Trade-off study between risk and benefit in safety devices for hydrogen refueling stations using a dynamic physical model

As hydrogen refueling stations become increasingly common, it is clear that a high level of economic efficiency and safety is crucial to promoting their use. One way to reduce costs is to use a simple orifice instead of an excess flow valve, which Japanese safety regulations have identified as a safety device. However, there is concern about its effect on refueling time and on risk due to hydrogen leakage. To clarify the effect, we did a study of model-based refueling time evaluation and quantitative risk assessment for a typical refueling station. This study showed that an orifice is an effective alternative safety device. The increase in refueling time was less than 10%, based on simulations using a dynamic physical model of the station. Neither was there a significant difference in the risk between a configuration with excess flow valves and one with an orifice.     

Economic competitiveness of compact steam methane reforming technology for on-site hydrogen supply: A Foshan case study

On-site hydrogen production through steam-methane reforming (SMR) from city gas or natural gas is believed to be a cost-effective way for hydrogen-based infrastructure due to high cost of hydrogen transportation. In recent years, there have been a lot of on-site hydrogen fueling stations under design or construction in China. This study introduces current developments and technology prospects of skid-mounted SMR hydrogen generator. Also, technical solutions and economic analysis are discussed based on China's first on-site hydrogen fueling station project in Foshan. The cost of hydrogen product from skid-mounted SMR hydrogen generator is about 23 CNY/kg with 3.24 CNY/Nm³ natural gas. If hydrogen price is 60 CNY/kg, IRR of on-site hydrogen fueling station project reaches to 10.8%. While natural gas price fall to 2.3 CNY/Nm³, the hydrogen cost can be reduced to 18 CNY/kg, and IRR can be raised to 13.1%. The conclusion is that skid-mounted SMR technology has matured and is developing towards more compact and intelligent design, and will be a promising way for hydrogen fueling infrastructures in near future.     

超稳光纤链路的理论与实践

超稳光纤链路这个概念包含超稳频率光源和超稳频率传递的光纤链路。从当前看,如何利用已有庞大的公用电信网、专用网的光纤和光网络的资源,选择一个通用的光纤通路改造成超稳光纤链路来实现频率传递,取代基于卫星的频率传递,提高传输的频率精度,这是一个巨大的系统工程。本文对超稳频率光源和超稳频率传递的光纤链路的关键技术进行研究和讨论。     

温州某公轨共建高架车站结构设计

为了解决城市廊道资源的紧张和公共交通发展需求的矛盾,出现了轨道交通和快速路的共建型式,即公轨共建的复合型交通模式,以温州市域铁路S2线一期工程的人民路站为例,研究公轨共建高架车站的结构设计要点。首先,为降低浅层气体对桩基的承载力及沉降影响,对遇到局部浅层气体发育的基础设计提供了合理的解决方案。然后针对公轨共建一体化车站分别进行了多遇和罕遇地震作用分析,研究表明构件及整体指标满足规范要求。最后针对工程的一些关键技术,如快速路桥面体系的选型、超长结构温度应力的控制措施、轨道梁挠度及应力的控制、快速路桥面振动对车站的影响等进行了分析,并给出了具体的解决方案和指导意见。     

离线式带钢双面翻转检查站方案设计及实践

针对某酸轧机组检查站穿带困难、检查效率低、产生废品多、故障率高的问题,开发了一种离线式带钢双面检查站。该检查站新增了带钢翻转装置,将在入口分切剪处完成定尺剪切的带钢试样由两侧压板夹紧,中间可升降皮带机落下,翻转装置将带钢试样张紧,并翻转90°或者180°,实现带钢的双面检查。皮带机两侧布置有可升降、可横移的活动操作平台,检测人员站在平台上对带钢进行打磨检查,可同时对带钢上下表面进行检测。由于缩短了带钢的传输距离,有效减少了其他擦划伤的影响,提高了带钢表面质量检测准确性。     

Novel silicon-contained lignin-based carbon fibers derived from bamboo pulping black liquor with improved electrochemical performance for supercapacitors

Carbon fibers (CFs) are a promising candidate as electrode materials for flexible supercapacitors given its light weight and moderate cost. In this study, the lignin used was partially separated from kraft bamboo pulping black liquor and the higher molecular weight fraction, unavoidably contains a small amount of silicon compounds, so named silicon-contained lignin. Novel CFs were prepared using commercial polyacrylonitrile (PAN) and the lignin by electrospinning and further carbonization. Even in the presence of silicon compounds, the fibrous morphology of precursor fibers was significantly good, and the CFs with uniform fiber diameter and high specific surface area up to 182 m²/g were obtained with an increase in silicon-contained lignin. The CFs fabricated from silicon-contained lignin and commercial PAN had higher specific capacitance (22.20 mF/cm² at 10 mA/cm²) and superb cycling stability (94.21%) than that from silicon-free lignin or pure PAN separately.     

