Influence of size-classified and slightly soluble mineral additives on hydration of tricalcium silicate

Early-age hydration of cement is enhanced by slightly soluble mineral additives (ie, fillers, such as quartz and limestone). However, few studies have attempted to systematically compare the effects of different fillers on cementitious hydration rates, and none have quantified such effects using fillers with comparable, size-classified particle size distributions (PSDs). This study examines the influence of size-classified fillers [ie, limestone (CaCO₃), quartz (SiO₂), corundum (Al₂O₃), and rutile (TiO₂)] on early-age hydration kinetics of tricalcium silicate (C₃S) using a combination of experimental methods, while also employing a modified phase boundary and nucleation and growth model. In prior studies, wherein fillers with broad PSDs were used, it has been reported that between quartz and limestone, the latter is a superior filler due to its ability to partake in anion-exchange reactions with C-S-H. Contrary to prior investigations, this study shows that when size-classified and area matched fillers are used—which, essentially, eliminate degrees of freedom associated with surface area and agglomeration of filler particulates—the filler effect of quartz is broadly similar to that of limestone as well as rutile. Results also show that unlike quartz, limestone, and rutile—which enhance C₃S hydration kinetics—corundum suppresses hydration of C₃S during the first several hours after mixing. Such deceleration in C₃S hydration kinetics is attributed to the adsorption of aluminate anions—released from corundum's dissolution—onto anhydrous particulates’ surfaces, which impedes both the dissolution of C₃S and heterogeneous nucleation of C-S-H.     

2 500 t/d生产线煅烧高镁熟料的生产应用

四川省兆迪水泥有限责任公司2500t/d新型干法熟料生产线,于2014年7月11日重建点火投产。生产过程中针对工厂高镁石灰石的原料特点,注意总结工艺操作、熟料质量等方面的经验,采取了积极有效的措施,取得了较好的效果。     

高温悬浮态下石灰石与菱镁矿热分解 特性比较及动力学研究

利用悬浮态高温炉,对比研究了菱镁矿及石灰石的热分解特性,探讨了其热解模型及动力学参数。结果表明:低温段(650~750℃)时,菱镁矿比石灰石易分解,达到一定高温后其分解速率相差不大;菱镁矿、石灰石在悬浮态下的热解机理均符合收缩核模型,其活化能分别为50 kJ/mol、79 kJ/mol;随着菱镁矿粒度的增大,其分解速率趋缓,分解表观活化能增大。     

Estimates for the local permeability of the Cobourg limestone

Argillaceous limestone formations are being proposed as sites suitable for constructing a deep geologic repository for storing low-to intermediate-level nuclear waste in southern Ontario, Canada. The Cobourg limestone is characterized by a visual appearance of heterogeneity resulting from light gray calcite nodular regions interspersed with dark gray calcite-dolomite-quartz partings containing a clay component. This paper presents the results of experiments conducted to determine the permeability of both the light gray and the dark gray species of the Cobourg limestone. The permeabilities were successfully estimated from both steady state and hydraulic pulse tests conducted using specially designed miniature water entry ports, which were epoxied to the surface of the rock sample containing cavities drilled into the rock species of interest. The results show that the dark gray species of the Cobourg limestone has a permeability that is roughly one order of magnitude greater than the light gray calcite species.     

基于声发射和高斯混合模型的灰岩破裂特征识别研究

通过单轴压缩条件下灰岩破裂过程的声发射试验研究,利用高斯混合模型(GMM)对加载过程声发射信号波形特征进行深入分析,探索性识别灰岩破裂失稳过程的裂纹模式及其前兆特征。分析结果表明,灰岩在单轴加载过程中先后主要存在张拉和剪切两种破裂模式。其中,张拉破裂的声发射信号波形特征在AF-RA坐标空间呈现低A_F值、高R_A值分布;剪切破裂的声发射信号波形特征在AF-RA坐标空间呈现低R_A值、高A_F值,且随着应力的增加分布中心向A_F轴靠拢。GMM分析结果揭示了灰岩在整个应力加载过程中以张拉裂纹为主,在加载前中期几乎全为张拉裂纹,临近破坏阶段过渡到剪切破坏为主。剪切裂纹所占比例的最大值出现在(0.8～0.9)σ_c阶段,也是AF-RA坐标轴分布呈现最大A_F值时。研究结果可为预测早期灰岩破裂失稳提供参考,同时为深入研究识别岩石破裂失稳前兆信号特征提供了一种分析方法。     

破损水文观测孔涌水封堵技术在高河矿的应用

针对高河矿奥灰水文观测孔空水管锈蚀断裂漏水严重的问题,分析了存在的问题,制定了钻孔涌水封堵技术方案及相应的注浆施工工艺,并进行了为期7天的井下试验。封堵注浆压力达到6 MPa,使用注浆水泥50 t,水泥浆液凝固良好,注浆阀门打开后无出水现象。     

含磷石灰岩矿的特征及其对水泥生产的影响

简要地分析了磷酸盐矿物的地质特征和结构特征,并详细分析了安哥拉罗安达水泥厂含磷石灰岩矿床的化学组成、磷和氟含量及其矿物特征和形貌。在此基础上,重点试验研究了P2O5对水泥生产和熟料性能的影响情况。试验结果初步显示:(1)含磷高的原料对熟料的烧成和产品性能影响很大,因P2O5既会影响水泥熟料矿物C3S的形成,还会阻碍水泥的早期水化,严重影响水泥的凝结和硬化过程;(2)熟料中当w(P2O5)2.0%时可以制备性能满足要求的水泥,在生产控制中要严格控制生料中w(P2O5)1.0%[石灰石中w(P2O5)0.8%]为宜;(3)在含磷熟料中,适量F-的存在[w(F-)0.35%]能降低P2O5的负影响。     

露天石灰石矿的开采方案及采准工作面的设计布置

矿山基建采准工作面布置,直接影响到基建工程量、投资费用和施工时间;而基建采准工作面位置的选择与设计布置又是一个系统工程,需考虑各种因素和条件,如山势地形、矿体规模、矿区地质,矿石储量、开采规模等等。以焦作千业水泥有限责任公司5000t/d熟料线的谷堆后矿区为例,详细介绍了该矿的储量、地形、矿体、夹层、上部覆盖层等总体概况;在此基础上重点介绍了该矿山基建采准工作面的设计布置情况,包括考虑因素、设计方案和建成后的生产情况。     

SO_3对高镁硅酸盐水泥熟料组成和性能的影响

为了充分利用高镁石灰石和高硫煤资源,本文从生料的易烧性、熟料矿物的形成状况以及熟料性能入手,运用化学分析、X射线衍射、岩相分析等测试手段,研究了SO3对高镁硅酸盐水泥熟料组成和性能的影响。研究表明,当熟料中MgO含量较高时,通过控制熟料中SO3/MgO比,能够生产出性能优良的高镁硅酸盐水泥熟料。