Chemical durability and surface alteration of lanthanide zirconates (A2Zr2O7: A = La-Yb)

Chemical durability of lanthanide zirconates (A₂Zr₂O₇) (A = La-Yb) under near-field environments is important for evaluating their application as potential nuclear waste forms. In this work, A₂Zr₂O₇ (A = La-Yb) are synthesized by spark plasma sintering with controlled microstructure and their chemical durability are evaluated in a nitric acid solution (pH = 1). Scanning transmission electron microscopy analysis reveals an amorphous passivation film either enriched with Zr or lanthanide. The complex chemistry of the passivation films can be correlated with a transition in corrosion mechanisms from a preferential release of lanthanide in La₂Zr₂O₇ to a preferential release of Zr in Er₂Zr₂O₇ and Yb₂Zr₂O₇. These results suggest a dominant mechanism of incongruent dissolution and surface reorganization for the formation of passivation films. Strong correlations are identified between the leaching rates and cation ionic size, ionic potential, electronegativity differences between A-site cation and Zr, and bonding valence sum of oxygen, suggesting important impacts of structural and bonding characteristics in controlling chemical durability of lanthanide zirconates.     

虚实结合的可穿戴产品适合性检验研究

目的 为了更科学地研究和检验可穿戴产品的适合性,提出一种适合性检验方法,能够精确保留现实环境中的产品佩戴关系,并能将现实与虚拟的适合性检验研究相结合,得到合理的适合性检验结果.方法 以虚拟现实眼镜的适合性检验为例,通过高精度的三维测量技术将现实环境中的人、产品以及人—产品佩戴关系转化为三维虚拟信息,并以人—产品佩戴三维模型为参考基准对齐人和产品的虚拟模型,得到保留现实佩戴关系的人—产品佩戴模型组,再应用偏差分析法得出人—机佩戴区域的可视化适合性结果和统计数据,结合主观评价方法进一步分析产品的适合性.结论 虚实结合的产品适合性检验方法可在虚拟环境中高精度地保留现实环境中的人—产品佩戴关系,并能得到可视化的适合性检验结果,为检验和指导产品的适合性提供依据.     

海南小型露天采石场矿山地质环境治理方法探讨：以日富石场为例

海南小型露天采石场矿山数量多且呈遍地开花式分布，且不规范的开采对环境造成较大的破坏，与绿色矿山之路背道而行，相对大型矿山规范化的治理，小型矿山治理比较滞后，本文以日富采石场地质环境治理为例，通过摸清当地的地质环境条件，结合矿山现状，因地制宜地制定出日富采石场地质环境治理的具体措施，通过治理可获得林地2.6hm2，矿山安全隐患及地貌景观等矿山地质环境问题得到有效地防治，有效解决农业灌溉及周边虾塘养殖用水缺乏问题，实现较好的社会经济效益，为今后治理类似矿山提供参考。     

乡村振兴战略下地方文创产品设计实践研究

目的 从设计学角度探索乡村振兴战略下的文创产品助农模式，深入挖掘、继承和创新优秀的传统乡土文化，将保护、传承和开发利用结合起来，为中华农耕文明赋予新的时代内涵，并应用于平谷区设计实践，助力乡村第一产业和第三产业的发展。方法 依托情感化设计理论，构建文创助农模型，依托北京互联农业果蔬产业创新创业孵化实训基地，借助“以花为媒，营销平谷”的东风，验证模型的可行性。结果 在文创助农模型的基础上，充分挖掘平谷区地方特色文化，结合中国古代哲学系统观“五行”思想，开发五行桃花运势皂，对产品、外观包装及购买交互方式等方面进行深入设计研究，探索了地方特色文创产品设计创新的思路、方法和路径，突出了情感价值提升地方特色文创产品设计的重要作用。结论 文创助农模型能够促进乡村地区农副产品资源的二次利用，提高乡村区域知名度，拉动当地经济增长。     

