Description of the thermodynamic properties and fluid-phase behavior of aqueous solutions of linear,branched, and cyclic amines

The SAFT-γ Mie group-contribution equation of state is used to represent the fluid-phase behavior of aqueous solutions of a variety of linear, branched, and cyclic amines. New group interactions are developed in order to model the mixtures of interest, including the like and unlike interactions between alkyl primary, secondary, and tertiary amine groups (NH₂, NH, N), cyclic secondary and tertiary amine groups (cNH, cN), and cyclic methine-amine groups (cCHNH, cCHN) with water (H₂O). The group-interaction parameters are estimated from appropriate experimental thermodynamic data for pure amines and selected mixtures. By taking advantage of the group-contribution nature of the method, one can describe the fluid-phase behavior of mixtures of molecules comprising those groups over broad ranges of temperature, pressure, and composition. A number of aqueous solutions of amines are studied including linear, branched aliphatic, and cyclic amines. Liquid–liquid equilibria (LLE) bounded by lower critical solution temperatures (LCSTs) have been reported experimentally and are reproduced here with the SAFT-γ Mie approach. The main feature of the approach is the ability not only to represent accurately the experimental data employed in the parameter estimation, but also to predict the vapor–liquid, liquid–liquid, and vapor–liquid–liquid equilibria, and LCSTs with the same set of parameters. Pure compound and binary phase diagrams of diverse types of amines and their aqueous solutions are assessed in order to demonstrate the main features of the thermodynamic and fluid-phase behavior.     

Flame Front Deformation Instabilities of Filtration Combustion for Initial Thermal Perturbation

The flame front deformation instability of low-velocity filtration combustion within an inert packed bed is studied based on the initial preheating non-uniformity. Based on the experimental phenomena, an initial thermal perturbation model is numerically proposed so as to predict the deformation behaviors of the flame front instabilities. The numerical prediction indicates that the assumption of an initial thermal perturbation is a feasible explanation as the cause of the flame front inclination instability. As the initial thermal perturbation increases, the phenomena of the flame front break and shrinking instabilities could easily occur at high filtration velocity or low equivalence ratio. Moreover, the evolutions of the flame front break rate and the shrinking rate are quantitatively analyzed.     

Steady MHD Casson Ohmic heating and viscous dissipative fluid flow past an infinite vertical porous plate in the presence of Soret,Hall, and ion‐slip current

In the present study, the influence of Hall and ion‐slip current on steady magnetohydrodynamics mixed convective, Ohmic heating, and viscous dissipative Casson fluid flow over an infinite vertical porous plate in the presence of Soret effect and chemical reaction are investigated. The modeling equations are transformed into dimensionless equations and then solved analytically through the multiple regular perturbation law. Computations are performed graphically to analyze the behavior of fluid velocity, temperature, concentration, skin friction, Nusselt number, and Sherwood number on the vertical plate with the difference of emerging physical parameters. This study reflects that the incremental values of Casson fluid parameter and Schmidt number lead to reduction in velocity. However, fluid velocity rises due to enhancement of ion‐slip parameter but an opposite effect is observed in case of Hall parameter. In addition, the Sherwood number declines with enhancing dissimilar estimators of the chemical reaction, Schmidt number, as well as Soret number.     

Chemical-Shift Perturbations Reflect Bile Acid Binding to Norovirus Coat Protein: Recognition Comes in Different Flavors

Bile acids have been reported as important cofactors promoting human and murine norovirus (NoV) infections in cell culture. The underlying mechanisms are not resolved. Through the use of chemical shift perturbation (CSP) NMR experiments, we identified a low-affinity bile acid binding site of a human GII.4 NoV strain. Long-timescale MD simulations reveal the formation of a ligand-accessible binding pocket of flexible shape, allowing the formation of stable viral coat protein–bile acid complexes in agreement with experimental CSP data. CSP NMR experiments also show that this mode of bile acid binding has a minor influence on the binding of histo-blood group antigens and vice versa. STD NMR experiments probing the binding of bile acids to virus-like particles of seven different strains suggest that low-affinity bile acid binding is a common feature of human NoV and should therefore be important for understanding the role of bile acids as cofactors in NoV infection.     

