The radiation crosslinking and scission of ethylene-propylene copolymers studied by solid-state nuclear magnetic resonance

Methyl groups from chain scission and H-crosslinks have been identified by solid-state nuclear magnetic resonance in amorphous ethylene-propylene copolymers containing 23 and 36 mole % propylene after γ-irradiation to 10 MGy at 30°C. G (scission) and G (crosslink) values determined from the n.m.r. spectra and by extraction are in agreement, which suggests that the crosslinks are not clustered. This may differ from the situation in polyethylene where there is a substantial crystalline content. G(S). G(X) and the ratio G(S)/G(X) increase with increasing propylene content of the copolymers.     

A test object with a line width less than 10 nm for scanning electron microscopy

Data are given on the test object for scanning electron microscopy in which the components (ridges) are of trapezoidal profile and have large angles of inclination for the side walls. The width of the top surface of a projection is less than 10 nm. Methods have been developed for measuring such dimensions of test objects on standard scanning electron microscopes. __________ Translated from Izmeritel'naya Tekhnika, No. 8, pp. 20–23, August, 2008.     

802.11系列标准演进的支撑技术分析

移动数据流量迅猛增长,给成本高、速率低的2G、3G、4G移动网络带来了巨大压力,运营商开始大规模部署WLAN(无线局域网),以减轻移动网络压力。文章介绍从最初支持2Mbps接入速率的WLAN标准到目前千兆标准的演进历程,分析支撑其传输速率节节攀升的关键技术,包括分布在物理层的信道捆绑、MIMO(多输入多输出)天线技术、OFDM(正交频分复用)、高效的调制编码及MAC(介质访问控制)层的帧聚合、块确认等。     

Hall effect characterization of LPE HgCdTe P/n heterojunctions

The field and temperature dependence of the Hall coefficient has been used to simultaneously extract information about the p and n layers in very long wave length infrared P/n HgCdTe heterojunctions. The field dependence allows the effects of high mobility electrons to be separated from those of low mobility holes. The higher the magnetic field, the higher the sensitivity to the parameters of the P layer. For a maximum magnetic field of 8000 gauss, the hole sheet concentration must be at least five times the electron sheet concentration to obtain accurate results for the P layer. This criterion is satisfied for typical liquid phase epitaxy (LPE) heterostructures. The analysis determines the hole sheet resistance (concentration times mobility), rather than the hole concentration or mobility separately. Independent knowledge of the P layer thickness and the relationship between hole concentration and resistivity are needed to convert the Hall measurement results to hole concentrations. Analysis of the field-dependent Hall data is complicated by the finding that at least three electrons of different mobilities are needed to fit the field dependence of the Hall coefficient in n-type LPE HgCdTe layers. These results are consistent with previous conclusions that electrons with different mobilities are needed to model bulk n-HgCdTe, and with a range of mobilities in the graded composition interface between the LPE layer and CdTe substrate. Consistent results are obtained for the concentrations and mobilities of the three types of electrons in the n-HgCdTe layer with and without the P layer present. N and P type carrier concentrations are also consistent with dopant concentrations measured by secondary ion mass spectroscopy.     

分形理论在煤储层物性研究中的应用

基于分形理论在地质问题研究中的标度不变性 ,利用煤层的自然粒级组成和压汞法测出的煤中不同孔径段的比孔密资料。进行了煤岩破碎结构的块度分形和孔隙结构分形 ,并就分形特征在构造煤破碎程度的划分中的意义及其对煤层气开发的影响进行了探讨。尤其指出了煤层孔隙结构分形存在两个“无标度区” ,孔径大于 10 -10 m的分数维 (D1) ,可用于评价煤层气的解吸和运移 ,小于 10 -10 m的分数维 (D2 )可用于评价煤层气的吸附与扩散。     

塑炼1,2-聚丁二烯的无扰尺寸

利用测得(?)和[η]数据,由Stockmayer-Fixman-Burchard、Stockmayer-Kurata-Roig和Inagaki-Suzuki-Kurata方程外推,估算了塑炼过程中不同1,2-链节含量的1,2-聚丁二烯(1,2-PB)的无扰尺寸变化规律。1,2-链节含量分别为40％和87.2％时,随薄通次数的增加,无扰尺寸降低;但前者薄通50次后变化很小,后者薄通100次后仍有波动。1,2-链节含量为87.2％的1,2-PB,薄通后放置30d,其无扰尺寸随薄通次数的增加而降低的程度,均大于当日测定的结果。     

新兴家庭网络技术的发展与分析

随着数字家电的普及,家庭网络技术呈现出越来越广阔的市场应用前景。包括HomePlug,HomePNA,MoCA,802．11n,UWB、60GHz无线技术等在内的一些新兴技术正在组建家庭网络中逐步得以实现和应用。