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1.
底板破坏深度影响底板注浆改造层位的选择,采取钻孔压水试验、声波测试、钻孔窥视3种实测技术手段,选择桑树坪煤矿下组煤3105工作面进行底板破坏深度综合测试。研究结果表明,钻孔压水试验测试显示底板破坏深度为14.9 m,声波测试显示底板破坏深度为14.7 m,钻孔窥视显示底板破坏深度为15 m,声波测试结果真实合理地反应了工作面回采过程中底板岩层应力、应变变化规律,最终综合评价3105工作面底板破坏深度为15 m,可应用于同一采区其他工作面,为底板注浆加固层位选择提供了技术参数。  相似文献   
2.
煤泥水的处理属于选煤厂的一个极其关键的过程,最终的处理结果能够影响到煤泥水的回用和洗水闭路循环指标,并且对于选煤厂以及其它环节,如发热量、分选效率指标等影响很大。也是制约经济以及社会效益的关键的因素。模糊控制原理包含的内容比较多,基于其整体性,提出自动添加药剂控制策略,用模糊控制算法代替目前使用的常规控制算法,根据在线设定的模糊规则参数,以进料浓度为输入量,以浓缩池沉积面厚度参数作为反馈量,以变频器频率为输出量,设计模糊控制器。对药剂添加系统进行补偿控制,基于此控制策略对实际数据进行验证采集。结果表明: 所设计的模糊控制系统项目参数选择符合控制要求,进而可以达到控制的标准,控制系统的稳定性也较好,煤泥水处理效果和处理速度得到了保证,进一步提升了经济效益等综合指标。  相似文献   
3.
静压气悬浮轴的悬浮技术,是利用多孔质材料做成的轴承,对高压气体节流降压,在轴承和轴之间形成一层薄的气膜,使轴悬浮,实现轴的无接触式工作,从而达到降低摩擦提高工作效率的目的。本论文基于的50冷吨的气悬浮离心制冷机组,名义工况的制冷量为170 kW,制冷能效5.6,IPLV值7.3,通过对该系统及测试数据进行分析,用理论计算制热量和实测制热量之间的差值,得出从100%负荷到25%负荷工况,悬浮轴的供气量的流量,大约在6 g/s~9 g/s,占系统制冷剂循环量的0.82%~2.2%。  相似文献   
4.
In this study, some locations with different climates, off-grid zero energy buildings with hydrogen energy storage systems are designed, and transient analysis is conducted. These considered buildings supply their electricity consumption without using the electrical grid and PV panels or wind turbines. Also, they supply thermal comfort to occupants by using a vapor compression chiller and humidifier. Domestic hot water of occupants is supplied using solar collectors. For analyzing building's performance and objectives achievement, TRNSYS software is used. Also, for evaluating occupant thermal comfort, the Fanger model is used. The considered building is a one-story building with a 150 m2 area. Four occupants are considered. Both of them are seated at rest, and another is seated with light working such as typing. Using the Fanger model equation and MATLAB software, the thermal comfort of occupants is determined. For domestic hot water consumption, verified profiles that vary during 24 h of the day are considered. Achieved results show that for humid and cold cities, PV panels with an area of 73 and 76 m2 can be supplied the required electricity of considered building with four occupants and battery state of charge is higher than 50% and 10%, respectively. Moreover, with a suitable air conditioner system, the predicted percentage of dissatisfied (PPD) can be lower than 12% and 8% for humid and cold cities. Therefore, the building can be converted to a zero-energy building using its rooftop area.  相似文献   
5.
The development of cost-effective bifunctional catalysts with excellent performance and good stability is of great significance for overall water splitting. In this work, NiFe layered double hydroxides (LDHs) nanosheets are prepared on nickel foam by hydrothermal method, and then Ni2P(O)–Fe2P(O)/CeOx nanosheets are in situ synthesized by electrodeposition and phosphating on NiFe LDHs. The obtained self-supporting Ni2P(O)–Fe2P(O)/CeOx exhibit excellent catalytic performances in alkaline solution due to more active sites and fast electron transport. When the current density is 10 mA cm?2, the overpotential of hydrogen evolution reaction and oxygen evolution reaction are 75 mV and 268 mV, respectively. In addition, driven by two Ni2P(O)–Fe2P(O)/CeOx electrodes, the alkaline battery can reach 1.45 V at 10 mA cm?2.  相似文献   
6.
为探究高水头大幅变化对混流式水轮机尾水管涡带的演化及对压力脉动的影响,以国内运行水头变幅最大的紫坪铺水电站水轮机为例,通过三维建模及定常和非定常条件的CFD分析,研究混流式水轮机在相同开度下最大水头、设计水头和最小水头三种工况的流动特点。结果表明,最小水头工况下尾水管内部流态较乱,尾水管中存在螺旋型空腔涡带,主要分布在直锥段。最大水头工况下尾水管的柱状涡带直径较大,且分布在直锥段和弯肘段,对机组振动和空化影响较大。研究结果阐明了非定常流动的特性,揭示了尾水管内压力脉动与涡带发展形态变化的规律,可为水轮机的安全可靠运行提供技术保障。  相似文献   
7.
