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In the present study we made an effort to deploy eco-friendly synthesized reduced graphene oxide/Lanthanum Alluminate nanocomposites (RGO-LaAlO3) and Lanthanum Alluminate (LaAlO3) as adsorbents to remove dye from the synthetic media. XRD, SEM, BET surface area and EDX have been used to characterize the above-mentioned adsorbents. The impacts of different factors like adsorbent dosage, the concentration of adsorbate and PH on adsorption were studied. The best fit linear and nonlinear equations for the adsorption isotherms and kinetic models had been examined. The sum of the normalized errors and the coefficient of determination were used to determine the best fit model. The experimental data were more aptly fitted for nonlinear forms of isotherms and kinetic equations. Pseudo-second-order and Freundlich isotherm model fits the equilibrium data satisfactorily. Methyl orange (MO) has been used as model dye pollutant and maximum adsorption capacity was found to be 469.7 and 702.2 mg g?1 for LaAlO3 and RGO-LaAlO3, respectively.  相似文献   
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The spongy nickel oxide (SNO) was synthesized the solution combustion method. The SNO was selected as a promoter to boost the catalytic activity of nanoraspberry-like palladium (NRPd) toward electrooxidation of five light fuels (LFs): methanol, ethanol, formaldehyde, formic acid, and ethylene glycol. The X-ray powder diffraction, Fourier-transform infrared spectroscopy (FT-IR), scanning electron microscopy, and field emission scanning electron microscope techniques were used for the materials characterization. In comparison with nonpromoted Pd, the NRPd-SNO electrocatalyst shown an excellent efficiency in parameters like the electrochemical active surface area and anti-CO poisoning behavior. The turnover data and the parameters, including reaction order, activation energy, and the coefficients of electron transfer and diffusion, were evaluated for the each process of LFs electrooxidation. The outcome for NRPd-SNO activity toward LFs electrooxidation was compared to some reported electrodes. The SNO increases the removal of intermediates created in the oxidation of LFs that can poison the surface of palladium catalyst. This is due to the presence of the lattice oxygens in SNO structure and Ni switching between its high and low valances. The compatibility of the adsorption process of LFs on the surface of the NRPd-SNO catalyst with different isotherms was determined by studying the Tafel polarization and calculating the surface coverage.  相似文献   
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The development of high-efficiency adsorbents for heavy metal ion removal from wastewater is highly desirable and challenging due to their synthesis complexity and low adsorption capacities. Herein, we reported the synthesis of strontium (Sr) doped hydroxyapatite (HAp) for the increased Cr (VI) adsorption. The effects of pH, temperature, and time on adsorption performances were studied. As a result, the Sr-HAp nanorods can achieve a Cr (VI) adsorption capacity of 443 mg/g, which is significantly higher than that of HAp nanorods (318 mg/g). To better understand the adsorption mechanism, the Langmuir isotherm model was established. The modeling results indicated that Langmuir monolayer chemical adsorption contributed to the efficient Cr (VI) ion removal for Sr-HAp nanorods adsorbents. The surface area and surface functional groups (O–H) contributed to the different Cr (VI) adsorption capacities between HAp and Sr-HAp.  相似文献   
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Green composites for environmental applications were successfully prepared by intercalation of the biosurfactant Quillaja saponin onto montmorillonite mineral clay on varying pH and surfactant/clay ratio. Equilibrium adsorption isotherms were constructed and the system was characterized by performing TGA and XRD analyses.The efficiency of the surfactant-modified clay in the removal of the organic content present in olive mill wastewaters (OMW) was evaluated by means of spectrophotometric measurements. The interest for this cogent issue comes from the consideration that, despite their high pollutant content, OMW can be considered as a potential resource of several organic compounds which can be recovered for a wide array of pharmaceutical and industrial applications. Two different strategies were proposed. In the first one, dried surfactant/clay hybrids were added to the batch samples under continuous stirring, while in the second alternative approach the organoclays were packed in chromatography column filled with multiple alternate layers of sand and organoclay.These studies revealed the efficacy of the methods used and suggested that the modification of the montmorillonite clay substrate significantly improves the performance of the clay.  相似文献   
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Self-assembled peptide nanofibers (NFs) obtained from β-sheet peptides conjugated with drugs, including antigenic peptides, have recently attracted significant attention. However, extensive studies on the interactions of β-sheet peptide NFs with model cell membranes have not been reported. In this study, we investigated the interactions between three types of NFs, composed of PEG-peptide conjugates with different ethylene glycol (EG) lengths (6-, 12- and 24-mer), and dipalmitoylphosphatidylcholine (DPPC) Langmuir membranes. When increasing the EG chain length, those interactions significantly decreased considering measurements in the presence of the NFs of: (i) changes in surface pressure of the DPPC Langmuir monolayers and (ii) surface pressure–area (π–A) compression isotherms of DPPC. Because the observed trend was similar to the EG length dependency with regard to cellular association and cytotoxicity of the NFs that was reported previously, the interaction of NFs with phospholipid membranes represented a crucial factor to determine the cellular association and toxicity of the NFs. In contrast to NFs, no changes were observed with varying EG chain length on the interaction of the building block peptide with the DPPC membrane. The results obtained herein can provide a design guideline on the formulation of β-sheet peptide NFs, which may broaden its potential.  相似文献   
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不同米蛋白组分与镉的结合规律   总被引:1,自引:0,他引:1  
对制备的4种不同米蛋白样品与镉进行结合动力学、热力学分析,结果表明:4种蛋白与镉结合的速度均非常快,30min就达到了反应平衡;其中,醇溶蛋白与镉的结合量最高(23.78mg/g),球蛋白的q值最低(3.64mg/g);结合过程符合准二级动力学模型;与Freundlich模型相比,Langmuir模型能更好地用来描述4种蛋白的等温吸附;结合反应的ΔG°值均为负值,而ΔH°均为正值,表明都是自发的吸热反应;酶提蛋白、谷蛋白、醇溶蛋白的ΔH°分别为41.44,40.32,58.75kJ/mol,推测它们与镉的结合是配位结合,其中醇溶蛋白可能是多齿配位;氨基酸组成的不同,可能是影响4种米蛋白与镉结合的主要因素,谷氨酸和天冬氨酸含量之和与q值的相关性达到了0.967。  相似文献   
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