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排序方式: 共有4055条查询结果,搜索用时 31 毫秒
1.
Larry R. Falvello 《Crystallography Reviews》2020,26(3):117-140
This educational review postulates the importance of maintaining an adequate level of crystallographic education among structure-dependent scientists whose interests are not primarily in crystallography, at a time when automation and validation have made it possible to obtain high-quality structure analyses in many cases with a minimum of crystallographic background. The topics addressed are intended to form a second round of crystallographic education for a novice user whose first round involved hands-on experience with structure solution and an introduction to elementary concepts. The specific topics, chosen for their relevance as basic knowledge and their lack of emphasis in many formal treatments, are (1) crystallographic reference frames and the utility of the reciprocal cell in geometrical calculations; (2) the relationship between the two concepts that constitute our model of the crystal, namely the unit cell and the lattice; (3) the manner in which an atom is represented in concept and in practice; (4) the importance of interleaved symmetry elements required by the presence of additional symmetry on a lattice; (5) the harnessing of the natural properties of the crystalline state for the potential manipulation of properties of synthetic crystals; and (6) useful terminology for navigating a crystal structure. 相似文献
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Sheng WANG Jun WANG Yingjie XU Weihong ZHANG Jihong ZHU 《Frontiers of Mechanical Engineering》2020,15(2):319-327
Frontiers of Mechanical Engineering - Lattice structures have numerous outstanding characteristics, such as light weight, high strength, excellent shock resistance, and highly efficient heat... 相似文献
4.
《Ceramics International》2020,46(9):13711-13723
Multi-track Ti-based wear-resistant composite coatings were fabricated on TC4 alloy surfaces using laser-clad TC4 + Ni45 + Co–WC mixed powders with different Y2O3 contents (0, 1, and 3 wt%). The microstructure, microhardness, and tribological properties of the coatings were characterised using X-ray diffraction, scanning electron microscopy, energy dispersive spectrometry, electron probe X-ray micro analyser, microhardness tester, and friction and wear testing apparatus. The results showed that the number of cracks on the coating surfaces gradually decreased with the addition of Y2O3 and that residual Co–WC powders existed in the coating subsurfaces. The phase composition of the coatings with different Y2O3 contents remained unchanged and was mainly composed of reinforcing phases of TiC, TiB2, Ti2Ni, and matrix α-Ti. With the addition of Y2O3, the coating microstructure was remarkably refined, the direction characteristic of the TiC dendrites obviously weakened, and the nucleation rate significantly increased. When the added Y2O3 was 3 wt%, a large amount of TiB2–TiC-dependent growth composite phases precipitated in the coating. The two-dimensional lattice misfit between (0001)TiB2 and (111)TiC was 0.912%, which indicated that TiB2 and TiC formed a coherent interface. When the amount of Y2O3 was increased, the microhardness of the coatings gradually decreased, and the wear volume of the coatings first increased and then decreased. Under the effect of the TiB2–TiC composite phases, the wear resistance of the 3 wt% Y2O3 coating was optimal. The 3 wt% Y2O3 coating friction coefficient was the lowest, and the wear mechanism was abrasive wear. 相似文献
5.
《中国有色金属学会会刊》2020,30(3):559-570
The formation of non-dendritic structures in the primary phase of an aluminum alloy solidified using low superheat pouring with a shearing field (LSPSF) machine was investigated by numerical simulation. The growth and motion of a dendrite during solidification was simulated by a combination of the lattice Boltzmann method and the phase field method. The simulation results indicated that enough shear flow helped homogenize the concentration fields, rotate crystals and altere microstructures from dendritic to non-dendritic. The interaction of grains was also discussed. A fragmentation criterion was established based on partial remelting of dendrite arms; fragmentation was enhanced by a strong shear flow and larger inclined angles. The simulation results were verified experimentally. 相似文献
6.
