Manufacturing catalyst-coated membranes by ultrasonic spray deposition for PEMFC: Identification of key parameters and their impact on PEMFC performance

This study deals with the manufacturing of catalyst-coated membranes (CCMs) for newcomers in the field of coating. Although there are many studies on electrode ink composition for improving the performance of proton-exchange membrane fuel cells (PEMFCs), there are few papers dealing with electrode coating itself. Usually, it is a know-how that often remains secret and constitutes the added value of scientific teams or the business of industrialists. In this paper, we identify and clarify the role of key parameters to improve coating quality and also to correlate coating quality with fuel cell performance via polarization curves and electrochemical active surface area measurements. We found that the coating configurations can affect the performance of lab-made CCMs in PEMFCs. After the repeatability of the performance obtained by our coating method has been proved, we show that: (i) edge effects, due to mask shadowing - cannot be neglected when the active surface area is low, (ii) a heterogeneous thickness electrode produces performance lower than a homogeneous thickness electrode, and (iii) the origin and storage of platinum on carbon powders are a very important source of variability in the obtained results.     

Transition metal atoms anchored on nitrogen-doped α-arsenene as efficient electrocatalysts for nitrogen electroreduction reaction

Electrocatalytic reduction of N₂ to NH₃ under ambient conditions, inspired by biological nitrogen fixation, is a new approach to address the current energy shortage crisis. As a result, developing efficient and low-cost catalysts is critical. The catalytic activity, catalytic mechanism, and selectivity of α-arsenene (α-Ars) catalysts anchored with various transition metal atoms and doped with different numbers of N atom were investigated for N₂ reduction reaction (NRR) in this paper. Results reveal that compared with WN₃-α-Ars which is coordinated with three N atoms, asym-WN₂As-α-Ars that coordinated with two N atoms not only exhibits high catalytic activity (U_L = ?0.36 V), but can also successfully suppress the hydrogen evolution reaction (HER). It is manifested that reducing the number of coordination atoms can promote the selectivity of the transition metal (TM) loaded N-doped arsenene catalysts. Furthermore, activity origin analyses show both the charge on 1N–NH and φ form volcano-type relationship with the limiting potential. The active center of the catalyst, which acts as the charge transporter and has the moderate ability to retrieve charges, is the most efficient in NRR. Overall, this research creates high performance NRR catalysts by varying the number of coordinating N atoms, which provides a novel idea for the development of new NRR catalysts.     

稳产国Ⅵ柴油并兼产喷气燃料技术方案的工业应用

介绍了浙江石油化工有限公司新建的3 Mt/a柴油加氢精制装置，其配套使用中国石化石油化工科学研究院有限公司开发的催化剂级配技术，并实施了可根据原料供应及市场产品需求情况灵活调整切换的2种生产技术方案。1 a的安稳生产运行结果表明:该装置以直馏柴油为主原料，通过分馏塔的馏分切割及其侧线抽出，实现了稳产国Ⅵ柴油并兼产喷气燃料技术方案的工业化应用；在实施以兼产喷气燃料为主的生产技术方案时，通过调整常一线柴油的掺炼量，不仅可以生产含硫量小于10.0 μg/g的精制柴油产品，同时兼产所得到的喷气燃料产品含硫量小于0.5 μg/g，赛波特颜色号值大于30；在实施主产精制柴油组分方案时，通过掺炼质量分数为20%~40%的催化柴油，并使所提炼得到的精制柴油组分含硫量小于6.0 μg/g的前提下，这些精制柴油组分产品既可直接作为满足国Ⅵ柴油产品出厂待售，也可作为柴油调和组分储存待用于产品的进一步优化。     

焙烧态水铝钙石催化剂的制备及催化合成生物柴油

分别采用共沉淀法、清洁法制备焙烧态水铝钙石,通过低温N2吸脱附法、CO2-TPD、XRD、DTA和FT-IR表征结构,并将其作为大豆油与甲醇酯交换合成生物柴油的催化剂,探讨制备方法对焙烧态水铝钙石催化合成生物柴油的影响。此外,考察了Ca/Al摩尔比、焙烧温度、甲醇与大豆油摩尔比(醇油比)、催化剂用量和反应时间对酯交换合成生物柴油的影响。结果表明,清洁法制备的焙烧态水铝钙石具有更高的比表面积,强碱中心的表面碱量更大,催化活性更高。当Ca/Al摩尔比为2∶1,焙烧温度为600℃时,制备的Ca2Al O-2-600催化剂的催化活性最高,在醇油比8∶1、催化剂用量3%、反应温度65℃、反应时间4 h的条件下,大豆油转化率达到98. 0%。催化剂经重复使用3次后仍保持较高催化活性。     

