Optimised phase compositions and improved microwave dielectric properties based on calcium tin silicates

The Ca_(1+2y)Sn_(1-x)Si_(1+y)O_(5-2x+4y) low-permittivity microwave dielectric ceramics were prepared through solid-state reaction at 1350–1450 °C for 5 h. The relations between microwave dielectric properties and phase compositions for non-stoichiometric Ca_(1+2y)Sn_(1-x)Si_(1+y)O_(5-2x+4y) ceramics have been investigated. A single CaSnSiO₅ phase with abnormally positive temperature coefficient of resonant frequency (τ_f = + 62.5 ppm/°C) was synthesised at 1450 °C. This composition was an effective τ_f compensator of CaSiO₃ and Ca₃SnSi₂O₉ phases with typically negative τ_f value. The CaSiO₃ second phase was related to the Sn deficiency in the CaSn_(1-x)SiO_(5-2x) (0 < x < 1.0) composition, whereas the Ca₃SnSi₂O₉ second phase was obtained by controlling the Ca:Sn:Si ratios on the basis of the Ca_(1+2y)SnSi_(1+y)O_(5+4y) (0 < y < 1.0) composition. A promising low-permittivity millimetre-wave ceramic with most excellent microwave dielectric properties (ε_r = 10.2, Q×f = 81,000 GHz and τ_f = −4.8 ppm/°C) was produced from the Ca_(1+2y)SnSi_(1+y)O_(5+4y) (y = 0.4) ceramic.     

Enhanced transduction coefficient in piezoelectric PZT ceramics by mixing powders calcined at different temperatures

Large transduction coefficient ($d_{33}\times g_{33}$) is difficult to obtain in piezoelectric ceramics because these two parameters show opposite trends with compositional modifications. Herein, the Pb(Zr_0.53Ti_0.47)O₃ ceramic powders were calcinated under different temperatures (A:830 °C, B:860 °C, and C:890 °C), and then mixed together according to different weight ratios (1A:1B:1C, 1A:2B:1C, 1A:2B:3C and 3A:2B:1C) for ceramics preparation. Both d₃₃ and g₃₃ are improved successfully, and the transduction coefficient with the weight ratio of 1A:2B:3C reaches up to 17,500 × 10⁻¹⁵ m²/N, which is 60 % higher than that with the powders calcinated under 830 °C, and at least twice those of commercial PZT-4, PZT-5A and PZT-8 ceramics. The improved transduction coefficient is owing to the enhanced piezoelectric constant and spontaneous polarization resulted from the increased grain size, relative density and the fraction of tetragonal phase. These results indicate that this is a simple but effective way to tailor the transduction coefficient in piezoelectric ceramics.     

High birefringence photonic bandgap fiber with elliptical air holes

In this paper, we proposed a high birefringence photonic bandgap fiber (PBGF) with elliptical air holes in cladding and circular air hole in core. The forbidden gaps of the honeycomb structure are calculated when the circular air holes are deformed to the elliptical shape. And the birefringence of the PBGFs is investigated by using a full-vector finite element method (FEM) and the numerical results are presented.     

Fabrication and frequency response of a complex ultrasonic transducer for multilayer evaluation

To characterize the thickness of a corrosive fluid system's coated facilities, such as pipes, tubes, tanks, and structural members, a complex ultrasonic transducer capable of measuring multilayered parts was fabricated and the time and frequency responses were evaluated. The target transducer was constructed with two active dual elements made from tape-cast PbNb₂O₆ sheets and an additional thin-film active element made from sol–gel spin-coated Pb(Zr_0.52Ti_0.48)O₃ films. After adjusting the properties of each active element, a complex transducer was assembled after matching the impedance of each element and considering the minimal interference between the active layers. The impulse response of the assembled complex transducer shows excellent characteristics. Moreover, the assembled transducer's capability of accurately measuring the thickness assures that it can be directly applied to related industries.     

Simulation of humidity control and greenhouse temperature tracking in a growth chamber using a passive air conditioning unit

In this paper, we define a dynamic discrete model of a passive air conditioning unit, without the more typical compression or absorption-refrigeration cycle. The unit is composed of heat exchangers, a positioning system and humid corrugated pads. The aim of the study was to follow the temperature in a greenhouse and to replicate it with a desired and stable relative humidity in a ventilated growth chamber. A control law, based on a quadratic criterion and dynamic programming, taking output error and energy consumption minimisation into account, was used to control the behaviour of the unit in spite of air intake disturbances. The results of the simulation indicate that the air conditioning unit can produce a variable climate in the growth chamber, with a wide range of relative humidity setpoints.     

Influence of SiO2 and CaO additions on the microstructure and magnetic properties of sintered Sr-hexaferrite

The effect of simultaneous addition of CaO and SiO₂ on the microstructure and magnetic properties of sintered SrO-excess Sr-hexaferrites was studied. Both additives markedly affect the grain growth behavior and the magnetic properties. CaO-additions promote densification, which results in increased remanence, but due to simultaneuous grain growth the coercivity drops to <100 kA/m. SiO₂ additions are known to suppress grain growth. Simultaneous addition of CaO and SiO₂ is shown to be very beneficial in tailoring a dense microstructure with relatively small grains. The ratio of CaO/SiO₂ was found to be optimum at about 1, and magnets with a remanence of 430 mT and a coercivity of 300 kA/m were obtained. Transmission electron microscopy (TEM) studies and investigations by energy-dispersive analysis of X-rays (EDX) in the scanning TEM (STEM) mode show that both CaO and SiO₂ are concentrated at grain boundaries and grain junctions forming an amorphous secondary phase.