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1.
Paul J. Flory 《Polymer International》1985,17(2):96-102
The earliest investigations on rubber elasticity, commencing in the 19th century, were necessarily limited to phenomenological interpretations. The realisation that polymers consist of very long molecular chains. commencing c. 1930, gave impetus to the molecular theory of rubber elasticity (1932-). according to which the high deformability of an elastomer, and the elastic force generated by deformation, stem from the configurations accessible to long molecular chains. Theories of rubber elasticity put forward from 1934-1946 relied on the assumption that the junctions of the rubber network undergo displacements that are affine in macroscopic strain. The theory of James and Guth (1947) dispensed with this premise, and demonstrated instead that the mean positions of the junctions of a ‘phantom’ network consisting of Gaussian chains devoid of material properties are affine in the strain. The vital significance of the distinction between the actual distribution of chain vectors in a network and their distribution if the junctions would be fixed at their mean positions went unnoticed for nearly 30 years. Experimental investigations, commencing with the incisive work of Gee in 1946. revealed large departures from the relationship of stress to strain predicted by the theories cited. This discrepancy prompted extensive studies, theoretical and experimental, during succeeding years. Inquiry into the fundamentals of polymer networks, formed for example by interlinking very long polymer molecules, exposed the need to take account of network imperfections, typically consisting of chains attached at only one end to a network junction. Various means were advocated to make corrections for these imperfections. The cycle rank ζ of the network has been shown (1976) to be the fundamental measure of its connectivity, regardless of the junction functionality and pattern of imperfections. Often overlooked is the copious interpenetration of the chains comprising typical elastomeric networks. Theories that attempt to represent such networks on a lattice are incompatible with this universal feature. Moreover, the dense interpenetration of chains may limit the ability of junctions in real networks to accommodate the fluctuations envisaged in the theory of phantom networks. It was suggested in 1975 that departures from the form predicted for the elastic equation of state are due to constraints on the fluctuations of junctions whose effect diminishes with deformation and with dilation. Formulation of a self-consistent theory based on this suggestion required recognition of the non-affine connection between the chain vector distribution function and the macroscopic strain in a real network, which may partake of characteristics of a phantom network in some degree. Implementation of the idea was achieved through postulation of domains of constraint affecting the equilibrium distribution of fluctuations of network junctions from their mean positions. This led in due course to a theory that accounts for the relationship of stress to strain virtually throughout the ranges of strain accessible to measurement. The theory establishes connections between structure and elastic properties. This is achieved with utmost frugality in arbitrary parameters. 相似文献
2.
High-T
c
Bi(Pb)-Sr-Ca-Cu-O thin films have been made on single-crystal MgO substrates using high-pressure dc sputtering technique. X-ray studies confirm the crystallinity and highly oriented structure withc-axis perpendicular to the substrate. By optimizing the annealing schedule the formation of the high-T
c
phase is stabilized. The best film exhibited superconducting transition temperature with zero-resistance temperature,T
c(0), as high as 101 K. Temperature dependence ofJ
c
indicates the presence of Josephson-type weak links. 相似文献
3.
4.
Jorge Soriano-Santos† Setsuko Iwabuchi Kenshiro Fujimoto 《International Journal of Food Science & Technology》1992,27(3):337-346
Nitrogen was extracted more efficiently from amaranth seed with 0.04 M Na2 SO4 (5% w/v) than with either 0.09 M or 0.17 M NaCl (5% or 10% w/v), despite both solutions having the same ionic strength (μ= 1). Solubility of saline soluble proteins (albumin ± globulin) was very poor in either water or 1M NaCl, but increased in 0.4M NaCl at alkaline pH between 7 and 10. Globulins were very soluble in 0.4M NaCl at a pH 9. Albumin was the main storage protein. Saline soluble proteins formed very weak gels. 相似文献
5.
国有企业计算机网络管理 总被引:1,自引:0,他引:1
本论文在简单了解了计算机网络的相关内容后,对国有企业的计算机网络进行了简单的介绍,并举例说明了某国有企业的网络管理结构及功能。 相似文献
6.