The influence of transition metals – Fe,Co, Cu on transformation of organic matters from Domanic rocks in hydrothermal catalytic system

Character of conversion of organic matter from Domanic rocks of Pervomaiskoye field (Tatarstan) of Semiluki horizon of upper Devonian deposits in the hydrothermal-catalytic system at temperature of 300?°C in carbon dioxide medium was studied with the application of complex of oil-soluble precursors of catalysts containing Fe, Co, and Cu. In presence of catalysts complex, content of organic extract increases, in which content of hydrocarbon fractions, saturated and aromatic hydrocarbons, increases 1.5 times, while resins content decreases by two times. As result of kerogen destruction in products of experiments, the content of asphaltenes and carbonaceous substances such as carbenes and carboides increase.     

基于α-FeOOH催化H2O2蒸气的低温烟气脱硝实验

针铁矿是分布广泛、储量丰富的铁氧化物，其主要成分为α-羟基氧化铁（α-FeOOH）。为了探究针铁矿在催化H₂O₂烟气脱硝反应中的性能，本文通过沉淀-水解法制备了α-FeOOH，并在自行搭建的实验台上开展了α-FeOOH催化H₂O₂的低温烟气脱硝实验研究，深入分析了H₂O₂流量、H₂O₂浓度、汽化温度、反应温度和共存气体浓度等工况参数对脱硝性能的影响。采用离子色谱（IC）分析了单独脱硝反应和同时脱硫脱硝反应后的含氧酸成分，结合各项表征分析技术考察了催化剂反应前后的理化特性和稳定性。实验结果显示，随着汽化温度和反应温度的升高，NO的脱除效率先增加后降低；增加H₂O₂浓度对脱硝效率有明显的促进作用。当汽化温度为140℃、反应温度为160℃时，以2.5mL/h注入10mol/L的H₂O₂脱硝效率达到80%。当SO₂浓度为1000μL/L时，脱硝效率提高至86.4%。离子色谱分析结果显示，单独脱硝反应和同时脱硫脱硝反应后含氧酸产物为HNO₃和H₂SO₄。反应前后催化剂的表征结果显示，α-FeOOH在脱硝反应后依然具有良好的稳定性，显示出针铁矿在低温烟气脱硝工艺中的潜在应用前景。     

Catalytic steam reforming of tar for enhancing hydrogen production from biomass gasification: a review

Presently, the global search for alternative renewable energy sources is rising due to the depletion of fossil fuel and rising greenhouse gas (GHG) emissions. Among alternatives, hydrogen (H₂) produced from biomass gasification is considered a green energy sector, due to its environmentally friendly, sustainable, and renewable characteristics. However, tar formation along with syngas is a severe impediment to biomass conversion efficiency, which results in process-related problems. Typically, tar consists of various hydrocarbons (HCs), which are also sources for syngas. Hence, catalytic steam reforming is an effective technique to address tar formation and improve H₂ production from biomass gasification. Of the various classes in existence, supported metal catalysts are considered the most promising. This paper focuses on the current researching status, prospects, and challenges of steam reforming of gasified biomass tar. Besides, it includes recent developments in tar compositional analysis, supported metal catalysts, along with the reactions and process conditions for catalytic steam reforming. Moreover, it discusses alternatives such as dry and autothermal reforming of tar.     

β-环糊精修饰Ni/SFCC强化C9石油树脂催化加氢性能

以废弃的流化催化裂化催化剂（简称SFCC）为载体、β-环糊精为金属络合剂、硝酸镍为镍源，采用湿法浸渍法制备β-环糊精修饰的Ni/SFCC催化剂（简称Ni/SFCC-CD催化剂），考察其对C9石油树脂的催化加氢性能。通过BET比表面积测试、H2程序升温还原、X射线光电子能谱等手段对催化剂的物相结构进行表征，研究β-环糊精的作用机理及其对催化剂加氢性能的影响。研究结果表明：在反应温度为260 ℃、反应压力为7 MPa、反应时间为2.0 h的最优条件下，采用Ni/SFCC-CD催化C9石油树脂加氢，可制得溴值为1.45 gBr/（100 g）、色号（加纳德）小于1的水白色氢化C9石油树脂，催化剂循环使用4次后仍保持良好活性；β-环糊精的作用机理是：β-环糊精与硝酸镍产生络合作用，抑制硝酸镍的分解、控制NiO的结晶过程和增强活性组分Ni与载体之间的相互作用力，从而提高了Ni/SFCC-CD的催化活性和稳定性。