十二酰胺丙基二甲基羟乙基氯化铵与十二烷基硫酸钠水溶液的表面吸附和胶束形成

利用十二酰胺丙基二甲胺和氯乙醇反应 ,合成了十二酰胺丙基二甲基羟乙基氯化铵 (DDHA)阳离子表面活性剂 ,将其与十二烷基硫酸钠 (SDS)以不同摩尔比进行混合 ,测定了混合系统的表面张力 ,计算了单一系统和混合系统的饱和吸附量、分子最小截面积 ,表面层和胶束中 DDHA的摩尔分率及分子间相互作用参数 ,目视观察了混合系统的浑浊情况。结果表明 :在降低γcmc和 cmc方面 ,DDHA SDS混合系统有协同效应 ,表面层和胶束的组成与二组分配比有关 ,但是非对称的 ,等物质的量混合物中 ,DDHA在胶束和表面层中具有较大的摩尔分数。DDHA与 SDS在实验测定的各混合系统中都不出现混浊     

Mechanical and microstructure studies on the modification of CA film by blending with PS

DriedMusa paradiciaca (banana) stem and veins of the leaves, which were hitherto discarded as a waste, were collected and used as starting material for the preparation of cellulose and cellulose acetate. This cellulose acetate was mixed with polystyrene to form blend of cellulose acetate-polystyrene in order to provide enhanced stability and extended utility to the end products. The films of these composites or their individual partners were made separately and studied for their mechanical properties, chemical modification and morphological changes. We report here that banana stem is good source of cellulose and that cellulose completely undergoes modification upon esterification.     

纤维素的辐射裂解及其化学性质

纤维素经高能射线辐照,能产生一系列的化学和物理性质的变化。本文报道在不同剂量的~(60)Coγ射线辐照下,稻草中的水溶性糖、易水解糖、难水解糖,以及氨基酸、蛋白质等物质的化学变化;用辐射与加泡涨剂相结合的方法处理稻草,可以降低剂量、提高效应。     

新的载体媒介传递膜

总结了近几年研究和发展的几种载体媒介传递膜。与支撑液膜相比，这些膜具有好的稳定性和长的寿命。对某些物质，如重金属离子、小分子中性碳氢化合物、氨基酸等有高的选择性和通量。它们的传递机理为固定位置跳跃或移动和固定载体2种机理结合。这些研究有望在环境、生物等技术领域中应用。     

Inter- and intra-molecular ionic interactions of polyampholyte: Carboxymethyl-2-diethylaminoethylcellulose

Carboxymethyl-2-diethylaminoethylcellulose (CM-DEAE cellulose) was prepared by etherification of carboxymethylcellulose with diethylaminoethyl chloride in a NaOH solution. The behaviour of CM-DEAE cellulose in aqueous solution was studied by viscosity and GPC measurements. The degree of substitution (DS) and existing states of DEAE substituents were examined by the use of proton NMR, and those of the CM substituents were observed with FT-IR. The results reveal that the reduced viscosity and apparent molecular size of CM-DEAE cellulose vary with the concentration of sodium chloride and changes in pH and DS. These phenomena can be explained in terms of inter- and intra-molecular ionic interactions.     

氧浓度对近临界水中纤维素分解的影响

研究了不同初始氧浓度对纤维素在近临界水中分解的影响，实验结果表明，氧浓度显著地影响产物总碳收支平衡，液相不同组分的收率、气体的产量以及气相产物的组成，微量氧对产物总碳收支平衡影响不大，而对液相不同组分的收率有一定的影响。从实验结果可以看出，离子型反应机理在纤维素水解的第一步中起主导作用。而单糖的进一步分解是一个以自由基反应机理为主的过程。     

Preparation and properties of transparent cellulose hydrogels

Highly transparent cellulose hydrogels with physical crosslinkage were prepared from nonaqueous organic cellulose solutions and viscose by coagulating and regenerating cellulose in an aqueous solution containing a water‐miscible organic solvent. Nonaqueous organic cellulose solutions used were LiCl/dimethylacetamide, paraformaldehyde/dimethyl sulfoxide, and triethylammonium chloride/dimethyl sulfoxide. Preparation conditions and physical properties of the transparent cellulose hydrogels were studied. The transparency of the cellulose hydrogels depended on the composition of the aqueous solution containing the organic solvent. Furthermore, transparent cellulose hydrogels from viscose showed high tensile strength. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 3020–3025, 2003     

Properties of paper coated with kaolin: The influence of the rheological modifier

The first part of this paper analyses the influence of the molecular weight and concentration of carboxymethyl cellulose (CMC) and of kaolin concentration on rheology of the coating colours and on paper properties coated with ultra lightweight coatings (ULWC). In the second part, relationships between the rheological characteristics of the coating colour formulations and coated paper surface quality was also studied.New indexes on paper roughness at micro-scale are presented (RZI and SRI). In general, they show good correlation with sheet gloss. A new gloss index (SGI) is presented, accounting for the contribution of gloss from machine direction (MD) and cross direction (CD). Porosimetry was used to access microstructural characteristics in order to correlate them with light scattering and gloss properties. The former property is closely related to Hg intrusion volume of the coated layer while gloss is related to surface porosity with pore diameters in the range of 7–15 μm as measured by Hg intrusion volume.     

Improved cellulase production by stable Clostridium cellulolyticum mutants

Methods for the production of mutants of the cellulase producer Clostridium cellulolyticum ATCC 35319 were examined using an agar plate screening technique. Spontaneous and UV light-induced mutants were isolated, some of which exhibited a high level of both endoglucanase and exoglucanase activities as assayed using CMC (carboxymethyl cellulose) and PNPCb (paranitrophenyi-β-cellobioside) respectively. The volumetric enzyme activities were up to 2.5 times those of the wild strain.     

High‐Tech‐Cellulose‐Funktionspolymere nach dem ALCERU®‐Verfahren

Functional High‐Tech‐Cellulose materials by the ALCERU® process Cellulose is one of the eldest materials of mankind. While the use of cellulose in former times was focused on application as a more construction or as a more textile material at present time the application profile turns to a more functional material using the ALCERU® process. Shaping of pure cellulose dissolution in NMMNO permits the manufacturing of materials for upholstery, filtration or biodegradable film strips having an uniform cross section. Fibreds, which can be applied in several packaging materials, are available using different techniques for regeneration cellulose. A great field of innovative functional cellulose materials is opened up by addition of several functional additives to cellulose dissolution. In this way piezo‐electrical conductive cellulose fibres (PZT) or high‐temperature filtration membranes are to be generated if one adds special types of ceramic powders. Above all PZT green fibres are applied in more recent uses as sensors or actuators. Electrically conductive cellulose fibres or filaments, which can be also used in the textile chain, can be prepared adding conductive carbon black to a cellulose dope on the same way, too. Cellulose material having adapted conductivity to different application is available by adding an exact defined amount of carbon black to cellulose dissolution. Finally cellulose beads can be manufactured by means of varied shaping technique. The beads are showing variable particle sizes and narrow pore size distribution. These properties open up very interesting application in the field of human blood purification or chromatography.