Electrochemical detection of catechol at integrated carbon nanotubes electrodes

The mechanical stability of the electrode plays a very important role in the long-term stability of electrochemical behavior. In this paper, multi-wall carbon nanotubes (MWCNTs) electrodes were prepared in the holes of glass directly by microwave plasma chemical vapor deposition and the electrochemical behavior of catechol at the integrated MWCNT electrodes was investigated. The oxygen plasma treated CNTs had excellent electrochemical behavior for the analysis of catechol. The catechol was detected in the linear concentration range of 1.0 × 10^− 6 mol L^− 1–1.0 × 10^− 3 mol L^− 1. And because CNTs were integrated directly on the substrate, the stable response to catechol solution showed that the carbon nanotubes electrodes had long-term stability.     

Repair evaluation of concrete cracks using surface and through-transmission wave measurements

Surface opening cracks are common defects in large civil structures like bridges. They allow penetration of water or other agents that result in loss of durability earlier than expected. Their repair can be conducted by the injection of epoxy material that seals the crack sides keeping out any aggressive substances in addition to the recovery of strength. In order to evaluate crack parameters before impregnation as well as to determine the final repair effectiveness, a combination of Rayleigh and longitudinal waves is applied. Rayleigh waves demonstrate the filling condition of the material into the shallow layer near the surface while tomography using longitudinal waves through the thickness yields information about the area inside the structure. Wave propagation dispersion features are exploited by the proposed tomography at different frequencies, demonstrating that higher frequencies lead to more accurate characterization.     

Degradation on a mechanical property of high-modulus aramid fiber due to hyperthermal atomic oxygen beam exposures

High-modulus aramid fiber was exposed to energetic (5 eV) atomic oxygen, which simulates the space environment in low Earth orbit. It was found that Young’s modulus and tensile strength decreased significantly due to the atomic oxygen exposures. X-ray photoelectron spectroscopy showed that the decomposition of amid group occured at the exposed surfaces. Scanning electron microscopy revealed that the diameter of the fiber was not influenced so much by the attack of atomic oxygen, but the exposed fiber became an extremely rough surface. The change in mechanical properties has been explained by the formation of surface texture that is characteristic to the high-energy atomic oxygen collisions.     

Study on early-age cracking of cement-based materials with superplasticizers

The addition of superplasticizers is an important approach to prepare high performance cement-based materials. The effect of polynaphthalene series superplasticizer (PNS) and polycarboxylate type superplasticizer (PC) on early-age cracking and volume stability of cement-based materials was investigated by means of multi-channel ellipse ring shrinkage cracking test, free shrinkage and strength test. The general effect of PNS and PC is to increase initial cracking time of mortars, and decrease cracking sensitivity of mortars. As for decreasing cracking sensitivity of mortars, PC > H-UNF (high-thickness-type PNS) > C-UNF (common-thickness-type PNS). To incorporate superplasticizers is apparently to increases free shrinkage of mortars when keeping the constant W/B ratio and the content of cement pastes. As for the effect of controlling volume stability of mortars, PC > C-UNF > H-UNF. Maximum crack width of mortars with PC is lower, but the development rate of maximum crack width of mortars with H-UNF is faster in comparison with control mortars. Flexural and compressive strength of mortars and concretes at 28 days increased with increasing superplasticizer dosages under drying conditions. C-UNF was approximate to H-UNF, but PC was superior to PNS in the aspect of increasing strength of cement-based materials.     

A review on improving the autonomy of unmanned surface vehicles through intelligent collision avoidance manoeuvres

In recent years unmanned vehicles have grown in popularity, with an ever increasing number of applications in industry, the military and research within air, ground and marine domains. In particular, the challenges posed by unmanned marine vehicles in order to increase the level of autonomy include automatic obstacle avoidance and conformance with the Rules of the Road when navigating in the presence of other maritime traffic. The USV Master Plan which has been established for the US Navy outlines a list of objectives for improving autonomy in order to increase mission diversity and reduce the amount of supervisory intervention. This paper addresses the specific development needs based on notable research carried out to date, primarily with regard to navigation, guidance, control and motion planning. The integration of the International Regulations for Avoiding Collisions at Sea within the obstacle avoidance protocols seeks to prevent maritime accidents attributed to human error. The addition of these critical safety measures may be key to a future growth in demand for USVs, as they serve to pave the way for establishing legal policies for unmanned vessels.