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1.
《Ceramics International》2022,48(11):15268-15273
SiC/SiC mini-composites reinforced with SiC fibers coated with different numbers of ZrSiO4 sublayers prepared via a non-hydrolytic sol-gel process were fabricated. The tensile strength and work of fracture of the prepared SiC/SiC mini-composites were determined, and the relationship between their mechanical properties and fracture morphologies was discussed. The toughening mechanism and the variation tendency of their mechanical properties were further elaborated by analyzing the interfacial debonding morphologies of the SiC/SiC mini-composites with 1 and 4 layers of ZrSiO4 interphase as well as the results of prior studies. A relatively rare phenomenon—the delamination of the multilayer ZrSiO4 interphase in the SiC/SiC mini-composites but not on the SiC fibers—was observed, which clearly demonstrated the weak bonding between the ZrSiO4 sublayers in the SiC/SiC mini-composites. The ZrSiO4 sublayer delamination mechanism was then explained based on the high-magnification morphologies found in and beside the ZrSiO4 interphase.  相似文献   
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《Ceramics International》2022,48(4):5312-5320
Ce3+ and Pr3+ co?doped Lu3Al5O12 phosphors were synthesized by the sol–gel process, and their crystal structure, photoluminescence (PL) properties, and energy transfer (ET) from the Ce3+ to Pr3+ were studied. The Lu2.94?yAl5O12:0.06Ce3+, yPr3+ phosphors (0.002 ≤ y ≤ 0.008) showed the green?yellow emission from the 2D3/2 → 2F5/2, 7/2 transition of Ce3+ and the red emission at 610 and 637 nm, which were caused by the 1D23H4 and 3P03H5 transitions of Pr3+, respectively. The optimal concentration of Pr3+ for efficient ET was found to be x = 0.006. The electric quadrupole?quadrupole interaction was responsible for the concentration quenching in the Lu2.94?yAl5O12:0.06Ce3+, yPr3+ phosphors, based on Dexter's theory. The incorporation of Pr3+ for Lu3+ enhanced the red PL intensity in the Lu2.94Al5O12:0.06Ce3+ phosphor.  相似文献   
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李淼  赵虹  姜标  陈思远  闫龙 《化工学报》2022,73(5):1908-1919
煤制电石(CaC2)乙炔工艺在我国煤化工行业中占有重要地位。但其关键中间体CaC2的工业生产过程具有反应温度高、能耗大、CO2排放严重等问题,严重制约了电石及下游相关产业的发展。开发绿色环保的煤制电石替代工艺具有重要意义。本研究提出采用BaC2替代CaC2作为煤制乙炔工艺的关键中间体,从热力学角度分析了BaC2合成反应体系的特点,并在1550℃进行了合成BaC2的实验验证。结果表明,以BaC2替代CaC2为煤制乙炔的关键中间体、通过BaCO3-BaC2-Ba(OH)2-BaCO3的钡循环将碳和二氧化碳转化为乙炔和一氧化碳的新路线,具有反应温度低、零CO2排放、联产CO、固废排放少等优点,可以为现代煤化工的绿色发展提供新的思路。  相似文献   
6.
《Ceramics International》2022,48(6):7897-7904
High-performance B4C-PrB6 composites were prepared via hot-pressing sintering with matrix phase B4C and with 2–5 wt% Pr6O11 as additive. The effects of different sintering processes and Pr6O11 content on the microstructure and mechanical properties of the composites were studied in detail. It is found that increasing sintering temperature and pressure will contribute to the densification of B4C-PrB6 composites. Coarse grains are formed in B4C without additives at high temperature conditions, resulting in the decrease of the densification. Pr6O11 can effectively hinder the formation of coarse grains and finally promote the densification of the composites. The main toughening mechanisms of composites was crack deflection. The composites with 4 wt% Pr6O11 prepared at 2050 °C and 25 MPa had the best comprehensive mechanical properties. The relative density, hardness, flexural strength and fracture toughness reached to 98.9%, 37.6 GPa, 339 MPa and 4.4 MP am1/2, respectively.  相似文献   
7.
《Ceramics International》2022,48(9):12585-12591
In this study, zinc oxide (ZnO) nanofibers were prepared using the electrospinning method, and the effects of different spinning voltages and annealing temperatures on the fiber structure were tested. La0.8Sr0.2FeO3 (LSFO) perovskite film was prepared by a sol-gel method. Then we dip LSFO on ZnO nanofiber and grow it on the interdigital gold electrode substrate for gas sensors. The results show that the ZnO/LSFO heterostructure gas sensor has a good sensing response to H2S gas and exhibits good gas selectivity. The best gas response is 52.17% under 4 ppm H2S and work temperature 200°C, which has good recovery and reproducibility.  相似文献   
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Nanosized particles of CoAlxFe2-xO4, where 0?≤?x?≤?2, were synthesized by the sol–gel combustion method and the magnetic properties of these compounds were investigated. According to X-ray diffractograms, the samples are single phase and the crystallite size is between 7 and 25?nm. The room temperature saturation magnetization of the samples was estimated from the cation distribution and ferromagnetic resonance spectra were used to determine the magnetocrystalline anisotropy. The results show that the saturation magnetization and the magnetocrystalline anisotropy vary over a wide range, from maxima of Ms =?0.42?MA/m and K?=?0.39?kJ/m3 for x?=?1.0 to minima of almost zero for x?≈?1.4, a result that could be useful for practical applications of these materials.  相似文献   
9.
采用伪布尔模型和启发式算法来求解无容量设施选址问题。首先给出了问题的伪布尔(pseudo-Boolean)表示,然后基于Khumawala规则对问题进行预处理,最后提出两种启发式分支准则来求解问题。实验结果表明所提算法简单有效。  相似文献   
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