyzed dehydrogenation of methanol to formaldehyde is a final example of an unusual new concept for selective oxidation.     

弹丸外弹道优化设计初始点的选取

在弹丸外弹道优化设计中,需对优化设计变量赋于初始值.初始值选取得如何,对整个优化计算所耗机时、迭代点收敛到哪个极值点上等等,影响很大.该文对初始值的选取原则、选取方法等作了讨论,所得结果也可作为对弹丸主要结构参数选优的预估.     

输入——输出迭代算法中松弛因子的确定

本文利用变分的手段提示了输入—输出迭代算法中松弛因子的取值规律。     

Development and simulation studies of an unsteady state biofilter model for the treatment of cyclic air emissions of an α‐pinene gas stream

This paper describes the development and simulation of an unsteady state biofilter model used to predict dynamic behaviour of cyclically‐operated biofilters and compares it with experimental results obtained from three, parallel, bench‐scale biofilters treating both periodically fluctuating concentrations and constant concentrations of an α‐pinene‐laden gas stream. The dynamic model, using kinetic parameters estimated from the constant concentration biofilter, was able to predict the performance of cyclic biofilters operating at short cycle periods (ie, in the order of minutes and hours). Steady state kinetic data from a constant concentration biofilter can be used to predict unsteady state biofilter operation. At a 24 h cycle period, the dynamic model compared well with experimental results. For long cycle periods (ie, hours and days), removal efficiency decreased after periods of non‐loading: the longer the period of non‐loading, the poorer the biofilter's performance at the re‐commencement of pollutant loading. At longer time scales the model did not effectively predict transient behaviour, as adsorption and changes in kinetic parameters were not accounted for. Modelling results showed that similar biofiltration performance for the cyclic and constant concentration biofiltration of α‐pinene is expected for biofilters operating solely in the first order kinetics regime. Poorer performance for cyclic biofilters following Monod kinetics spanning the entire kinetics range is expected as the cycle amplitude increases. The most important parameters affecting the performance of a cyclically‐operated biofilter with short cycle periods are: amplitude of cyclic fluctuations, C_{g, max}/C_g, relative value of the half‐saturation constant in the Monod expression, K_s, and effective diffusivity of α‐pinene in the biofilm, D_e. Copyright © 2005 Society of Chemical Industry     

多时滞Lotka-Volterra互惠系统周期正解的存在性

用重合度理论研究具时滞非自治Lotka-Volterra互惠系统，获得了周期正解的存在性，推广了Gopalsamy及He(1997)的结果。     

灞河生态治理工程模型试验研究

通过模型试验 ,对位于西安市东郊因采沙使河道破坏严重的灞河河段进行了复现试验和研究 ,并以此为依据 ,通过优化比较为设计部门提供了合理的橡胶坝坝址和坝座高程。在此基础上 ,又对建坝后橡胶坝对上下游冲淤变化的影响进行了试验研究和分析 ,解决了工程设计中的一些关键技术问题     

宜昌站泄流能力变化对葛洲坝设计洪水影响

宜昌水文站是葛洲坝、三峡水利枢纽的设计依据站。葛洲坝水利枢纽动工修建和运行 ,对该站水位流量关系中低水部分产生了影响。探讨了该河段泄流能力的变化对葛洲坝水利枢纽设计洪水有无影响的问题。用1 967～ 1 999年实测资料对宜昌站以汛期平均水位为参数的水位流量关系曲线簇进行了检验 ,大部分年份最大日平均流量、3、7、1 5、30d洪量的偏差在± 4 %之间 ,说明曲线簇推流具有相当的精度。证明了宜昌河段中低水泄流能力的变化对葛洲坝水利枢纽设计流量和校核流量基本没有影响     

长江口北支水道水沙特性分析

从实测资料出发,结合水流数值计算成果,对长江口北支水道的水流、泥沙和含盐度等资料进行分析,得出了北支水道的水沙特性,并分析了水沙变化与河床变化的相互关系.北支水道在1958年南通河段河势控制后,径流分流比逐年下降,并渐趋稳定于3%左右.北支水道受径流影响越来越小,主要受潮流作用.随着水沙特性的逐年变化,北支水道0 m以下槽蓄容量逐年减小,并渐趋稳定,北支上段为逐年淤积最快的区域.由此反过来影响了水沙条件的进一步变化,使北支上段平均潮差增加,北支的会潮点由崇头附近下移至青龙港附近.