A comparison of shear stress estimation methods for a single geobag on a rough bed

There are several methods for estimating bed shear stress in the literature, but comprehensive comparisons among them are limited and under specific conditions. This study compared these methods first on a bare smooth bed, and then for a single geobag on a rough bed in the interest of determining the stability of geobags used in riverbank protection structures. The geobag was filled with cement or sand and tested under different open channel flow conditions. The turbulent kinetic energy method appeared to best represent the local bed shear stress on the geobag when using the newly calibrated proportionality constants. The Reynolds stress method via extrapolation was relatively unaffected by changes to the geobags shape and measurement locations, suggesting this method inadequately represents the local bed shear stress. The Patel method and the universal law of the wall method failed to represent local bed shear stress in the rough bed cases due to instrument limitations and the breakdown of the law of the wall. This study highlights the impact of different methods on the bed shear stress estimation.     

Theoretical study on a kind of cyclization mechanism of boron trichloride and hexamethyldisilazane to form the borazine ring for SiBCN ceramics precursor

Borazine rings act as a pivotal part in siliconboroncarbonitride ceramics (SiBCN) for high-temperature stability and great resistance to crystallization. A detailed investigation of the ring formation mechanism will guide the design and synthesis of SiBCN to meet application requirements under extreme conditions. Boron trichloride (BCl₃) and hexamethyldisilazane (HN(SiMe₃)₂) are common raw materials for the synthesis of precursors for SiBCN. In this paper, quantum chemical calculation was used to study the cyclization reaction mechanism between BCl₃ and HN(SiMe₃)₂ to form trichloroborazine (TCBZ) at the MP2/6-31G (d,p) level of theory. We discussed the structure properties, reaction pathways, energy barriers, reaction rates, and other aspects in detail. The results show that BCl₃ and HN(SiMe₃)₂ alternately participate in the reaction process, accompanied by the release of trimethylchlorosilane (TMCS), and that the entire reaction shows an absolute advantage in terms of energy. In the Step by step reaction, lower reaction barriers are formed due to the introduction of BCl₃ with more heat released compared to that for the introduction of HN(SiMe₃)₂. The final single-molecule cyclization and TMCS elimination steps are found to be faster compared to all previous bimolecular reactions.     

木片筛余物高得率半化学法清洁制浆技术研究

以太阳纸业备料车间木片筛选碎料（筛余物）为原料，对其烧碱法半化学制浆的实验室工艺和生产试验进行了研究。结果表明，筛余物采用半化学法制浆可获得较高得率和环压强度的纸浆，且用碱量对纸浆性能有显著影响。相对8%NaOH （相对于绝干原料）化学预处理，采用14%NaOH化学预处理结合两段浆浓22%的高浓磨浆工艺，所制半化学浆抄造浆张的裂断长和环压指数分别达2.89 km和9.76 N·m/g，是前者的1.9倍和1.2倍，而且优于现用国内OCC废纸浆抄造浆张；生产试验得到的浆张性能指标与实验室相吻合，其中紧度和环压强度分别达到GB/T 13023—2008瓦楞芯（原）纸AA级和A级优等品要求。     

Morpholine As a Scaffold in Medicinal Chemistry: An Update on Synthetic Strategies

Morpholine is a frequently used heterocycle in medicinal chemistry and a privileged structural component of bioactive molecules. This is mainly due to its contribution to a plethora of biological activities as well as to an improved pharmacokinetic profile of such bioactive molecules. The synthesis of morpholines is a subject of much study due to their biological and pharmacological importance, with the last such review being published in 2013. Here, an overview of the main approaches toward morpholine synthesis or functionalization is presented, emphasizing on novel work which has not been reviewed so far. This review is an update on synthetic strategies leading to easily accessible libraries of bioactives which are of interest for drug discovery projects.     

