Fe-based bulk metallic glasses (BMGs) with high boron content have potential application as a coating material used in the framework for storing spent nuclear fuels to support their safe long-term disposal. The high glass forming ability (GFA) and large supercooled liquid region are therefore required for such Fe-based BMGs in either the glassy powder fabrication or the subsequent coating spraying. In order to meet these requirements, the influence of Nb content on the GFA of Fe57Cr10Zr8B18Mo7−xNbx (x=1–5, at.%) alloys was investigated, as Nb has positive roles in GFA and thermal stability of BMGs. The results indicate that a fully amorphous phase in the as-cast samples with 3 mm in diameter is obtained for both the Fe57Cr10Zr8B18Mo5Nb2 and Fe57Cr10Zr8B18Mo4Nb3 alloys. The corresponding supercooled liquid regions of the two BMGs are 78 K and 71 K, respectively. The mechanism for improving their GFA was analyzed based on the principle of metal solidification, the parameters for glass formation and thermal properties of the alloys. The compression strength and Vicker’s hardness of the two BMGs are 1,950 MPa and 1,310 HV, 2,062 MPa and 1,180 HV, respectively. The developed BMGs with high B content, good GFA, and very high hardness can be used as coating materials to the framework for spent nuclear fuels.
为提高城市排水防涝能力,满足国家、地方政策及标准要求,老城区低标排水系统提标改造需求日益迫切。但许多老城区存在现状条件复杂、地下公用管线多、道路狭窄、施工条件苛刻等问题,提标改造难度较大。文中以上海市宝山区月浦城区雨水排水系统提标改造工程为例,详细介绍工程设计方案,结合Info Works ICM排水模型对系统内积水风险、管网水力条件进行分析,结果表明:提标改造后的管网系统在3年一遇设计降雨时,可保证城区内无积水产生,系统内大部分管道的水力坡度与管道坡度接近,基本未出现非满管或超载的情况;在100年一遇的设计降雨时,城区内积水深度普遍在0.15 m以下。针对排水系统改造中的重点、难点,提出充分利用现状设施、合理选择顶管与开槽埋管相结合的施工方案、减少骑马井数量、利用已建雨水管道收集路面雨水、合理确定井位管位,减小管线搬迁工程量等解决方案,同时,对关键节点进行具体分析。案例可为其他老城区的雨水排水系统提标改造工程提供一定的借鉴。 相似文献
The direct-synthesis of conductive PbS quantum dot (QD) ink is facile, scalable, and low-cost, boosting the future commercialization of optoelectronics based on colloidal QDs. However, manipulating the QD matrix structures still is a challenge, which limits the corresponding QD solar cell performance. Here, for the first time a coordination-engineering strategy to finely adjust the matrix thickness around the QDs is presented, in which halogen salts are introduced into the reaction to convert the excessive insulating lead iodide into soluble iodoplumbate species. As a result, the obtained QD film exhibits shrunk insulating shells, leading to higher charge carrier transport and superior surface passivation compared to the control devices. A significantly improved power-conversion efficiency from 10.52% to 12.12% can be achieved after the matrix engineering. Therefore, the work shows high significance in promoting the practical application of directly synthesized PbS QD inks in large-area low-cost optoelectronic devices. 相似文献