Lithium alanate (LiAlH4) is a material that can be potentially used for solid-state hydrogen storage due to its high hydrogen content (10.5 wt%). Nevertheless, a high desorption temperature, slow desorption kinetic, and irreversibility have restricted the application of LiAlH4 as a solid-state hydrogen storage material. Hence, to lower the decomposition temperature and to boost the dehydrogenation kinetic, in this study, we applied K2NiF6 as an additive to LiAlH4. The addition of K2NiF6 showed an excellent improvement of the LiAlH4 dehydrogenation properties. After adding 10 wt% K2NiF6, the initial decomposition temperature of LiAlH4 within the first two dehydrogenation steps was lowered to 90 °C and 156 °C, respectively, that is 50 °C and 27 °C lower than that of the аs-milled LiAlH4. In terms of dehydrogenation kinetics, the dehydrogenation rate of K2NiF6-doped LiAlH4 sample was significantly higher as compared to аs-milled LiAlH4. The K2NiF6-doped LiAlH4 sample can release 3.07 wt% hydrogen within 90 min, while the milled LiAlH4 merely release 0.19 wt% hydrogen during the same period. According to the Arrhenius plot, the apparent activation energies for the desorption process of K2NiF6-doped LiAlH4 are 75.0 kJ/mol for the first stage and 88.0 kJ/mol for the second stage. These activation energies are lower compared to the undoped LiAlH4. The morphology study showed that the LiAlH4 particles become smaller and less agglomerated when K2NiF6 is added. The in situ formation of new phases of AlNi and LiF during the dehydrogenation process, as well as a reduction in particle size, is believed to be essential contributors in improving the LiAlH4 dehydrogenation characteristics.  相似文献   
8.
Constructing efficient and stable bifunctional electrocatalysts for overall water splitting remains a challenge because of the sluggish reaction kinetics. Herein, the core-shell hybrids composed of Co(PO3)2 nanorod core and NiFe alloy shell in situ grown on nickel foam (NiFe/Co(PO3)2@NF) are synthesized. Owing to the hierarchical palm-leaf-like structures and strong adhesion between NiFe alloys, Co(PO3)2 and substrates, the catalyst provides a large surface area and rapid charge transfer, which facilitates active sites exposure and conductivity enhancement. The interfacial effect in the NiFe/Co(PO3)2 core-shell structure modulates the electronic structure of the active sites around the boundary, thereby boosting the intrinsic activity. Benefiting from the stable structure, the durability of the catalyst is not impaired by the inevitable surface reconfiguration. The NiFe/Co(PO3)2@NF electrode presents a low cell voltage of 1.63 V to achieve 10 mA cm?2 and manifests durability for up to 36 h at different current densities.  相似文献   
9.
In this work, the SnS2 nanoflowers (SnS2 NFs) were solvothermally prepared in the solvent of ethanol, while SnS2 nanoplates (SnS2 NPs) were obtained through the identical conditions except for the solvent of water. The flowers were assembled with numerous nanosheets with very thin thickness, and the NPs exhibited hexagonal shape. When used as the battery-type electrode material for supercapacitors, the SnS2 NFs delivered a specific capacity of as high as 264.4 C g?1 at 1 A g?1, which was higher than the 201.6 C g?1 of SnS2 NPs. Furthermore, a hybrid supercapacitor (HSC) was assembled with the SnS2 as positive electrode and activated carbon (AC) as negative electrode, respectively. The SnS2 NFs//AC HSC exhibited a high energy density of 28.1 Wh kg?1 at 904.3 W kg?1, which was higher than the 24.2 Wh kg?1 at 844.3 W kg?1 of SnS2 NPs//AC HSC. Especially, when the power density was enhanced to the highest value of 8666.8 W kg?1, the NFs-based device could still hold 20.4 Wh kg?1. In addition, both HSC devices showed an excellent cycling stability after 5000 cycles at 5 A g?1. The present method is simple and can be extended to the preparation of other transition metal sulfides (TMSs)-based electrode materials with brilliant electrochemical performance for supercapacitors.  相似文献   
10.
The H2 storage properties of isoreticular metal-organic framework materials (IRMOFs), MOF-5 and IRMOF-10, impregnated with different numbers and types of heterogeneous C48B12 molecules were investigated using density functional theory and grand canonical Monte Carlo (GCMC) calculations. The excess hydrogen adsorption isotherms of IRMOFs at 77 K within 20 bar indicate that suitable number and type of C48B12 molecules play a crucial role in improving the H2 storage properties of IRMOFs. Among the studied pure and nC48B12 (n = 1, 2, 4, 8) in Ci symmetry impregnating into MOF-5, at 77 K under 6 bar, MOF-5-4C48B12 with a 3.5 wt% and 29.9 g/L hydrogen storage density, and at 77 K under 12 bar, the pure MOF-5 with a 4.9 wt% and 31.0 g/L hydrogen storage density has the best hydrogen storage properties. Whereas, among the studied pure and nC48B12 (n = 1, 2, 4, 8) in S6 symmetry impregnating into IRMOF-10, IRMOF-10-8C48B12 always shows the best hydrogen storage properties among the pure and C48B12-impregnated IRMOF-10 at 77 K within 20 bar. IRMOF-10-8C48B12 has a 6.0 wt% and 34.6 g/L hydrogen storage density at 77 K under 6 bar, and has a 7.1 wt% and 41.4 g/L hydrogen storage density at 77 K under 12 bar. The confinement effect of IRMOFs on C48B12 molecules, and steric hindrance effect of C48B12 molecules on IRMOFs mainly affects the H2 uptake capacity by comparing the absolute H2 molecules in individual IRMOFs units, C48B12 molecules, and IRMOFs-nC48B12 compounds. The absolute hydrogen adsorption profiles show that eight C48B12 molecules impregnating into MOF-5 can exert obvious steric effects for H2 adsorption. The saturated gravimetric and volumetric H2 densities of IRMOF-10-8C48B12 higher than those of MOF-5-8C48B12 due to with larger free volume.  相似文献   
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