Channa Wang Ling Li Huihua Wang Tianpeng Qu Jun Tian Deyong Wang Zhenhui Kang 《加拿大化工杂志》2020,98(8):1784-1793
Cost-effective catalysts for hydrogen evolution reaction (HER) are attractive for sustainable production of H2 fuel. Herein, a series of tunable Ni/Fe-Mo carbide catalysts have been synthesized via a sol-gel method coupling with a subsequent high temperature carbonization process. The amount of nickel and iron was tuned in the Mo7/C precursors, accomplishing a favourable performance of noble-metal-free electrocatalysts for HER. As expected, the designed Ni10Fe4Mo7/C catalyst displays an enhanced catalytic activity toward hydrogen production with an ultralow overpotential (η10 = 110 mV) and striking kinetics (ηonset = 58 mV, k = 54 mV · dec−1) in the alkaline electrolyte (1 M KOH), which are comparable to those of the commercial 20% Pt/C catalyst. Such excellent performance of Ni10Fe4Mo7/C could be attributed to the high intrinsic activities of Ni-based alloys (NiMo4) and Mo2C, as well as to the lattice contraction in the Mo2C unit cell, in accordance with its high electrochemical surface area (~133 m2 · g−1) and low charge-transfer resistance (~31.5 Ω) for the associated electrode. 相似文献
7.
In this article, we developed a pore-scale model of integrated lattice Boltzmann method and cellular automata to investigate competitive growth of aerobic nitrite and ammonium oxidizers in a bioreactor. The results showed that inlet nutrient concentrations have significant effects on maximum biofilm concentration, ratio of microorganisms' concentrations, growth pattern, and time. The local availability of oxygen could control the competition, resulting in different growth patterns. The coexistence of ammonium and nitrite in same inlet zone increased not only the biofilm concentration (7%) but also the ratio of microorganisms' concentrations (36%). Although this coexistence decreased the total biofilm concentration in some cases, it increased the growth rate about 25%. Changes of the maximum biomass concentration could change biofilm concentration of about 40% and microorganisms' concentrations ratio of about 30%. This framework provides a powerful tool to improve our understanding of dynamic interdependency of many complex microbial consortia systems with environments. 相似文献
8.
Recently, microfluidic paper-based analytical devices (μPADs) have outstripped polymeric microfluidic devices in the ease of fabrication and simplicity. Surface tension-based fluid motion in the paper's porous structure has made the paper a suitable substrate for multiple biological assays by directing fluid into multiple assay zones. The widespread assumption in most works for modeling wicking in a paper is that the paper is a combination of capillaries with the same diameter equal to the effective pore diameter. Although assuming paper as a bundle of capillaries gives a good insight into pressure force that drives the fluid inside the paper, there are some difficulties using the effective pore radius. The effective pore radius is totally different from the average geometrical pore radius which makes it impossible to predict wicking in μPADs based on geometrical parameters. In this article, we introduce different analytical and numerical models to investigate the possibility of determining the permeability of the paper, based on geometrical parameters rather than effective parameters. The lattice Boltzmann method is used for numerical simulations. The permeability of each of the proposed models was compared with the experimental permeability. Results indicated that assuming paper as a combination of capillaries and annuluses leads to accurate results that totally depend on average geometrical values rather than effective values. This paves the way for prediction of the fluid wicking only by considering average geometrical pore and fiber diameters. 相似文献
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10.
Wontae Lee Soyeong Yun Hao Li Jaeyoung Kim Hayeon Lee Kyeongkeun Kwon Jin Yong Lee Young‐Min Choi Won‐Sub Yoon 《Small (Weinheim an der Bergstrasse, Germany)》2020,16(5)
The anionic redox chemistries of layered cathode materials have been in focus recently due to an intriguing phenomenon that cannot be described by the number of electrons of transition metal ions. However, even though several studies have investigated the anionic redox chemistry of layered materials in terms of the charge compensation, the relationship between the origin of the structural behavior and anionic redox chemistry in layered materials remains poorly understood. In addition, a simultaneous redox process of transition metal ions could occur through the d bands interaction. Here, it is demonstrated that the anionic redox chemistry is associated with the anisotropic structural behavior of the layered cathode materials albeit without providing additional capacities exceeding the theoretical values. These findings will provide a foundation of a new chapter in the understanding of the properties of materials. 相似文献