Co?N graphene encapsulated cobalt catalyst for H2O2 decomposition under acidic conditions

Hydrogen peroxide (H₂O₂) has been listed as one of the 100 most important chemicals in the world. However, huge amount of residual H₂O₂ is hard to timely decomposed into O₂ and H₂O under acidic condition, easily resulting in explosion hazard. Here, we reported a core–shell structure catalyst, that is graphene with Co N structure encapsulated Co nanoparticles. Co N graphene shell serves as the active site for the H₂O₂ decomposition, and Co core further enhance this decomposition. Benefiting from it, the H₂O₂ decomposition were close to 100% after 6 cycles without pH adjustment, which increased 6 orders of magnitude compared with no catalyst. At the same time, the O₂ generation reached 99.67% in 2 h with little metal leaching, and ·OH has been greatly inhibited to only 0.08%. This work can cleanly remove H₂O₂ with little deep oxidation and protect the process of H₂O₂ utilization to achieve a safer world.     

5G核心网业务模型的智能化预测研究

摘 要：核心网业务模型的建立是5G网络容量规划和网络建设的基础，通过现有方法得到的理论业务模型是静态不可变的且与实际网络存在偏离。为了克服现有5G核心网业务模型与现网模型适配性较差以及规划设备无法满足用户实际业务需求的问题，提出了一种长短期记忆（long short-term memory，LSTM）网络与卷积LSTM （convolution LSTM，ConvLSTM）网络双通道融合的 5G 核心网业务模型预测方法。该方法基于人工智能（artificial intelligence，AI）技术以实现高质量的核心网业务模型的智能预测，形成数据反馈闭环，实现网络自优化调整，助力网络智能化建设。     

多堆厂址始发事件分析探讨

多堆厂址一级概率安全评价（PSA）研究中，机组数目的增加使得建模工作量剧增，给整个核电厂的风险评估带来困难。结合已有基础，本文研究了多堆厂址始发事件分析的筛选方法，提出利用堆芯损伤频率（CDF）上下限值评估方法，分析厂址内不同机组数对厂址CDF的影响。结果表明，双机组厂址适合优先进行具体分析。针对双机组核电站，对多堆厂址内各始发事件进行筛选。结果表明，丧失厂外电、丧失热阱等事件适合建模分析，并对其他筛选结果给出后续分析建议，为多堆厂址一级PSA后续事故序列建模工作提供了重要基础。     

Core–Shell Photoanodes for Photoelectrochemical Water Oxidation

Photoelectrochemical (PEC) water splitting into hydrogen and oxygen is a promising solution for the conversion and storage of solar energy. Because sluggish water oxidation is the bottleneck of water splitting, the design and preparation of an efficient photoanode is intensively investigated. Currently, all known photoanode materials suffer from at least one of the following drawbacks: ① low carriers separation efficiency; ② sluggish surface water oxidation reaction; ③ poor long-term stability; ④ insufficient water adsorption and gas desorption. Core–shell configurations can endow a photoanode with improved activity and stability by coating an overlayer that plays energetic, catalytic, and/or protective roles. The construction strategy has an important effect on the activity of a core–shell photoanode. Nonetheless, the mechanism for the improvement of performance is still ambiguous and is worthy of a closer examination. In this review, the successes and challenges of core–shell photoanodes for water oxidation, focusing on synthesis strategies as well as functionalities (facilitating carrier separation, surface reaction promotion, corrosion prevention, and bubble detachment) are explored. Finally, the perspectives of this class of materials in terms of new opportunities and efforts are discussed.     