Lei Guo Xingwei Wang Qingyang Song Weigang Hou Fei Yang 《Information Sciences》2008,178(18):3635-3644
With the development of intelligent optical networks and the general multi-protocol label switching (GMPLS) technique, the seamless convergence between IP network and optical network is no longer be a dream but a practical reality. Similar to the Internet, current optical networks have been divided into multiple domains each of which has its own network provider and management policy. Therefore, the development of multi-domain optical networks will be the trend of new-generation intelligent optical networks, and GMPLS-based survivability for multi-domain optical networks will become a hot topic of research in the future. This paper provides a comprehensive review of the existing survivable schemes in multi-domain optical networks and analyzes the shortcomings of current research. Based on previous studies, we present possible challenges and propose new ideas to design efficient survivable schemes to guide the future work of researchers in multi-domain optical networks. 相似文献
7.
Bumhwi KimAuthor Vitae 《Neurocomputing》2011,74(4):646-655
A new incrementally growing neural network model, called the growing fuzzy topology ART (GFTART) model, is proposed based on integrating the conventional fuzzy ART model with the incremental topology-preserving mechanism of the growing cell structure (GCS) model. This is in addition, to a new training algorithm, called the push-pull learning algorithm. The proposed GFTART model has two purposes: First, to reduce the proliferation of incrementally generated nodes in the F2 layer by the conventional fuzzy ART model based on replacing each F2 node with a GCS. Second, to enhance the class-dependent clustering representation ability of the GCS model by including the categorization property of the conventional fuzzy ART model. In addition, the proposed push-pull training algorithm enhances the cluster discriminating property and partially improves the forgetting problem of the training algorithm in the GCS model. 相似文献
8.
Finite-time weighted average consensus with respect to a monotonic function and its application 总被引:1,自引:0,他引:1
The consensus state is an important and fundamental quantity for consensus problems of multi-agent systems, which indicates where all the dynamical agents reach. In this paper, weighted average consensus with respect to a monotonic function, which means that the trajectories of the monotonic function along the state of each agent reach the weighted average of their initial values, is studied for a group of kinematic agents with time-varying topology. By constructing a continuous nonlinear distributed protocol, such a consensus problem can be solved in finite time even though the time-varying topology involves unconnected graphs. Then the distributed protocol is employed to compute the maximum-likelihood estimation of unknown parameters over sensor networks. Compared with the existing results, the estimate scheme proposed here may reduce the costs of data communication, storage memory, book-keeping and computational overheads. 相似文献
9.
路玲霞 《计算机工程与应用》2012,48(25):57-60
设L是一个完备剩余格,定义了定向完备偏序集上的Hohle意义下的满层L-拓扑,称之为模糊Scott拓扑;基于满层的L-滤子,建立了相应的Scott收敛理论。证明了一个定向完备偏序集是连续的当且仅当对于每一个满层的L-滤子,其Scott收敛等价于按模糊Scott拓扑收敛。 相似文献
10.
Burle Borís; Allain Sonia; Vidal Franck; Hasbroucq Thierry 《Canadian Metallurgical Quarterly》2005,31(4):831
Although it is widely accepted that control mechanisms are necessary for human behavior to be adapted, very little is known about how such mechanisms are recruited. A suggestion to fill the gap was put forward by M. M. Botvinick, T. S. Braver, C. S. Carter, D. M. Barch, and J. D. Cohen (2001), who proposed the conflict-loop theory. This theory has been successful in accounting for the reduction of compatibility effects after an incompatible trial: The level of conflict being, on average, higher during an incompatible trial, more control occurs after such a trial. The authors have tested this prediction by sorting the trials on the basis of amount of conflict (quantified by the electromyographic activity) they presented. A reduction of the compatibility effect was observed after incompatible trials, but it was independent of the level of conflict on previous trials, suggesting that the conflict does not trigger changes in executive control. Consequences for the conflict monitoring model are discussed. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献