基于改进型巴特勒矩阵的短波8元圆环阵列多波束技术研究

传统短波接收天线为单一的波束指向天线或全向天线。为提高接收天线增益,同时产生多个波束指向不同方向,提出利用巴特勒矩阵作为短波接收天线阵的无源波束形成网络。在传统8×8巴特勒矩阵结构的基础上,设计改进型8×8巴特勒矩阵。以均匀8元圆环阵列为天线模型,利用FEKO仿真分析了其天线特性。在3~11 MHz频段内,P2、P3、P6、P7四个端口分别在202.5°、292.5°、112.5°、22.5°方向上得到了方向性较强的单一波束,7 MHz时波束增益达到最大11.9 dBi,波瓣3 dB宽度平均为60°;在P1、P4、P5、P8端口产生相同的2个波瓣,7 MHz时其波束增益达到最大9.8 dBi,波瓣3 dB宽度平均为89°。由以上仿真分析得出,该改进型8×8巴特勒矩阵能够同时产生6个波束,波束覆盖8个方向,提高了波束的方向性,提高了天线增益。     

A values–beliefs–attitude model of local food consumption: An empirical study in China and Denmark

Consumers’ and policy makers’ interest in local foods is growing. Accordingly, researchers are also increasingly paying attention to the consumption of local foods. Studies have identified preference for local foods as an emergent consumer ideology called “locavorism”, but they have not yet addressed its antecedents or put it into a theoretical context. In addition, extant research provides several insights into local food buying behaviour in developed economies (e.g., USA, UK, Germany, or Italy); however, studies simultaneously conducted in developed and emerging economies are lacking. To address these research gaps, this study develops a conceptual framework with proposed relationships among values, beliefs (locavorism and fresh start mindset), and attitudes towards and intentions to purchase local foods in China and Denmark. We conducted an online survey in China and Denmark that evaluated our constructs with pre-developed multiple-item measures. Using structural equation modelling to test the integrated model, we find that values and long-term orientation are antecedents of consumer beliefs but the influences of values on consumer beliefs differ between collectivistic-dominated China and individualistic-dominated Denmark. Specifically, collectivistic values are significantly and positively related to locavorism in both countries, while individualistic values are strongly linked to locavorism only in Denmark; collectivistic values have no effects on fresh start mindset for the two samples, but individualistic values are significantly and positively related to a fresh start mindset in Denmark. In addition, consumer beliefs are significantly and positively associated with attitudes towards and intentions to buy local foods. Local food marketers can use our findings to target their communications more effectively.     

融入局部几何特征的流形谱聚类图像分割

为了改善谱聚类图像分割的精准性和时效性,文中提出融入局部几何特征的流形谱聚类图像分割算法.首先,考虑图像数据的流形结构,在数据点的K近邻域内执行局部PCA,得到数据间本征维数的关系.然后,引入流形学习中的局部线性重构技术,通过混合线性分析器得到数据间局部切空间的相似性,结合二者构造含有局部几何特征的相似性矩阵.再利用Nystr m技术逼近待分割图像的特征向量,对构造的k个主特征向量执行谱聚类.最后,在Berkeley数据集上的对比实验验证文中算法的准确性和时效性优势.     

Influence and comparison of emerging techniques of yarn manufacturing on physical–mechanical properties of polyester-/cotton-blended yarns and their woven fabrics

Abstract

In this study, the physical–mechanical properties of ring spun, ring compact, rotor and air-vortex yarns were investigated. The study was carried with yarn having linear densities of 24.4 tex and 36.7 tex, which were then converted to woven fabrics. The ring spun yarns have higher values of strength but also with higher strength irregularities. Extra-ordinarily low hairiness was observed in air-vortex yarns due to its unique yarn formation technique. The deviation rate (DR) of yarns have correlation with the mass spectrogram of respective yarns obtained from USTER Tester 5. Rotor and air-vortex yarns exhibited higher coefficient of friction. The woven fabrics made from ring spun yarns exhibited higher tensile and tear strength with higher elongation at break. The fabrics made from air-vortex yarns have very good pilling grade due to less protruding fibres on their surface and good structural integrity.     

增材制造技术在超高膨胀封隔器中的应用

石油和天然气行业不断关注增材制造技术在航空航天和汽车行业的应用发展。研发了利用增材制造技术的超高膨胀封隔器,该封隔器的支承环系统由增材制造。增材制造设计大幅减少了支承系统的构件数量,同时显著提高了膨胀能力和额定压力。密封元件系统与增材制造支承环安装在一起,提供了极端膨胀比、零挤压间隙和对不规则孔的良好适应性。分析和测试结果表明:直径膨胀比高达111%,与常规封隔器相比,提高50%以上; 至少涵盖5种线重的套管(外径相同); 在148.89 ℃的温度下,密封元件能够保持压力68.95 MPa。介绍了增材制造技术、增材制造支承环概念、增材制造材料力学性能、密封元件系统优化和测试情况,以期给我国的完井作业提供借鉴。