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1.
喷雾焙烧法是针对不锈钢混酸废液的全酸回收工艺方法,不仅可以实现废酸中游离酸的回收,还可以实现化合酸及金属元素的回收。针对青拓集团福建鼎信科技有限公司不锈钢混酸废液再生中试项目,介绍了喷雾焙烧法不锈钢混酸再生机组的技术方案、运行指标,并与引进机组进行了主要技术经济指标对比分析,各项指标均达到或超过了国外同类机组水平。同时,对该技术的进一步研究方向进行了展望。  相似文献   
2.
王晋虎  古向前  周曼 《中州煤炭》2021,(2):73-77,82
以流域污染负荷核算为重点,对京杭运河(苏州段)两岸涉及的5个区20个街道各污染源负荷进行核算,对污染源进行系统、高精度分析,明确排污单元,核算污染贡献,根据各区及各街道水污染源解析结果,形成重点整治内容的各控制单元。研究为削减氨氮和总磷的总量提供数据支撑,为各项水污染防治提供技术支持和科学指导。  相似文献   
3.
基于单片机设计一套无线温湿度检测系统,用软硬件相结合的方式,阐述设计的思路和实现的方法,并通过与高精度标准器比对的方式,验证了检测系统的准确性。  相似文献   
4.
In this study, La was doped into the lithium layer of Li-rich cathode material and formed a layered-spinel hetero-structure. The morphology, crystal structure, element valence and kinetics of lithium ion migration were studied by field emission scanning electron microscope (FESEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and electrochemical impedance spectroscopy (EIS). The La doped lithium-rich cathode material exhibited similar initial discharge capacity of 262.8 mAh g?1 at 0.1 C compared with the undoped material, but the discharge capacity retention rate can be obviously improved to 90% after 50 cycles at 1.0 C. Besides that, much better rate capability and Li+ diffusion coefficient were observed. The results revealed that La doping not only stabilized the material structure and reduced the Li/Ni mixing degree, but also induced the generation of spinel phase to provide three-dimensional diffusion channels for lithium ion migration. Moreover, the porous structure of the doped samples also contributed to the remarkable excellent electrochemical performance. All of these factors combined to significantly improve the electrochemical performance of the material.  相似文献   
5.
Utilizing inner-crystal piezoelectric polarization charges to control carrier transport across a metal-semiconductor or semiconductor–semiconductor interface, piezotronic effect has great potential applications in smart micro/nano-electromechanical system (MEMS/NEMS), human-machine interfacing, and nanorobotics. However, current research on piezotronics has mainly focused on systems with only one or rather limited interfaces. Here, the statistical piezotronic effect is reported in ZnO bulk composited of nanoplatelets, of which the strain/stress-induced piezo-potential at the crystals’ interfaces can effectively gate the electrical transport of ZnO bulk. It is a statistical phenomenon of piezotronic modification of large numbers of interfaces, and the crystal orientation of inner ZnO nanoplatelets strongly influence the transport property of ZnO bulk. With optimum preferred orientation of ZnO nanoplatelets, the bulk exhibits an increased conductivity with decreasing stress at a high pressure range of 200–400 MPa, which has not been observed previously in bulk. A maximum sensitivity of 1.149 µS m−1 MPa−1 and a corresponding gauge factor of 467–589 have been achieved. As a statistical phenomenon of many piezotronic interfaces modulation, the proposed statistical piezotronic effect extends the connotation of piezotronics and promotes its practical applications in intelligent sensing.  相似文献   
6.
It is still a challenge for simultaneously achieving high heat resistance, high strength and outstanding electrochemical performance for separators in power lithium-ion battery (PLB). Herein, new high performance electrospun separators are developed through building unique structure based on polyimide (PI) and poly (m-phenylene isophthalamide) (PMIA). Orthogonal tests (44) show that the magnitude order of electrospinning factors on the morphology of membrane is concentration>injection rate>receiving distance>voltage. With the optimum factors, the electrospun membrane (PI/PMIA) was prepared, which was further pressed at 100°C for 10 min to get treated membrane (H-PI/PMIA). Interestingly, the comprehensive performance of PI/PMIA is not a simple combination of those of PI and PMIA; instead, PI/PMIA has much better thermal and mechanical properties than both PI and PMIA, proving that PI/PMIA has a synergistic effect. PI/PMIA and H-PI/PMIA not only have good ionic conductivity and electrochemical stability, but also have superiorly high properties including dimensional stability (thermal shrinkage temperature>300°C), tensile strengths (24.1 MPa for PI/PMIA, 34.3 MPa for H-PI/PMIA) and capacity retentions (97.9%, 99.2%) compared with electrospun membranes for PLBs reported in the literature so far (SCI database). The mechanism behind these attractive performances is discussed from condensed structure of membranes.  相似文献   
7.