Adaptive robust boundary control of shaft vibrations under perturbations with unknown upper bounds

This paper presents robust and adaptive boundary control designs to stabilize the two‐dimensional vibration of hybrid shaft model. The hybrid shaft is mathematically represented by a set of partial differential equations, governing the shaft vibrations, coupled to ordinary differential equations, describing rigid body spinning and dynamic boundary conditions. The control objective is to stabilize the transverse vibrations of the perturbed shaft while regulating the spinning rate. To achieve this, the paper first establishes robust boundary control laws that fulfil the control objective in the presence of modeling uncertainties and external disturbances operating over the shaft domain and boundary. Lyapunov‐based analyses show that the proposed robust control exponentially stabilizes the shaft with vanishing distributive perturbations, while assuring ultimately bounded vibrations in the case of nonvanishing perturbations. Then, adaptive control philosophy is utilized to achieve redesigned robust controllers that only use online adaptation of control gains without acquiring the knowledge of bounds on perturbations, as well as dynamic parameters. An advantage of this design is avoiding an overconservative robust control law, which may induce poor stability and chattering in tackling system perturbations with unknown upper bounds. Simulations through finite element method illustrate the results. Copyright © 2014 John Wiley & Sons, Ltd.     

大型MOX燃料快堆钠空泡反应性微扰理论研究

钠空泡反应性效应是钠冷快堆核设计和安全分析的重要内容。本文基于多群节块扩散法，采用微扰理论推导出钠空泡反应性的计算方法，对1 000 MWe钠冷快堆MOX燃料堆芯的总钠空泡反应性、空间分布、物理分项进行了计算。结果表明，钠空泡反应性主要来源于中子泄漏的增加和能谱的硬化，两者一正一负，且空间分布规律相反，导致钠空泡反应性具有强烈的空间依赖性；对于所计算的MOX燃料堆芯钠空泡反应性高达3 $左右。计算和分析结果阐明了钠空泡反应性的产生机理和分布规律，可为低钠空泡的设计提供参考。     

Estimation of magnetic island width by the fluctuations of electron cyclotron emission radiometer on J-TEXT

The width of a magnetic island is an important parameter for the quantitative analysis of magnetohydrodynamic-related physics. An electron cyclotron emission radiometer(ECE) is a powerful tool that can be used to obtain this width, which can usually be determined from the flat temperature distribution at the O-point phase or the maxima temperature perturbation. An improved method to estimate the width of a magnetic island is proposed in this paper, and it is independent of calibration. With this method and the existing 24-channel ECE system, the width of a rotation magnetic island can be estimated. Additionally, by filtering the fluctuation ECE signal, the evolution of the magnetic island can be obtained. The results of this method are consistent with those of the integrated magnetic probe signals, which represent the relative change of the magnetic island.     

基于摄动法的表贴式永磁电机转子偏心空载气隙磁场计算

采用摄动法解析计算表贴式永磁电机转子偏心空载气隙磁场,以无量纲的偏心扰动量作为摄动变量,可解决表贴式永磁电机内转子结构和外转子结构的转子偏心磁场解析问题。根据气隙区域及永磁体区域的边界条件求解拉普拉斯方程和泊松方程,通过矢量磁位推导出气隙磁通密度的解析表达式,进而应用麦克斯韦应力张量法计算不平衡磁拉力,并将解析法结果与有限元法结果进行比较,发现二者一致性较好,验证了该方法的正确性和有效性。     

Hall current impacts on unsteady MHD free convective flow past an infinite vertical porous surface

In this paper, the magnetohydrodynamic free convective flow of an incompressible electrically conducting fluid over a vertical plate embedded in a porous medium is considered. A homogeneous transverse magnetic field is applied in the presence of a heat source and chemical reaction in a rotating frame, taking Hall current effects into account. The momentum equations for the fluid flow in a porous medium were determined by Brinkman modeling. At the undisturbed state, both the plate and fluid have an rigid body rotation due to the constant angular velocity, perpendicular to the infinite vertical plane surface. The vertical surface is subject to the homogeneous constant suction and the heat on the surface vary by time about a nonzero constant rate whereas the temperature of free stream is engaged to be constant. The accurate solutions for the velocity, temperature, and concentration distributions were acquired systematically using the perturbation method. The consequences of an assortment of governing flow parameters on the velocity, temperature, and concentration were analyzed through graphical profiles. The computational results for the skin friction, Nusselt number, and Sherwood number in a tabular format were also examined.