A Role for Human Renal Tubular Epithelial Cells in Direct Allo-Recognition by CD4+ T-Cells and the Effect of Ischemia-Reperfusion

Direct allorecognition is the earliest and most potent immune response against a kidney allograft. Currently, it is thought that passenger donor professional antigen-presenting cells (APCs) are responsible. Further, many studies support that graft ischemia-reperfusion injury increases the probability of acute rejection. We evaluated the possible role of primary human proximal renal tubular epithelial cells (RPTECs) in direct allorecognition by CD4+ T-cells and the effect of anoxia-reoxygenation. In cell culture, we detected that RPTECs express all the required molecules for CD4+ T-cell activation (HLA-DR, CD80, and ICAM-1). Anoxia-reoxygenation decreased HLA-DR and CD80 but increased ICAM-1. Following this, RPTECs were co-cultured with alloreactive CD4+ T-cells. In T-cells, zeta chain phosphorylation and c-Myc increased, indicating activation of T-cell receptor and co-stimulation signal transduction pathways, respectively. T-cell proliferation assessed with bromodeoxyuridine assay and with the marker Ki-67 increased. Previous culture of RPTECs under anoxia raised all the above parameters in T-cells. FOXP3 remained unaffected in all cases, signifying that proliferating T-cells were not differentiated towards a regulatory phenotype. Our results support that direct allorecognition may be mediated by RPTECs even in the absence of donor-derived professional APCs. Also, ischemia-reperfusion injury of the graft may enhance the above capacity of RPTECs, increasing the possibility of acute rejection.     

Effect of wind condition on unintended hydrogen release in a hydrogen refueling station

Ambient condition, especially the wind condition, is an important factor to determine the behavior of hydrogen diffusion during hydrogen release. However, only few studies aim at the quantitative study of the hydrogen diffusion in a wind-exist condition. And very little researches aiming at the variable wind condition have been done. In this paper, the hydrogen diffusion in different wind condition which including the constant wind velocity and the variable wind velocity is investigated numerically. When considering the variable wind velocity, the UDF (user defined function) is compiled. Characteristics of the FGC (flammable gas cloud) and the HMF (hydrogen mass fraction) are analyzed in different wind condition and comparisons are made with the no-wind condition. Results indicate that the constant wind velocity and the variable wind velocity have totally different effect for the determination of hydrogen diffusion. Comparisons between the constant wind velocity and the variable wind velocity indicate that the variable wind velocity may cause a more dangerous situation since there has a larger FGC volume. More importantly, the wind condition has a non-negligible effect when considering the HMF along the radial direction. As the wind velocity increases, the distribution of the HMF along the radial direction is not Gaussian anymore when the distance between the release hole and the observation line exceeds to a critical value. This work can be a supplement of the research on the hydrogen release and diffusion and a valuable reference for the researchers.     

白鹤滩水电站左岸边坡稳定性分析

为研究缓倾角错动带及断层对白鹤滩水电站左岸顺层岩质高边坡稳定性的影响,以勘I5线地质剖面为例建立力学模型,借助综合法试验模拟岩体内主要地质构造及相关工程措施。在此基础上,再利用RFPA3D有限元数值模拟方法,分析岩体内裂隙萌生、发育、扩展直至贯通的损伤演化过程。结果表明,混凝土置换洞阻碍裂缝沿软弱面扩展成效显著,开挖后工程边坡安全系数为1.62;离心加载法得到的边坡潜在滑移面与物理模型试验得到的裂缝扩展模式基本一致,层内错动带LS337、层间错动带C3-1、断层f101、裂缝J110等软弱结构面共同控制岩体的开裂与边坡失稳。研究成果可为本工程边坡开挖与支护以及类似工程提供参考。     

水电站大型竖井施工安全风险控制措施研究

竖井是大型水电工程中广泛采用的重要建筑物,但竖井的传统施工方法存在施工程序复杂、人工劳动强度大、施工效率不高等特点,同时还存在较大的安全风险。通过对杨房沟水电站大型竖井施工过程的研究,总结出精细化控制爆破、小溜渣井施工方式,同时也设计了一套用于运输的综合提升系统。采用上述创新方法不仅减少了繁琐的施工程序,降低了安全施工风险,而且大量采用机械化手段进一步提高了施工效率,确保了该工程竖井施工的安全风险可控。相关措施可为类似工程的竖井施工提供较好的借鉴作用。