Tuning of shear thickening behavior and elastic strength of polyvinylidene fluoride via doping of ZnO-graphene

ZnO rice like nonarchitects are grafted on the graphene carbon core via a rapid microwave synthesis route. The prepared grafted systems are characterized via XRD, SEM, RAMAN, and XPS to examined the structural and morphological parameters. Zinc oxide grafted graphene sheets (ZnO-G) are further doped in β-phase of polyvinylidene fluoride (PVDF) to prepare the polymer nanocomposites (PNCs) via mixed solvent approach (THF/DMF). β-phase confirmation of PVDF PNCs is done by FTIR studies. It is observed that ZnO-G filler enhances the β-phase content in the PNCs. Non-doped PVDF and PNCs are further studied for rheological behavior under the shear rate of 1–100 s⁻¹. Doping of ZnO-G dopant to the PVDF matrix changes its discontinuous shear thickening (DST) behavior to continues shear thickening behavior (CST). Hydrocluster formation and their interaction with the dopant could be the reason for this striking DST to CST behavioral change. Strain amplitude sweep (10⁻³% -10%) oscillatory test reveals that the PNCs shows extended linear viscoelastic region with high elastic modulus and lower viscous modulus. Effective shear thickening behavior and strong elastic strength of these PNCs present their candidature for various fields including mechanical and soft body armor applications.     

Experimental study on high temperature performances of silica-based ceramic core for single crystal turbine blades

Silica-based ceramic cores are widely utilized for shaping the internal cooling canals of single crystal superalloy turbine blades. The thermal expansion behavior, creep resistance, and high temperature flexural strength are critical for the quality of turbine blades. In this study, the influence of zircon, particle size distribution, and sintering temperature on the high-temperature performance of silica-based ceramic cores were investigated. The results show that zircon is beneficial for narrowing the contraction temperature range and reducing the shrinkage, improving the creep resistance and high-temperature flexural strength significantly. Mixing coarse, medium and fine fused silica powders in a ratio of 5:3:2, not only reduced high temperature contraction, but effectively improved the creep resistance. Properly increasing the sintering temperature can slightly reduce the thermal deformation and improve the high-temperature flexural strength of the silica-based core, but excessively high sintering temperature negatively impacts the creep resistance and high-temperature flexural strength.     

粮仓环境监测系统设计

随着科学技术的发展,粮食行业信息化发展得到了强有力的科技支撑。为满足粮库整体信息化建设的要求,打破"信息孤岛"现状,实现资源整合、数据共享,为大数据分析和数据应用提供数据基础,设计一款能够实时采集粮仓内温湿度、氧气、二氧化碳气体浓度、粮堆高度的数据集成系统。系统采用分层分布式结构,由数据集中器和多种传感器模块组成,数据集中器与各传感器模块间通过RS485总线进行数据通讯,并由数据集中器通过网络专线传输汇总的环境监测数据,通过专用软件进行数据处理和挖掘,从而实现粮仓环境监测和预警等功能。     

压水堆堆芯损伤评价系统研究与开发

堆芯损伤评价是反应堆事故后应急评价的重要组成部分。本文在国外文献基础上,结合国内的运行经验,对压水堆堆芯损伤评价进行研究,并开发了相应的软件程序。堆芯损伤评价包括基于堆芯裸露时间、在线监测仪表读数和取样分析数据三种方法。考虑应急实时要求、电厂实际情况与国际经验,本文采用了基于在线监测仪表读数的评价方法,该方法主要是基于堆芯热电偶读数与安全壳辐射监测仪表读数进行评价,其他监测仪表读数进行辅助合理性证实。     

家用WiFi路由器安全性研究

无线网络的公开传输特性导致WiFi环境中的通信存在着极大的安全隐患。文章通过使用Rogue DHCP攻击方法,对现实环境中的家用WiFi安全性进行了深入评估分析,进一步提出了基于IP冲突的Rogue DHCP攻击方法,并进行了测试验证。结果表明:被测试厂商在路由器环境中,Rogue DHCP攻击都能有效实施,其中"IP冲突诱导"ARP攻击会导致Android设备出现暂时无法使用网络的现象,而iOS设备第一次收到攻击数据包时没有任何反应,但收到持续的攻击数据包时,会导致系统暂时处于无法通信的状态。文章最后提出了针对性的解决方案并予以代码实现。