超深断溶体油藏纵向连通性好,油井生产时井底下方油气易沿断裂高导流通道向井底流动。为明确油井油藏动用深度,以Z油田W9井为例,对比分析超深断溶体油藏流温、静温特征,并基于温度特征建立不同温度-深度关系下油井动用深度计算方法。研究表明:同一深度下流温大于静温,与油嘴直径无关;当深度一定时,油嘴直径越大,流温越高;随深度增大,流温与静温差整体呈降低趋势,靠近井底处流温梯度较低;超深断溶体油藏温度特征受热损失、油井动用深度和传热方式影响;W9井在目前4.5 mm油嘴生产条件下动用深度约为52~62 m。该研究可为超深断溶体油藏油柱高度判断、储量计算、合理生产制度的制订提供依据。  相似文献   
8.
Lithium metal anodes (LMAs) are promising for next-generation batteries but have poor compatibility with the widely used carbonate-based electrolytes, which is a major reason for their severe dendrite growth and low Coulombic efficiency (CE). A nitrate additive to the electrolyte is an effective solution, but its low solubility in carbonates is a problem that can be solved using a crown ether, as reported. A rubidium nitrate additive coordinated with 18-crown-6 crown ether stabilizes the LMA in a carbonate electrolyte. The coordination promotes the dissolution of NO3 ions and helps form a dense solid electrolyte interface that is Li3N-rich which guides uniform Li deposition. In addition, the Rb (18-crown-6)+ complexes are adsorbed on the dendrite tips, shielding them from Li deposition on the dendrite tips. A high CE of 97.1% is achieved with a capacity of 1 mAh cm−2 in a half cell, much higher than when using the additive-free electrolyte (92.2%). Such an additive is very compatible with a nickel-rich ternary cathode at a high voltage, and the assembled full battery with a cathode material loading up to 10 mg cm−2 shows an average CE of 99.8% over 200 cycles, indicating a potential for practical use.  相似文献   
9.
LiFePO4 modified by N-doped graphene (NG) with a three-dimensional conductive network structure was synthesized via a one-step in situ hydrothermal method. The effects of N amount of NG on the phase structure, morphology, and electrochemical properties of LiFePO4 are investigated in this study. X-ray diffraction (XRD) results show that doping suitable N amounts in NG do not alter the crystal structure of LiFePO4, and scanning electron microscopy (SEM) images show that NG can slightly reduce the particle size of LiFePO4. The high-resolution transmission electron microscopy (HRTEM) results show that the LiFePO4 particles are well covered and connected by NG. The electrochemical performance confirms that LiFePO4 modified by 20% N-doped graphene (named LFP/NG-4) displays a perfect specific capacity of 166.6 mAh·g?1 at a rate of 0.2C and can reach 125 mAh·g?1 at a rate of 5 C. Electrochemical impedance spectroscopy (EIS) results illustrate that the charge transfer resistance value of the LFP/NG-4 composite is only 58.6 Ω, which is very low compared with LiFePO4. Cyclic voltammetry (CV) tests indicate that the addition of 20% N-doped graphene can effectively reduce electrode polarization and improve reversibility. The LFP/NG-4 composite with a three-dimensional conductive network structure can be regarded as a promising cathode material for Li-ion batteries.  相似文献   
10.
陈海虹  张玲 《光学仪器》2021,43(1):69-75
黄曲霉素B1(aflatoxin B1,AFB1)是一种常见于农作物中的真菌毒素,是所有真菌霉素中毒性最强且具有致癌性。因此,快速、有效地检测出食品中AFB1对于食品安全来说具有重要意义。设计了一种基于表面增强荧光(surface-enhanced fluorescence,SEF)技术的光学芯片用于AFB1灵敏检测。该光学芯片以纳米多孔金(nanoporous gold,NPG)作为荧光增强基底,通过在其表面先后组装适体SH-DNA2和互补适体Cy5-DNA1构建针对AFB1的功能芯片。该芯片利用AFB1和Cy5-DNA1与SH-DNA2之间竞争结合,释放Cy5-DNA1引发来自Cy5荧光信号的衰减,通过监测Cy5的荧光强度的变化实现对AFB1的检测,检测极限可达到10?7μg/L且线性动态范围有4个量级。  相似文献   
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