地域文化元素融入都江堰旅游产品的设计策略

目的 针对目前市面上都江堰旅游产品识别性较弱、同质化严重，对具有地域文化特色的旅游产品开发较少的问题，以地域文化元素作为都江堰旅游产品设计的核心，提出旅游产品的设计策略。方法 研究都江堰旅游产品设计，应从地域化和文化内涵入手。通过分析旅游产品现状，地域文化元素及新旅游时代背景下旅游产品的发展趋势，结合情感化设计理念，围绕用户体验进行探究，总结出都江堰旅游产品设计开发模式。以李冰石像和鱼嘴段水利工程元素为例，进行产品实践。结论 提出符合都江堰区域特色的旅游产品设计策略，即树立品牌意识、打造IP形象，以地域文化元素为设计核心，加强情感互动、与科技相融合的设计策略。赋予旅游产品更深层次的内涵，打造更多具有地域文化特色的旅游产品，从而推动历史文化与商业价值的融合，也能够为同类型旅游产品提供具有应用价值和参考的设计策略和思路。     

Ammonia mitigation and induction effects on hydrogen environment embrittlement of SCM440 low-alloy steel

The effect of ammonia (NH₃) contained in hydrogen (H₂) gas on hydrogen environment embrittlement (HEE) of SCM440 low-alloy steel was studied in association with the NH₃ concentration, loading rate, and gas pressure. NH₃ worked as both mitigator of the HEE and inducer of hydrogen embrittlement (HE) depending on the testing conditions. The mitigation of the HEE was achieved by the deactivation of the iron (Fe) surface for H₂ dissociation caused by the preferential adsorption of NH₃ on the Fe surface, which is enhanced by the increase in the NH₃ concentration and decrease in the H₂ gas pressure. NH₃ induced HE was caused due to creating hydrogen by the NH₃ decomposition. Since the NH₃ decomposition rate is low, the induction effect was observed when the loading rate was low. The effect of NH₃ was determined by the competition of the mitigation and induction effects.     

Application of artificial neural network method to predict the breakage properties of PGE bearing chromite ore

In the present investigation, systematic grinding experiments were conducted in a laboratory ball mill to determine the breakage properties of low-grade PGE bearing chromite ore. The population balance modeling technique was used to study the breakage parameters such as primary breakage distribution (B_{i, j}) and the specific rates of breakage (S_i). The breakage and selection function values were determined for six feed sizes. The results stated that the breakage follows the first-order grinding kinetics for all the feed sizes. It was observed that the coarser feed sizes exhibit higher selection function values than the finer feed size. Further, an artificial neural network was used to predict breakage characteristics of low-grade PGE bearing chromite ore. The predicted results obtained from the neural network modeling were close to the experimental results with a correlation of determination R² = 0.99 for both product size and selection function.     

Inhibitory effects of curcumin and piperine on fluorescent advanced glycation end products formation in a bovine serum albumin–fructose model

This study investigated the inhibitory effects of curcumin and piperine on fluorescent advanced glycation end products (fAGEs) formation in a bovine serum albumin (BSA)–fructose model. Model systems of BSA and fructose were prepared, and curcumin or piperine was added. fAGEs and BSA oxidation product (dityrosine, kynurenine and N'-formylkynurenine) contents were determined. The results showed that fAGEs content decreased with increasing concentration of curcumin and piperine (P < 0.05). Addition of curcumin and piperine at 160 µg mL⁻¹ could inhibit fluorescent AGEs by 100% and 93% respectively. Dityrosine and N'-formylkynurenine contents decreased as curcumin and piperine concentration increased (P < 0.05). Furthermore, the result of principal component analysis indicated that curcumin and piperine markedly impeded BSA oxidation, resulting in a lower level of fAGEs in model systems. Therefore, adding curcumin and piperine may facilitate reduced fAGEs levels in BSA–fructose model.     

Graduate Student Literature Review: Considerations for nutritional grouping in dairy farms

Each cow in a group has different nutritional requirements even if the group is formed by cows of similar age, number of lactations, and lactation stage. Common dairy farm management setup does not support formulating a diet that accurately matches individual nutritional requirements for each cow; therefore, a proportion of cows in the group will be overfed and another proportion underfed. Overfeeding and underfeeding cows increases the risk of metabolic diseases, decreases milk production, and increases nutrient waste. Consequently, profitability of dairy farms and the environment are negatively affected. Nutritional grouping is a management strategy that aims to allocate lactating cows homogeneously according to their nutritional requirements. Groups of cows with more uniform nutritional requirements facilitates the formulation of more accurate diets for the group. Current availability of large data streams on dairy farms facilitates the design of algorithms to implement nutritional grouping. Our review summarizes important factors to consider when grouping cows, describes nutritional grouping approaches, and summarizes benefits of implementing nutritional grouping in dairy farms.