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Monomers and their polymers containing 3-arylcarbazolyl electrophores have been synthesized by the multi-step synthetic route. The materials were characterized by thermo-gravimetric analysis, differential scanning calorimetry and electron photoemission technique. The polymers represent materials of high thermal stability having initial thermal degradation temperatures in the range of 331–411 °C. The glass transition temperatures of the amorphous polymeric materials were in the rage of 148–175 °C. The electron photoemission spectra of thin layers of monomers showed ionization potentials in the range of 5.6–5.65 eV. Hole-transporting properties of the polymers were tested in the structures of organic light emitting diodes with Alq3 as the green emitter. The device containing hole-transporting layers of polyether with 3-naphthylcarbazolyl groups exhibited the best overall performance with a maximum current efficiency of 3.3 cd/A and maximum brightness of about 1000 cd/m2. 相似文献
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A new constitutive equation of thermoelasticity for crystals is presented based on the interatomic potential and solid mechanics at finite temperature. Using the new constitutive equation, the calculations for crystal copper and graphene are carried out under different loading paths at different temperatures. The calculated results are in good agreement with those of the previous thermoelasticity constitutive equation based on quantum mechanics, which clearly indicates that our new constitutive equation of thermoelasticity is correct. A lot of comparisons also show that the present theory is more concise and efficient than the previous thermal stress theory in the practical application. 相似文献
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This paper deals with the investigation of the effect of hygrothermal conditions on the bending of nanoplates using Levy type solution model employing the state-space concept. The nanoplates are assumed to be subjected to a hygrothermal environment. The two-unknown function plate theory is used to derive the governing differential equations on the basis of Eringen's nonlocal elasticity theory. The governing equations contain the small scale effect as well as hygrothermal and mechanical effects. These equations are converted into a set of first-order linear ordinary differential equations with constant coefficients. Analytical solution of bending response for nanoplates under combinations of simply supported, clamped and free boundary conditions is obtained. Comparison of the results with those being in the open literature is made. The influences played by small scale parameter, temperature rise, the degree of moisture concentration, boundary conditions, plate aspect ratio and side-to-thickness ratio are studied. 相似文献
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通过对接轨站设置位置和布置图型主要影响因素的分析。按照能够充分反映接轨站作业特点的交接方式。对接轨站所采用的布置图型进行了归纳和分类。 相似文献
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阜阳地区石炭-二叠系煤系烃源岩特征 总被引:2,自引:0,他引:2
阜阳地区石炭-二叠系煤系地层发育,但由于勘探程度较低,对该区煤系地层烃源岩的生烃潜力认识不清,严重制约了该区的油气勘探。在已有资料的基础上,通过有机地球化学和有机岩石学方法并结合模拟实验,探讨了该区煤系烃源岩的生烃潜力。研究结果表明阜阳地区石炭-二叠系煤系烃源岩有机质丰度达到中等-好烃源岩标准,有机质类型以腐殖型为主,盆地模拟结果显示阜阳地区石炭-二叠系煤系地层油资源量为(30.47~152.33)×106t,气资源量为(266.7~1333.7)×108m3,展示阜阳地区石炭-二叠系煤系地层具有较好的生油气潜力。 相似文献
9.
The three-dimensional morphology of polyethylene single crystals grown from dilute solution has been examined by atomic force microscopy. Single crystals were deposited on a soft ground of aqueous solution of poly(vinyl alcohol) (PVA) to avoid the collapse of thin lamellar crystals with thickness of 10 nm. The observation of single crystals on dried PVA clarifies the morphology of a chair type crystal as well as well-known hollow pyramidal type. It has been confirmed that the screw dislocations in the chair type follow a selection rule of the handedness in a manner to relieve the distortion in the chair type. 相似文献
10.
江苏复杂小断块油藏老井侧钻实践与认识 总被引:2,自引:0,他引:2
利用停关、低效井实施老井侧钻,其条件包括油藏、井身及技术经济等3个方面。侧钻效益的好坏与油藏类型、侧钻目标有着很大关系,侧钻断块油层、挖掘构造高部位剩余油成功率高,边底水、高渗透油藏侧钻效果好。实践表明,老井侧钻是提高江苏复杂小断块油藏开发效果,降低投资、提高效益的一项重要手段。 相似文献